超大型材生产经验

对几种超大型材挤压生产的工艺技术、工模具设计、挤压参数控制等过程进行了分析，通过例子总结了挤压生产超大型材的经验及关键技术。     

减压渣油与FCC油浆共炭化的化学组成变化

考察了齐鲁石化胜利炼油厂催化油浆（FCC）和胜利减压渣油（VR）在490℃，0.8MPa下不同混合比的原料和不同反应时间的中间产物的HS、TS、PS、P及其1h中间产物的HS和TS的^1H-NMR。数据结果反映了体系的反应速度。掺入FCC油浆抑制了VR的反应活性，降低了体系的反应速度，增加了基质的溶解度；1h中间产物的组成结构更接近于原料及反应体系的反应性和基质的溶解度；1h中间产物的芳香度越高，取代基越少，侧链越短，基质对VR中的活性反应组分在炭化早期生成的高度缩合物质的溶解度越大。     

探讨缩聚催化剂对聚酯切片质量的影响

通过试验，分析比较了江西Sb2O3、南宁Sb2O3和大连Sb(Ac)3三种缩聚催化剂对聚酯切片质量的影响。试验结果表明，Sb(Ac)3是优良的缩聚催化剂。     

根据人工裂缝特征优化油井压裂地质方案

近年来大庆油田外围地区地质储量得到动用，每年依靠压裂投产的井逐渐增多，由达西定律可知，在油层厚度一定的情况下，措施井的渗透率是影响产量的关键参数，油井压裂可以改善油井周围地层渗透性，消除近井地带油层污染，从而提高油井产能，而人工压裂的成功与否主要取决于裂缝的导流能力和裂缝的几何形态，为此，根据台105地区地质特征，结合低渗透油田开发实际，本着经济有效的开发原则，从人工裂缝特征，方位对开发效果的影响等方面，论述了优化油井压裂地质方案技术的方法，改善了低渗透油田的开发效果。     

A new efficient method for one‐pot conversions of aryl carboxylic acids into nitriles without solvent

A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry     

天然气长输管道泄漏检测方案对比

大口径、长距离天然气输送管道的泄漏检测和定位技术日益受到人们的重视。总结评价了用于天然气长输管道泄漏检测和安全预警的各种技术方案，讨论了其基本原理、适用范围、技术成熟度、优点和缺点以及工程应用情况；采用灵敏度、定位精度等7项技术指标对各种泄漏检测方法进行了评价和对比。目前，音波泄漏检测技术和分布式光纤泄漏检测技术由于具有诸多方面的优点，是近年来国内外泄漏检测技术研究的重点和热点，这两种技术已初步应用于实际，并取得了良好的效果。重点对这两种泄漏检测技术的原理、适用范围、所能达到的技术指标、优、缺点以及工程案例进行了详细讨论、分析和对比，可为我国天然气长输管道泄漏检测和安全预警系统的开发和研究提供技术依据。     

铁素体球墨铸铁与20钢的闪光对焊

试验使用铁素体球墨铸铁和20钢的实心棒料进行了闪光对焊，通过改变次级电压4～8级，通电时间3～5s，观察其焊接接头组织的变化并测定其抗拉强度。结果表明，接头由三个区组成；当通电时间一定时，抗拉强度随次级电压的升高先减小后增大；当次级电压一定时，抗拉强度随通电时间的增加而增大。在次级电压为8级、通电时间为5s时，抗拉强度达最大值，为370．8MPa，是20钢母材的90.4％，是球墨铸铁母材的83.7％。     

Modeling for local dynamic behaviors of phenol biodegradation in bubble columns

A coupled three-dimensional (3-D) model, combining hydrodynamics with biochemical reactions, was developed to simulate the local transient flow patterns and the dynamic behaviors of cell growth and phenol biodegradation by yeast Candida tropicalis in the bubble-column bioreactor, using the computational fluid dynamic (CFD) method. In order to validate this proposed model effectively, the validation of the local hydrodynamic characteristics of the gas-mineral salt solution (gas-liquid) two-phase system, with the phenol concentration of 1200 mg/L, and with the absence of cells, was performed in a square-sectioned bubble column bioreactor using the LDA system and conductivity probe. Furthermore, the validation of phenol biodegradation behaviors by yeast Candida tropicalis at different initial concentrations of phenol and cell was also carried out in the above bubble-column bioreactor. The results indicated that the model simulations had a satisfying agreement with the experimental data. Finally, the local instantaneous flow and phenol biodegradation features including gas holdup, gas velocity, liquid velocity, cell concentration and phenol concentration inside the bioreactor were successfully predicted in different-scale bubble columns by the proposed model. © 2006 American Institute of Chemical Engineers AIChE J, 2006     

Hydrothermal Reaction Mechanism and Pathway for the Formation of K2Ti6O13 Nanowires

Calculations and detailed first principle and thermodynamic analyses have been performed to understand the formation mechanism of K₂Ti₆O₁₃ nanowires (NWs) by a hydrothermal reaction between bulk Na₂Ti₃O₇ crystals and a KOH solution. It is found that direct ion exchange between K⁺ and Na⁺ plus H⁺ interactions with [TiO₆] octahedra in Na₂Ti₃O₇ promote the formation of an intermediate H₂K₂Ti₆O₁₄ phase. The large lattice mismatch between this intermediate phase and the bulk Na₂Ti₃O₇ structure, and the large energy reduction associated with the formation of this intermediate phase, drive the splitting of the bulk crystal into H₂K₂Ti₆O₁₄ NWs. However, these NWs are not stable because of large [TiO₆] octahedra distortion and are subject to a dehydration process, which results in uniform K₂Ti₆O₁₃ NWs with narrowly distributed diameters of around 10 nm.     

Diameter NASREQ协议在卫星移动通信系统中的应用研究

如何对接入网络的用户进行身份认证、授予相应权限并进行计费,是卫星移动通信系统网络管理需解决的重要问题。简要介绍认证、授权、计费(AAA)的基本概念,分析Diameter协议框架、协议原理以及协议应用于网络接入的特点。阐述协议中包含的各种应用,给出Diameter NASREQ应用的一种系统模型。重点研究Diameter NASREQ协议在卫星移动通信系统中的应用,详述应用中客户机和服务器中各模块的功能和工作原理。通过分析,说明该应用的可行性及有效性。