Aromatic nitrations by mixed acid. Slow liquid-liquid reaction regime

Aromatic nitrations by mixed acid have been selected as a specific case of a heterogeneous liquid-liquid reaction. An extensive experimental programme has been followed using adiabatic and heat-flow calorimetry and pilot reactor experiments, supported by chemical analysis. A series of nitration experiments has been carried out to study the influences of different initial and operating conditions such as temperature, stirring speed and sulphuric acid concentration. In parallel, a mathematical model to predict the overall conversion rate has been developed. In this paper the mathematical modelling and the implementation and experimental validation for benzene, toluene and chlorobenzene mononitration in the kinetic control regime (slow liquid-liquid reaction) are presented and discussed.     

新取代苯基荧光酮试剂的合成及其性质的研究Ⅱ．新型取代苯基荧光酮与金属离子显色反应的研究

研究了３，５－二溴－４－氨基苯基荧光酮、３，５－二溴－４－偶氮变色酸等８种苯基荧光酮在酸性介质中与高价金属离子Ｚｒ（Ⅳ）、Ｍｏ（Ⅵ）、Ｗ（Ⅵ）、Ａｌ（Ⅲ）、Ｇａ（Ⅲ）等的显色反应。３，５－位二溴取代的试剂的灵敏度高于未取代的灵敏度，摩尔吸光系数绝大多数在１０５Ｌ·ｍｏｌ－１·ｃｍ－１以上。     

Separate assessment of porosity and uncombined carbon in cemented carbides

Porosity and uncombined carbon in cemented carbides are traditionally assessed by comparison to standardized microstructure charts, such as those in ISO 4505-1978. To improve the accuracy in the characterization a fully automatic image analysis procedure has been developed. The analysis is performed using light optical microscopy on unetched polished specimens. The implemented algorithm separates uncombined carbon, C-defects, from pores, A- and B-defects. Pores are approximately distributed in a random way in the structure. Uncombined carbon is on the other hand precipitated into clusters of carbon particles. This difference is together with defect size used as a base for the separation. Small defects situated close together are classified as C-defects, small isolated defects as A-pores and large defects as B-pores. Pores are found to be more round than the somewhat elongated C-defects. The difference in shape is significant and can also be used as a separation criterion.

Image analysis is used to quantitatively characterise the ISO 4505-1978 standard charts with respect to volume fraction, number density and size distribution of defects. The results are compared to measured distributions for true microstructures.     

Analysis of thin walled structures using the boundary element method

In this article the direct boundary element formulations of stretching and bending plate problems are combined together to solve thin walled structures and other similar frames. The final system is obtained by assuming each individual plane structural element as a subregion. After the necessary transforms of these equations they can be combined together taking into account the displacement compatibility and equilibrium conditions.     

Depth of intergranular oxygen diffusion during environment-dependent fatigue crack growth in alloy 718

The elevated-temperture fatigue crack growth behavior in alloy 718, when subjected to a loading frequency lower than the transitional frequency of this alloy, is viewed as fully environment dependent. In this process, the crack growth increment per loading cycle is assumed to be equal to the intergranular oxygen diffusion depth at the crack tip during the cycle effective oxidation time. In order to identify the trend of this diffusion depth an experimental program was carried out on compact tension specimens made of alloy 718 at 650 °C in which fatigue crack growth measurements were made for cyclic load conditions with and without hold time periods at minimum load level. This work resulted in establishing a relationship correlating the intergranular oxygen diffusion depth and the value of the stress intensity factor range ΔK. This relationship, when integrated over the cycle effective oxidation time, results in a closed-form solution describing the environment-dependent fatigue crack growth rate. A comparison is made between the results of this solution when applied to different loading frequencies and the corresponding experimental results. This comparison shows good agreement between the two sets of results. Furthermore, by combining the parabolic rate law of diffusion and the equation for the intergranular oxygen diffusion depth, an explicit expression for the oxygen diffusivity of grain boundaries is derived. It is found that this diffusivity is both a ΔK- and a frequency-dependent parameter.     

Cost Effective VLSI Architectures for Full-Search Block-Matching Motion Estimation Algorithm

In this paper, we present efficient VLSI architectures for full-search block-matching motion estimation (BMME) algorithm. Given a search range, we partition it into sub-search arrays called tiles. By fully exploiting data dependency within a tile, efficient VLSI architectures can be obtained. Using the proposed VLSI architectures, all the block-matchings in a tile can be processed in parallel. All the tiles within a search range can be processed serially or concurrently depending on various requirements. With the consideration of processing speed, hardware cost, and I/O bandwidth, the optimal tile size for a specific video application is analyzed. By partitioning a search range into tiles with appropriate size, flexible VLSI designs with different throughput can be obtained. In this way, cost effective VLSI designs for a wide range of video applications, from H.261 to HDTV, can be achieved.     

一种实验炼钢渣的穆斯堡尔谱研究

一种实验炼钢渣不同炉次样品的室温透射穆斯堡尔谱由两组裂距较大的四极分裂双峰和一组裂距较小的双峰组成，它们分别相应于具有不同微观环境的Ｆｅ＾２＋和Ｆｅ＾３＋。参照文献中已知ＦｅｘＯ的穆斯堡尔谱数据，可确定该渣中的主要含铁相为ＦｅｘＯ。Ｘ射线衍射相分析给出相同的结果。按亚谱的面积比计算出Ｆｅ＾２＋和Ｆｅ＾３＋的相对含量分别为８５％和１５％左右。进一步选取与样品晶体结构相联系的原子簇模型。用ＭＳ－Ｘａ方     

Effect of Bi and Sr concentrations on the formation of the 2223 phase in Bi-Pb-Sb-Sr-Ca-Cu-O materials, obtained under different conditions of thermal treatment

The superconducting properties and the phase and chemical composition of Bi _x Pb_0.3Sb_0.1Sr _y Ca₂Cu₃O_z (x=1.5, 1.6, and 1.7;y=1.9, 2.0, and 2.1) materials synthesized by one-step and multistep thermal treatments have been investigated. The multistep annealing between 825–875°C promotes the 2223 phase. The change of Bi concentration has little effect on the 2223 phase formation, regardless of the kind of thermal treatment used, but increasing the Sr concentration (y> 2) strongly inhibits this phase. It has also been established that the loss of Pb after synthesis depends on the initial Bi concentration. The loss of Pb decreases when the initial Bi content is lower.     

Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.