纳米稀土复合固体超强酸催化合成乙酸苄酯

采用共沉淀法制备了纳米稀土复合固体超强酸SO4^2-／ZrO2-2％Nd2O3催化剂，电镜分析表明，催化剂颗粒直径在25nm左右，比表面积测定：71．03m^2／g。酸强度-12．70〈Ho〈-11．99。并对合成乙酸苄酯的最佳反应条件进行了研究。研究表明：当苯甲醇与乙酸的物质的量比为1：2，反应时间为5h，反应温度为120℃，催化剂用量为6％苯甲醇的质量时，酯化率可达92．04％。研究发现，该催化剂可重复使用并可活化再生。     

金纳米线拉伸行为的分子动力学模拟

采用分子动力学方法模拟了不同截面尺寸金纳米线的拉伸力学行为。计算结果表明:相同长度的金纳米线弹性模量随着截面尺寸的减小而减小,而其屈服强度随着截面尺寸的减小而增大,并且发生屈服推迟现象。应力—应变曲线与形变过程相对应。在弹性变形阶段,纳米线形变不显著;随着应变量的增加,发现纳米线出现大量堆垛层错。     

Analysis of junction temperatures in high-power GaN-based LEDs

We presented the analysis of the incomplete conduction in bonding medium in high power GaN-based light-emitting diode (LED) packages. A numerical study was carried out with parametric model to understand the junction temperature variation due to bonding medium defects. Transient thermal measurement was performed to evaluate LED’s junction temperature. Thermal resistance from chip to lead frame was 20 K/W in our sample LED. It was suggested that only 60% of the surface area of the bonding medium was involved...     

Influence of Zn ion implantation on structures and field emission properties of multi-walled carbon nanotube arrays

The structures and field emission properties of multi-walled carbon nanotube arrays implanted with Zn+ by MEVVA ion implanter have been investigated.The results revealed that Zn+implantation induced structural damage and that the top of carbon nanotubes with multi-layered graphite structure were transformed into carbon nanowires with amorphous structure.Meanwhile,C:Zn solid solution was synthesized after Zn+ implantation.The turn-on field and threshold field were 0.80 and 1.31 V/μm,respectively for original...     

Alekseevskii-Tate revisited:An extension to the modified hydrodynamic theory of long rod penetration

The modified hydrodynamic theory of long rod penetration into semi-infinite targets was established independently by Alek-seevskii and Tate over forty years ago and since then many investigators contributed much to the development of the high speed penetration mechanics.However,in all the models proposed so far,the target resistance Rt is not well defined and usually determined by adjusting it until the predicted depth of penetration comes to an agreement with experimental data.In this paper,assumptions are...     

一种高效的网格资源监测算法ACTC的改进算法

资源监控是网格计算的关键组成部分。资源监控算法既要保证网格系统中资源信息高保真度又要考虑资源信息在网络传输中的负担最低。ACTC算法就是为实现以上目的而被提出,但是算法中对资源信息更新量的动态门槛值(d_threshold)计算方式不合理,有可能导致算法演变成低级的单纯依靠时间敏感机制(TSM)来发送资源更新通知,并且算法中遗漏了一些极端情况的考虑。提出了新的d_threshold计算公式和限制条件,进行性能改进和完善,并对改进前后两算法进行实验对比。实验表明,改进后算法提高了资源信息准确性,并使监控系统     

Monitoring slope deformation using a 3-D laser image scanning system:a case study

An ILRIS-36D 3-D laser image scanning system was used to monitor the Anjialing strip mine slope on Pingshuo in Shanxi province.The basic working principles,performance indexes,features and data collection and processing methods are illustrated.The point cloud results are analyzed in detail.The rescale range analysis method was used to analyze the deformation characteristics of the slope.The results show that the trend of slope displacement is stable and that the degree of landslide danger is low.This work indicates that 3-D laser image scanning can supply multi-parameter,high precision real time data over long distances.These data can be used to study the distortion of the slope quickly and accurately.     

中国银行利率风险实证分析

随着中国融入世界的步伐加快,加入WTO中要求中国放开金融市场的开放程度,利率管制的放松也将逐步的实行,利率风险日益成为中国商业银行面临的重要风险之一。本文从理论和实践角度对中国商业银行的利率风险进行了分析和研究,剖析中国商业银行存在的诸多障碍,指出了商业银行风险管理中存在的问题,并提出中国商业银行利率风险管理建议。     

2,4,6-三甲氧基脱氧安息香的合成新方法

以1,3,5-三甲氧基苯替代间苯三酚为原料和苯乙腈反应,用甲苯替代不易回收且安全性较差的乙醚为溶剂,通过Hoesch反应制备得到2,4,6-三甲氧基脱氧安息香,产品经HNMR和MS定性.因醚键的保护作用降低了羟基的反应活性,抑制了副反应,使得方法改进后,Hoesch反应的单步收率提高到81.3%.考察了原料配比、反应时间及ZnCl2用量对反应的影响,得到了较佳的反应条件为1,3,5-三甲氧基苯与苯乙腈的摩尔配比为1.2∶1,反应时间为28 h,ZnCl2与苯乙腈的摩尔配比为0.3∶1.     

韧性断裂准则在板料成形中应用研究进展

对板料成形中的成形极限应力图、最大变薄率、成形极限图以及韧性断裂准则等预测成形极限的方法进行了综述和分析,提出了利用韧性断裂准则能够较好地预测塑性差的板料成形极限,而且还能考虑应变路径的变化.利用有限元方法模拟时,韧性断裂准则既可以运用到完全耦合的弹塑性损伤模型的增量方法中,也可以运用到一步有限元逆算法中.指出了为准确地预测成形极限,除了提高有限元模拟精度外,应找到一种本质地反映材料性能的准则.