In situ polymerization and characterization of polyester‐based polyurethane/nano‐silica composites

Polyester‐based polyurethane/nano‐silica composites were obtained via in situ polymerization and investigated by Fourier‐transform infrared spectroscopy (FTIR), or FTIR coupled with attenuated total reflectance (FTIR‐ATR), Transmission electron microscopy (TEM), atomic force microscopy (AFM), an Instron testing machine, dynamic mechanical analysis (DMA) and ultraviolet‐visible spectrophotometry (UV‐vis). FTIR analysis showed that in situ polymerization provoked some chemical reactions between polyester molecules and nano‐silica particles. FTIR‐ATR, TEM and AFM analyses showed that both surface and interface contained nano‐silica particles. Instron testing and DMA data showed that introducing nano‐silica particles into polyurethane enhanced the hardness, glass temperature and adhesion strength of polyurethane to the substrate, but also increased the resin viscosity. UV‐vis spectrophotometry showed that nano‐silica obtained by the fumed method did not shield UV radiation in polyurethane films. Copyright © 2003 Society of Chemical Industry     

Research advances in cognitive ultra wide band radio and their application to sensor networks

The paper illustrates the novel concept of Cognitive UWB Radio, a wireless system based on UWB transmission able to self-adapt to the characteristics of the surrounding environment. First, salient features of UWB transmission are reviewed, and then, application of UWB characteristics to the problem of cognitive radio systems is discussed. Current ongoing studies and achieved results on a possible physical layer based on Prolate Spheroidal Wave Functions and consistent with the Cognitive UWB Radio paradigm are presented and analyzed, and their application to the sensor network scenario is discussed.     

On the relationship between parity space and approaches to fault detection

Parity space approach and H₂ approach are two important fault detection approaches. This paper studies the relationship between these two approaches, which reveals frequency domain characteristics of the optimal solution of the parity space approach on the one side and provides a numerical solution of the H₂-optimal design of residual generators on the other side.     

土工植草网在城防工程中的应用

文章以双辽市城防工程建设为例,介绍土工植草网新材料在护坡工程中的应用方法.     

Alleviation Effect of Lanthanum on Cadmium Stress in Seedling Hydroponic Culture of Kidney Bean and Corn

Since1970s,rare earths(RE)have been exten-sively used as micro-fertilizers for crops in China.Ithas already been proved that REcani mprove the pro-duction and quality of crops.However,there havebeen a fewinvestigations about using RE as regulatorin pollution ecology.For example,An et al[1]studiedthe effects of O3on wheat growth and the protectiveeffect of RE.Yan and Zhou et al[2,3]discussed theprotective effect of RE on plants under acid rainstress.Jia et al[4]and Hu et al[5]reported th…     

梯恩梯-吉纳、地恩梯-太安装药体系自旋爆轰特性的研究

本文研究了梯恩梯-吉纳(TNT-DINA)和地恩梯-太安(DNT-PETN)体系的自旋爆轰现象,爆轰波是以低频脉冲方式传播.这些体系具有的爆速、爆热分别为DJ=7.3～7.4km/s和Qv=(5.40±0.01)MJ/kg.不同组成的爆速和爆压PJ通过SW程序计算.用扩散区的爆压P3和爆温T3来评估爆轰波的衰减和重新点火.敏化剂含量相同,梯恩梯-黑索金(TNT-RDX)体系的爆压PJ大于TNT-DINA的爆压,TNT-RDX体系的温度T3比TNT-DINA高60～100K.计算值与实验结果吻合较好.     

25mm厚钢板产生层间撕裂的原因和防治

层间撕裂并非是厚板独有的质量问题 ,结合工程实例 ,分析 2 5mm厚低合金钢板产生层间撕裂的原因。通过对钢材的超声波探伤检测、化学成分分析和Z向性能检测 ,指出层间撕裂主要与节点设计不当和钢材内非金属夹杂物偏析、分层有关 ,并提出了预防措施。对产生裂纹的构件视严重情况提出了不同的修补处理方法     

A subunit interaction in chloroplast ATP synthase determined by genetic complementation between chloroplast and bacterial ATP synthase genes

F1F0-ATP synthases utilize protein conformational changes induced by a transmembrane proton gradient to synthesize ATP. The allosteric cooperativity of these multisubunit enzymes presumably requires numerous protein-protein interactions within the enzyme complex. To correlate known in vitro changes in subunit structure with in vivo allosteric interactions, we introduced the beta subunit of spinach chloroplast coupling factor 1 ATP into a bacterial F1 ATP synthase. A cloned atpB gene, encoding the complete chloroplast beta subunit, complemented a chromosomal deletion of the cognate uncD gene in Escherichia coli and was incorporated into a functional hybrid F1 ATP synthase. The cysteine residue at position 63 in chloroplast beta is known to be located at the interface between alpha and beta subunits and to be conformationally coupled, in vitro, to the nucleotide binding site > 40 A away. Enlarging the side chain of chloroplast coupling factor 1 beta residue 63 from Cys to Trp blocked ATP synthesis in vivo without significantly impairing ATPase activity or ADP binding in vitro. The in vivo coupling of nucleotide binding at catalytic sites to transmembrane proton movement may thus involve an interaction, via conformational changes, between the amino-terminal domains of the alpha and beta subunits.     

以杂多酸为催化剂合成乙二醇-乙醚的研究

研究了杂多酸催化无水乙醇和环氧乙烷(EO)制备乙醇乙醚的醚化反应,考察了不同种类的杂多酸以及醚化反应工艺条件对反应活性和选择性的影响.结果表明,PW_(12)催化剂的反应活性高、反应温度低、选择性好,当用PW_(12)作催化剂,乙醇与环氧化乙烷之比为3.0(mol),反应温度45℃,反应时间1h时,转化率和选择性均超过97%.     

应用均匀设计法研究安息香缩合工艺

利用均匀设计法通过SPSS10.0计算机软件研究了反应条件对安息香缩合的影响。从而获得优化的工艺条件，与正交试验相比，该法试验次数少。工作效率高，并且便于分析各种因素的影响。