A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry     

Modeling wireless fading channels via stochastic differential equations: identification and estimation based on noisy measurements

This paper is concerned with modeling and identification of wireless channels using noisy measurements. The models employed are governed by stochastic differential equations (SDEs) in state space form, while the identification method is based on the expectation-maximization (EM) algorithm and Kalman filtering. The algorithm is tested against real channel measurements. The results presented include state space models for the channels, estimates of inphase and quadrature components, and estimates of the corresponding Doppler power spectral densities (DPSDs), from sample noisy measurements. Based on the available measurements, it is concluded that state space models of order two are sufficient for wireless flat fading channel characterization.     

油田放射性作业人员外周血淋巴细胞染色体畸变的观察

本文调查了油田212例受γ射线和中子混合辐射照射的作业人员和30例正常人的外周血淋巴细胞染色体畸变。作业人员受γ射线照射的人均年受照剂量为1.28mGy。调查结果表明,放射性测井人员与正常人相比染色体畸变率有显著差异。     

收尽铁路油槽车底油的措施

介绍了造成铁路油槽车底油收不尽的原因，一是节约意识差；二是设备设施陈旧或维护不够；三是操作不当。提出了增强节约意识，挖掘设备潜力，采用合理的吸油方法的对策。     

水库周边违建问题清查整治中的依法行政与权利救济

针对临近水库的别墅等建筑物的清查整治,在实体层面,尤其对于五证齐全的建筑物,如何定性为违建需要慎重把握,对水库管理范围的界定是一个重点问题;在程序层面,应避免执法中因急于求成而催生的程序违法.强拆行为会产生重大损失,涉及多方主体和多重法律关系,应理清其中各方的法律责任,妥善解决纠纷.     

A recognition method of vibration parameter image based on improved immune negative selection algorithm for rotating machinery

To overcome the limitations of traditional monitoring methods, based on vibration parameter image of rotating machinery, this paper presents an abnormality online monitoring method suitable for rotating machinery using the negative selection mechanism of biology immune system. This method uses techniques of biology clone and learning mechanism to improve the negative selection algorithm to generate detectors possessing different monitoring radius, covers the abnormality space effectively, and avoids such problems as the low efficiency of generating detectors, etc. The result of an example applying the presented monitoring method shows that this method can solve the difficulty of obtaining fault samples preferably and extract the turbine state character effectively, it also can detect abnormality by causing various fault of the turbine and obtain the degree of abnormality accurately. The exact monitoring precision of abnormality indicates that this method is feasible and has better on-line quality, accuracy and robustness.     

EL-CID电磁铁心故障检测试验的应用研究

为了检验发电机定子铁心质量,在制造过程中和安装现场,对发电机定子铁心进行试验是必不可少的.目前国内针对定子铁心更多地是采用常规试验方法,但是常规铁损试验所需的设备容量大、试验线路复杂,而且经济性较差、效率低下.而采用电磁定子铁芯故障探测仪(EL-CID)铁心试验只需提供约4％的额定磁通量,即可完成对铁心故障的诊断,其所需的励磁电源容量较小且容易配备和携带.为了更好地利用EL-CID检测方式进行铁心质量的判定,本文通过模拟多种故障状况下的试验,论证了EL-CID的使用条件和影响因素,为实际工作中EL-CID的应用提供更好的参考依据.     

Proximity-Induced Fully Ferromagnetic Order with Eightfold Magnetic Anisotropy in Heavy Transition Metal Oxide CaRuO3

Ferromagnetic materials with a strong spin-orbit coupling (SOC) have attracted much attention in recent years because of their exotic properties and potential applications in energy-efficient spintronics. However, such materials are scarce in nature. Here, a proximity-induced paramagnetic to ferromagnetic transition for the heavy transition metal oxide CaRuO₃ in (001)-(LaMnO₃/CaRuO₃) superlattices is reported. Anomalous Hall effect is observed in the temperature range up to 180 K. Maximal anomalous Hall conductivity and anomalous Hall angle are as large as ∼15 Ω⁻¹ cm⁻¹ and ∼0.93%, respectively, by one to two orders of magnitude larger than those of the typical 3d ferromagnetic oxides such as La_0.67Sr_0.33MnO₃. Density functional theory calculations indicate the existence of avoid band crossings in the electronic band structure of the ferromagnetic CRO layer, which enhances Berry curvature thus strong anomalous Hall effects. Further evidences from polarized neutron reflectometry show that the CaRuO₃ layers are in a fully ferromagnetic state (∼0.8 μ_B/Ru), in sharp contrast to the proximity-induced canted antiferromagnetic state in 5d oxides SrIrO₃ and CaIrO₃ (∼0.1 μ_B/Ir). More than that, the magnetic anisotropy of the (001)-(LaMnO₃/CaRuO₃) superlattices is eightfold symmetric, showing potential applications in the technology of multistate data storage.     

Exploring Statistical Arbitrage Opportunities Using Machine Learning Strategy

Computational Economics - Arbitrage opportunity exploration is important to ensure the profitability of statistical arbitrage. Prior studies that concentrate on cointegration model and other...     

网络图形最短路径算法分析与研究

着重对求网络图上每一对节点之间最短路径的矩阵算法及Floyed算法进行分析与比较,详述它们的功能、原理及异同点,以求在实际应用中合理选择恰当的算法。