丙烯酸钠与N-乙烯基吡咯烷酮共聚物的制备

通过 NH ₃ · H ₂ O/ H ₂ O ₂ 氧化还原引发体系引发丙烯酸钠( AANa)与乙烯基吡咯烷酮(NVP)共聚,制备了PAANa - co - PVP共聚物。通过FTIR对共聚产物进行了结构表征。在元素分析表征的基础上,采用FR法, KT法和YBR法对采用NH ₃ ·H ₂ O/ H ₂ O ₂ 引发时,AANa与 NVP共聚的竞聚率( r ₁,r ₂)进行了计算,其值分别为3 .296,0 .808。采用MTT法对所制备产物的体外细胞毒性进行了研究,结果表明所制备的产物具有良好的生物相容性。     

Nitration of Wood Cellulose in HNO_3/Organic Solvent Medium

Wood celluloseis a mainraw material for prepar-ing NC[1],there are different reactivities of the threehydroxyl groups in an anhydrogluose unit,in differ-ent positions along molecular chain and within differ-ent points of cellulose samples[2].Allowance shouldbe madefor the existenceincellulose of tworegions ofunequal accessibility to reactants.The“amorphous”regionis more or less freely accessible to all the con-stituents of the nitrating bath,and hydroxyl groupshere are esterified without any…     

弹引系统动态特性有限元分析

提出一种基于有限元分析的弹引系统动态特性计算方法.采用预紧单元对弹体和引信的耦合部位进行网格划分,对不同拧紧力时弹引系统的动态特性进行模拟.在相同的激励环境下,对某弹引系统进行了有限元数值计算和实测锤击试验,试验结果表明,所采用的有限元分析方法精度较高.     

Mechanism Modeling and Simulation Based on Dimensional Deviation

To analyze the effects on motion characteristics of mechanisms of dimensional variations,a study on random dimensional deviation generation techniques for 3D models on the basis of the present mechanical modeling software was carried out,which utilized the redeveloped interfaces provided by the modeling software to develop a random dimensional deviation generation system with certain probability distribution characteristics. This system has been used to perform modeling and simulation of the specific mechanical time delayed mechanism under multiple deviation varieties,simulation results indicate the dynamic characteristics of the mechanism are influenced significantly by the dimensional deviation in the tolerance distribution range,which should be emphasized in the design.     

Pretreatment of Corn Stalk by Steam Explosion

A steam explosion pretreatment,which is one of the best ways of pretreating plant stalk,is applied at various severities to corn stalk.It could effectively modify the super-molecular structure of com stalk and defibrat-ing corn stalk into individual components.The relationship between yield of reducing sugar and the operating con-ditions,including temperature,pressure of steam explosion pretreatment and acidity,is also established.Experi-mental results prove that the steam explosion substantially increases the yidld of reducing sugar,and the optimal condition for steam explosion is as follows;the pressure is 2.0MPa,the pressure-retaining time 300s,the initial acid concentration 1%and the acid treatment time 24h.     

无线网络中的攻击检测技术研究

分析了无线网络的脆弱性、需要进行攻击检测的原因以及不能直接应用目前已有方法的原因，并提出了无线网络中的攻击检测与应用机制。     

NC/NG与ADN的相互作用

用高压差示扫描量热法(PDSC),热重-微商热重法(TG-DTG),研究了双基粘合剂(NC/NG体系)与二硝酰胺铵(ADN)之间的相互作用.结果表明,(NC/NG)/ADN体系中NG的分解峰由NC/NG中的207.0 ℃提前至159.8 ℃,在高压下该分解峰温提前至153.6 ℃.NC/ADN的分解峰温比NG/ADN提前了4.8 ℃,而且大部分的ADN没有被NG加速而提前分解,表明NC对ADN的作用比NG更强烈.此外,还用真空安定性试验(VST)评价了NC/NG与ADN的相容性,混合体系的净增放气量大于11 mL,属于严重不相容,证明在90 ℃下NC/NG与ADN之间也存在强烈的相互作用.     

引信磁通门近感探头的理论及实验

本文对磁通门磁强计式探头用于引信进行串联装药战斗部的近感起爆控制作了理论、试验及初步工程设计的研究探讨。主要对环形磁芯近感探头的灵敏度进行了分析计算,在满足灵敏度要求的前提下按紧凑、小体积原则设计了探头,通过静态标定,灵敏度达到1.16V/Oe。对真实坦克目标进行了静态磁场测量,为得到动态时近感探头的输出特性。设计并进行了动态模拟试验,试验结果为引信的磁探头进一步详细设计提供了可靠的试验依据。为进行探头与引信功能电路的联调试验,设计并制做了串联装药延时起爆引信电路。     

可降解高分子量聚癸二酸己二醇酯的合成及表征

以癸二酸和己二醇为原料,以十氢萘为溶荆,进行直接聚合,合成了高分子量聚癸二酸己二醇酯,产率达到96％．用FT-IR和^1H-NMR对其蛄构进行表征,GPC测得其数均分子量达到45809．DSC测得其熔点为76℃,拉伸强度为23．5MPa,断裂伸长率为935．0％。     

含六硝基六氮杂异伍尔兹烷的NEPE因体推进剂能量水平分析

利用怀特最小自由能法和CAD软件对纯NEPE/CL 2 0与NEPE/HMX进行对比 ,其能量特性计算结果表明 ,当体系固含量为 73%～ 80 %时 ,含CL 2 0和HMX粘合剂体系比冲分别为 2 5 6 1.1N·s/kg、2 4 6 2 .1N·s/kg,前者比后者提高了近4 % ,而体系密度比冲的增幅相差更大 ,前者比后者提高 7%以上 ,这对提高战术导弹射程有利。而从燃烧产物对比分析来看 ,CL 2 0在固体推进剂尤其是在高能低特征信号推进剂中很有应用价值