Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

Online and Offline Rotary Regression Analysis of Torque Estimator for Switched Reluctance Motor Drives

A new torque estimator for switched reluctance motor (SRM) drives based on 2-D rotary regression analysis is presented in this paper. The proposed torque estimator is composed of a bicubic regressive polynomial as a function of rotor position and input current. The regressive coefficients can be computed offline or online from the torque characteristics acquired either experimentally or from numerical computation. Furthermore, a torque estimation method by taking mutual coupling into consideration is proposed. It can be seen that the estimated and experimentally obtained self-coupling and mutual-coupling torque characteristics are in good agreement with each other. In addition, the dynamic torque waveforms with and without the mutual coupling, estimated by the proposed estimator, are found to be virtually the same as those obtained from the bicubic spline interpolation for SRM drives with single-pulse voltage, hysteresis current chopping, as well as with voltage pulse width modulation control. The success of all the case studies being reported is a good validation of the usefulness and accuracy of the proposed real-time torque estimator that, as described in this paper, can be used to quickly estimate the instantaneous output torque of SRM drives.     

Effect of vibration condition and inter-particle frictions on the packing of uniform spheres

We present a numerical study of the packing of uniform spheres under three-dimensional vibration using the discrete element method (DEM), focusing on the effects of vibration condition (amplitude and frequency) and inter-particle frictions (sliding and rolling frictions). The results are analysed in terms of packing density, coordination number (CN), radial distribution function (RDF) and pore structure. It is shown that increasing either the vibration amplitude or frequency causes packing density to increase initially to a maximum and then decrease. Both vibration frequency and amplitude should be considered to characterize the effect of vibration process on packing structure. The sliding and rolling frictions between particles can decrease packing density since they dissipate energy, although the effect of rolling friction is less significant. In line with the change of packing density, microstructural properties such as CN, RDF and pore distribution also change: a looser packing often corresponds to smaller CN, less peaked RDF and larger but more widely distributed pores.     

3D velocity from 3D Doppler radial velocity

We present local least squares and regularization frameworks for computing 3D velocity (3D optical flow) from 3D radial velocity measured by a Doppler radar. We demonstrate the performance of our algorithms quantitatively on synthetic radial velocity data and qualitatively on real radial velocity data, obtained from the Doppler radar at Kurnell Radar station, Botany Bay, New South Wales, Australia. Radial velocity can be used to predict the future positions of storms in sequences of Doppler radar datasets.© 2005 Wiley Periodicals, Inc. Int J Imaging Syst Technol, 15, 189–198, 2005     

建筑雷击电位分布模拟软件诞生

由天津城市建设学院联合天津中力防雷技术有限公司共同承担的“建筑物与构筑物雷击电位分布模拟系统开发与应用研究“课题是2D03年正式在建设部立项研究的科技项目．于2005年11月17日通过了建设部科技司委托天津建委组织的专家验收，专家组一致认为该项且研究成果在工程应用领域达到了国内领先水平，具有广泛地应用前景。该项目研制开发出雷击建筑物的计算软件，定量地分析雷击时，在建筑物钢筋网内形成的电位、电流和电磁场分布情况，从而为防雷设计提供了设置防雷装置的设备和依据，为防雷施工检测提出了施工要求、检测依据，并可辅助雷电事故分析。     

中美纳电子技术发展对比研究(续)

3 中美纳米技术经费支持对比 3．1 美国 NNI计划出台之前，美国政府对纳米技术研发的投入力度并不算大，如1997年投入约为1．16亿美元，比日本政府的投入（1．20亿美元）稍低，但也比除日和西欧国家之外的其他国家（包括中国、加拿大、澳大利亚、韩国、新加坡以及前苏联各共和国等）政府投入的总和（约0．71亿美元）高得多：NNI计划出台之后，美国政府对纳米技术研发的投入大幅度增加。2001年，美国政府纳米技术研发投入从2000年的2．70亿美元增加到4．22亿美元，净增1．52亿美元，年增幅达56．3％；2002年度美国政府的纳米技术投入预算为5．189亿美元，比2001年度约增长了23％。这种高增幅在美国政府其他方面的预算中并不多见。     

冰蓄冷系统运行经济性分析

建筑物的空调制冷系统采用蓄冷方式，可以节约运行费用，减少设备容量，转移用电高峰。蓄冷空调系统与常规空调系统相比，在运行的经济性方面有很多优点。因此开发了冰蓄冷系统运行经济性分析计算机软件，应用这套软件对实际工程项目进行分析，计算出各种冰蓄冷系统与相应常规系统的逐时耗电量、电费、全年运行费用和设备容量减少率等，并以图表的方式对两种系统的经济性作出综合的比较，能全面、直观的显示冰蓄冷系统的优点。     

储层压力与天然气分布关系——以鄂北塔巴庙地区上古生界储层为例

通过分析塔巴庙地区储层压力的分布特征，建立了研究区泥岩压实曲线，并对影响和控制该区储层压力的主要因素和机理进行了探讨，对“欠压实”剩余压力、生气增压、抬升引起的降压进行了定量计算。分析结果表明，晚三叠-早白垩世末“欠压实”作用和晚侏罗-早白垩世末烃源岩大量生烃作用使塔巴庙地区上古生界形成异常高压；晚白垩系构造抬升降压，使得现今储层为正常-低异常压力。同时证实了“欠压实”对天然气有压力封盖作用，天然气都分布在最大“欠压实”幅度以下的储层当中。烃源岩生气高峰为晚侏罗-早白垩世末，但天然气大规模运移是在晚白垩世，方向以沿过剩压力梯度降低较快的方向（太原-山西组至下石盒子组）垂向运移，通道主要为裂缝，运移的动力主要为异常高压。由于储层致密，聚集成藏能量有限，造成天然气充注不足、气水分异不好、含气饱和度低。