Computer simulation of the effective double layer occurring on a catalyst surface under electro-chemical promotion conditions

In this work, the structural and energetic properties of two typical catalytic surfaces, Na/Pt(111) and O/Pt(111), are studied by means of quantum mechanical calculations and Monte Carlo Grand Canonical simulations. The simulations were performed with electrostatic potentials at different truncation schemes. In order to elucidate the modification of catalyst surfaces produced by the backspillover of ionic species onto Pt(111), the electrostatic field at the interface due to the electric double layer was also analyzed.     

Potential applications of poly(vinyl alcohol)‐congo red aqueous solutions and hydrogels as liquids for hydraulic fracturing

The authors report on the viscoelastic characterization of guar hydrogels obtained through complexation reactions with borax ions. These gels are compared with hydrogels obtained from poly(vinyl alcohol) of different degree of hydrolysis through complexation reactions with congo red. The effect of the degree of hydrolysis and both, the concentration of PVA and the concentration of congo red, on the viscoelastic properties of the hydrogels is analyzed. The potential use of the PVA‐based hydrogels as hydraulic fracturing liquids is discussed in relation to the commonly used fracturing liquid based on the guar–borax system. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

On copulas, quasicopulas and fuzzy logic

We investigate (quasi)copulas as possible truth functions of fuzzy conjunction which is not necessarily associative and present some axiom systems for such fuzzy logics. In particular, we study an expansion of Łukasiewicz (infinite valued propositional) logic by a new connective interpreted as an arbitrary quasicopula (and also by a new connective interpreted as the residuum of the copula). Main results concern standard completeness.     

Lipid damage in farmed rainbow trout (Oncorhynchus mykiss) after slaughtering and chilled storage

The flow ice system including ozone (OFI condition) was tested for slaughtering and storage (up to 16 days) of farmed rainbow trout (Oncorhynchus mykiss). Lipid damage analyses were carried out and compared to sensory acceptance and instrumental colour changes. Comparison to individuals processed with the flow ice system in the absence of ozone (FI condition) was undertaken. Rainbow trout slaughtered and chilled under FI and OFI conditions showed a low lipid damage development, according to lipid oxidation and hydrolysis events and lipid composition (polyunsaturated fatty acids, phospholipids and endogenous antioxidants) changes. Additionally, both icing conditions led to largely good quality and shelf life times and to the absence of changes in colour properties. It is concluded that flow ice as such, or including the presence of ozone, can be considered as ideal strategy to be employed as slaughtering and storage system during the commercialisation of the actual farmed species. The ozone presence has shown some profitable effects as leading to an extended shelf life time by quality retention of several sensory parameters; in contrast, some negligible negative effects could be observed on the secondary and tertiary lipid oxidation development. However, the oxidation values reached by individuals kept under OFI conditions cannot be considered as particularly high.     

Karyotype description of Pomacea patula catemacensis (Caenogastropoda, Ampullariidae), with an assessment of the taxonomic status of Pomacea patula.

Mitotic chromosomes of the freshwater snail Pomacea patula catemacensis (Baker 1922) were analyzed on gill tissue of specimens from the type locality (Lake Catemaco, Mexico). The diploid number of chromosomes is 2n = 26, including nine metacentric and four submetacentric pairs; therefore, the fundamental number is FN = 52, No sex chromosomes could be identified. The same chromosome number and morphology were already reported for P. flagellata, i.e., the other species of the genus living in Mexico. The basic haploid number for family Ampullariidae was reported to be n = 14 in the literature; so, its reduction to n = 13 is probably an apomorphy of the Mexican Pomacea snails. Lanistes bolteni, from Egypt, also shows n = 13, but its karyotype is much more asymmetrical, and seems to have evolved independently from P. flagellata and P. patula catemacensis. The nominotypical subspecies, P. patula patula (Reeve 1856), is a poorly known taxon, whose original locality is unknown. A taxonomical account is presented here, and a Mexican origin postulated as the most parsimonious hypothesis.     

MTCLAB: A MATLAB®-based program for traveltime quality analysis and pre-inversion velocity tuning in 2D transmission tomography

A MATLAB^®-based computer code that analyses the traveltime distribution and performs quality analysis at the pre-inversion stage for 2D transmission experiments is presented. The core tools of this approach are the so-called mean traveltime curves. For any general recording geometry, the user may select any pair of subsets of contiguous sources and receivers. The portion of the domain swept by the implied rays defines a zone of analysis, and for each source (receiver) the outcoming (incoming) ray fan is named a source (receiver) gather. The empirical mean traveltime curves are constructed, for each zone, by assigning the average and the standard deviation of the traveltimes in the gathers to the positions of the sources (receivers).The theoretical expressions assume isotropic homogeneous velocity inside each zone. The empirical counterparts use the observed traveltimes and make no assumptions. Isotropic velocity in each zone is inferred by least-squares fitting of the empirical mean traveltime curves. The user may refine the analysis considering different zones (multi-zone analysis). Initially the whole domain is modelled as a single zone. The procedure compares empirical versus theoretical curves. In addition, residuals can be plotted using source–receiver positions as plane coordinates. The results are used to unravel the possible presence of anomalous gathers, heterogeneities, anisotropies, etc. Depending on the kind of anomalies, velocity estimation and mean time residuals are different in the source and receiver gather curves.This software helps to grasp a better understanding of the data variability before the inversion and provides to the geophysicist an approximate zonal isotropic model and a range of velocity variation that can be used in the inverse problem as a priori information (regularization term). Its use is described through tutorial examples. A guided user interface leads the user through the algorithm steps.     

Balance-dendrogram. A new routine of CoDaPack

A statistical analysis of compositional data based on the Aitchison geometry of the simplex requires an appropriate basis for representing the data. A simple and intuitive way of building such a basis employs a sequential binary partition of the compositional vector. The partition, together with some statistical summaries of the coordinates, or balances, can be represented in a dendrogram-type graph. In this paper we introduce an implementation of this methodology inside CoDaPack, which is freeware. An example with real data illustrates the use of the Balance-Dendrogram routine.     

The myopic intraocular lens in a phakic eye. Initial experience

The very first experiences with implantation of 3 phakic anterior chamber lenses for high myopia correction are presented. After average 4 month follow up good stability and transparation of concave lenses type ZB5M were observed with accurately achieved correction postoperatively.     

Programs of early detection of breast cancer and access of mammography in Spain

BACKGROUND: We studied availability to mammography among Spanish women aged 40 to 70 years, variation in use of the mammography by autonomous community, and the situation and importance of breast cancer screening programs among other factors, in the access to mammography. SUBJECTS AND METHODS: A cross-sectional population survey was conducted in 1994 in a sample of 3,218 women. A questionnaire was used to collect data on the variable access (receipt of at least one mammogram in the last 2 years) as well as different access-related variables. Information on breast cancer screening programs was collected by contacting the responsible institutions. We considered that a program had total coverage if it included all the municipalities in the province and partial if it did not include all municipalities. RESULTS: Twenty-eight percent of women had performed a mammogram. This proportion varied among autonomous communities (AACC) from 11.5 to 73.8%. Breast cancer screening programs existed in 8 AACC. The multivariant analysis revealed an association between access to mammography and the existence of a screening program, especially when the later had total coverage (OR = 7.64; 95% CI = 5.24-11.10). An association was also found between access to mammography and physician-related factors, place of residence and attitudes of women toward mammography. CONCLUSIONS: Less than one third of women aged 40-70 have performed a mammography in the last 2 years, and this proportion varies among AACC. Gynecologist visits and the existence of breast cancer screening programs are fundamental factors in the access to mammography in Spain.