Corrosion inhibitors based on derivatives of monocarboxamides

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 4, pp. 11–13, April, 1994.     

Power optimization of small-scale chemical oxygen-iodine laser withjet-type singlet oxygen generator

Studies of power optimization of a 5-cm gain length chemical oxygen-iodine laser (COIL) energized by a jet-type singlet oxygen generator (JSOG) are presented. For 10 mmol/s of Cl₂ flow rate, output power of 132 W with chemical efficiency of 14.5% was obtained without a water vapor trap, 163 W and 18% were achieved when coholed (173 K). He was introduced downstream of the JSOG; under these conditions, the small-signal gain was estimated to be 0.32% cm^-1 . 190 W and 10.5% were obtained for 20 mmol/s of CI₂ flow rate. Replacing He by N₂ as a buffer gas resulted in a 13% power decrease only. The main key for increasing the chemical efficiency of a COIL without a water vapor trap for a given iodine-oxygen mixing system is found to be high oxygen pressure and low water vapor pressure inside the reaction zone of the JSOG. The last goal was achieved by optimizing the composition and temperature of the basic hydrogen-peroxide solution (BHP). The experimental results are discussed and related to the composition and flow conditions of the gaseous reactants and of the BHP     

Results of small-signal gain measurements on a supersonic chemicaloxygen iodine laser with an advanced nozzle bank

High-resolution diode laser spectroscopy has been used to probe the gain in the active medium formed by an advanced supersonic chemical oxygen iodine laser (COIL), ejector nozzle bank. The probe beam was directed through the medium at 90° (normal) to the flow velocity and at an angle of 27.5° away from normal incidence. Analysis of the small-signal gain spectrum allowed for the determination of the gain, average gas velocity, static pressure, and temperature. The dependence of gain, temperature, and gas velocity on the primary nitrogen molar flow rate and basic hydrogen peroxide temperature was obtained. A maximum small-signal gain of 7 × 10^-3 cm^-1, average gas velocity of 575 m/s, static temperature of 172 K were measured for flow rates of 270 mmole/s of primary nitrogen, 39.2 mmole/s of chlorine, 11 mmole/s of secondary nitrogen, and 0.8 mmole/s of iodine. Estimation of the static pressure in the flow core from spectroscopic data is very close to the static sidewall pressure. The role of transverse velocity components in the gas flow and their effect on the interpretation of gain profiles is discussed