Model study of IPMC beam electroactive response based on root deformation

Ionic polymer-metal composite (IPMC) is a type of electroactive polymer (EAP). In this paper, based on Nemat-Nasser model, an improved model is developed to explain the initial nonlinear response of electric actuation on the fixed end deformation. Three IPMC strip samples with different surface resistance are chosen for analysis. Further, from simulation and experiment results, it is found that the root deformation made the tip movement of the IPMC strip with little surface resistance, but this effect was less and less when the surface resistance reduced. The calculation results of this model for the fixed end show a more accurate simulation for the actual deformation of IPMC strips.     

一步法制备芳基微孔聚酰亚胺及其性能表征

以均苯四酸二酐和多苯基多异氰酸酯为原料,采用一步合成法,通过浇注发泡成型,限定空间发泡,制备了一种孔径均匀的微孔聚酰亚胺材料。经红外光谱测定,在1 778cm-1、1 723cm-1、1 371cm-1处观察到聚酰亚胺特征峰。扫描电镜照片显示,所得聚酰亚胺微孔材料孔径均匀,闭孔结构,泡孔平均尺寸在0.2～0.3 mm之间,密度为0.4g/cm3。热失重分析结果表明,微孔聚酰亚胺样品的起始分解温度为550℃,热稳定性较好。力学性能测试结果表明,在样品形变量为10%时,抗压强度为6.12MPa。     

不同热边界条件下热管对沥青混凝土换热特性的影响

沥青混凝土在阳光的照射下会迅速升温,影响路面的高温稳定性.热管是一种理想的散热、均热和热能输送元件,可有效降低路面内的升温速率.采用数值模拟方法,建立了沥青混凝土的三维模型,考虑了有、无热管两种情况,对距路面不同深度位置的温度-时间响应特性进行了计算,并分析了路面吸热和放热两种不同热边界条件对换热特性的影响.计算结果表明,在加热过程中,热管会显著降低路表温度,最高降温幅度可达9℃,而且会阻止热量进一步向深层传递;在冷却过程中,热管会加快路表冷却,同时使其周围温度保持较好的均匀度,有助于减小内部应力,提高路面稳定性.     

氮掺杂二氧化钛的制备及可见光催化研究进展

TiO2在紫外光下具有优异的光催化性能，在废水处理、空气净化、抗茵等环保领域有着广泛的应用，但实现其可见光催化一直是研究的难点之一，而氮掺杂TiO2可以实现可见光催化，本文详细介绍了氮掺杂TiO2的制备方法、研究现状和可见光催化的应用情况，并对未来的发展趋势作了预测。     

塑料抗氧剂国外发展近况

本文综述了塑料用抗氧剂的国外发展近况。主要对国外常用受阻酚主抗氧剂的现状、酚类抗氧剂的新品种、辅助抗氧剂亚磷酸酯的新品种、复合抗氧剂的开发情况作了较详细的介绍。     

改性高岭土上甲苯的选择性硝化(IV)

应用Ｍｅｎｋｅ条件，在改性高岭土固体酸催化下，甲苯能被浓硝酸对位选择性硝化，表现在对邻硝化产物比例达到１．５。     

全电动注塑机的特点及应用领域

重点分析了全电动注塑机与全液压注塑机的不同之处,简单地概述了国内塑料工业发展落后的现状以及把我国建成注塑机生产强国的突破口。详细介绍了全电动注塑机的应用领域,并展望了全电动注塑机的发展。     

体制转型与企业文化建设的战略思考

企业文化是企业核心竞争力之所在，处于体制转型过程中的国有企业，一方面要建立合乎市场经济要求的现代企业制度，另一方面要实现企业文化的延续与创新。论述了要在全面把握改革前和改革过渡时期国企的企业文化特征的基础上，正确处理企业文化建设的几个基本关系。     

Determination of the modified effect of nano-SiO2 by titration in nonaqueous phase

The dispersion of nanosilica that was modified and original in organic solvents could be judged directly by using methyl red as the indicator, and the principle of color development was also discussed. A method has been developed for the determination of the acidity of solid surfaces, which consists of titration of the solid suspended in benzene with n-butyl amine, using neutral red as the indicator. Basic indicator forms a red color on acidic solids, and the end-point of the titration is the disappearance of the red color. The text was submitted by the authors in English.     

A low temperature preparation and photocatalytical activities of PDVB@TiO2 hybrid microspheres

The core/shell anatase TiO₂ encapsulated poly(divinylbenzene) (PDVB@TiO₂) hybrid microspheres were prepared by the two steps: (1) the copolymer particles (PDVB) were prepared by the radical precipitation copolymerization of divinylbenzene (DVB) and γ-[(methacryloxy)propyl]trimethoxysilane (KH-570); (2) tetrabutyl titanate (TBOT) was co-hydrolyzed with the trimethoxysilyl groups on the surfaces of the PDVB cores and then the amorphous TiO₂ shell obtained was phase transformed to anatase TiO₂ by acid peptization. The products were characterized by FT-IR, UV–vis, scanning electron microscopy (SEM), X-ray diffraction (XRD) and thermal gravimetric analysis (TGA). Their photocatalytical activities were measured by the photo-degradation of methylene blue (MB). The polymer supported TiO₂ photocatalysts prepared at low temperature, had better repetition because of the coupled action of KH-570 between the PDVB core and TiO₂ shell. Furthermore, it could be easily separated from the solution by simple sedimentation.