荧光染料用于涤纶织物染色的荧光性能研究

在实验条件下，染色织物的荧光反射率随荧光染料的浓度增加而增加，超过一定浓度后，有下降趋势；在pH=5左右，荧光反射率最高；荧光增白剂会提高染色织物的荧光反射率，在荧光黄2GFL中，当荧光增白剂的浓度由0.1％增加到5％时，荧光反射率由8．43增加至18．59，而对非荧光染料只有增艳的作用，不产生荧光。荧光染料染色织物的荧光反射率随着加入非荧光染料量的增加而减弱。     

Soap‐free emulsion copolymerization of perfluoroalkyl acrylates in the presence of a reactive surfactant

Soap‐free emulsion copolymerization of perfluoroalkyl acrylate (FA)/methyl methacrylate (MMA)/n‐butyl acrylate (n‐BA) was carried out in the presence of sodium 2‐acrylamide‐2‐methyl propanesulfonate (AMPSNa) as a reactive surfactant and potassium persulfate (KPS) as an initiator. An analysis of the effects of concentration of AMPSNa, KPS, FA as well as polymerization temperature on the kinetic features (rate of polymerization) and colloidal characteristics (mean particle diameter, particle disperse index, particle numbers, and surface charge density) was followed. NMR, FTIR, AFM, and fluorine‐selective electrode analysis were used to characterize the composition and morphology of the FA copolymers. Both AFM analysis and contact angle measurements strongly implied that the fluorinated segments migrated to the outmost surface and created films with lower surface energy. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2438–2444, 2007     

Fabrication and amplification of Rhodamine B‐doped step‐index polymer optical fiber

A step‐index polymer optical fiber (SI POF) containing Rhodamine B in poly(methyl methacrylate) (PMMA) has been fabricated by a preform technique. Fluorescence of different fiber lengths were observed and discussed. A high gain (23 dB) for a SI POF with 60‐cm length, 400‐μm diameter was obtained. The Rhodamine B content of the doped SI POF is 5 ppm‐wt. The signal wavelength providing the highest gain for a 60 cm SI POF is around 630 nm, and the optimum fiber length is about 60 cm at 10 kW launched pump power. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 681–685, 2004     

高效液相色谱法在氟铃脲标准样品制备中的应用研究

标准样品是农残分析巾的必要条件。应用高效液相色谱法进行氟铃脲的纯化、制得氟铃脲标准样品，用DELTA PAK C18柱，以乙腈-水(68：32)为流动相，在波长254nm，室温下进行了保留值定性、定值分析、均匀性及稳定性考察，效果良好。     

气体控制参数对气体辅助成型产品翘曲的影响

从气体辅助注射成型工艺的角度探讨了气体的延迟时间和第一段压力这两个关键的参数对槽的影响进而对产品翘曲变形的影响，结果表明：虽然通过使用气体辅助注射成型技术能改善产品变形，但并不能完全消除变形；造成产品变形的原因和机理十分复杂，只有进行从设计到工艺的全方位考察才能有效的控制变形，气体手指效应也是造成产品变形的一个重要因素，工艺上可以通过调整延迟时间和气体压力来减小产品的变形量。     

骨架材料对全钢载重子午线轮胎性能的影响

讨论骨架材料的规格、结构分布及工艺控制对全钢载重子午线轮胎性能的影响。胎体帘布采用带有外缠丝的 3 + 9+ 15× 0 2 2 + 0 15规格钢丝、胎体帘线密度在 45 0～ 65 0根·m- 1 范围内 (帘线直径大于 1 2mm)以及胎体反包端点在成品外轮廓曲线的第 2或 3条装配线上等措施均有利于保证胎体强度 ;合理设计带束层结构 ,端点与胎侧肩部花纹距离取 10mm左右有利于消除应力过度集中 ;采用钢丝增强带有利于提高胎圈刚性。     

低熔点合金填充聚合物材料断口形貌研究

研究了合金元素、加工温度、金属含量、第三组分对低熔点金属填充聚合物材料断口形貌的影响。实验结果表明:不同的合金对体系的影响很大,低分子量、低结晶性聚合物,高的成型加工温度可提高材料的相容性。     

普钙产品转化率的数值计算方法

对影响普钙产品转化率的各种因素进行了分析,利用MATLAB 软件包得到了转化率的计算公式,提出了确定未分解磷矿的比例和由倍半氧化物引起的有效磷退化幅度的方法,为生产系统的预测和调整提供了一种途径。     

金平水电站坝型比选研究

根据金平水电站坝址的水文气象和地形地质条件等基本资料,对砾石土心墙堆石坝和沥青混凝土心墙堆石坝进行技术经济比较。沥青混凝土心墙堆石坝防渗土料工程量小,施工环节少,占用土地少,环境影响小,施工技术成熟,工程投资省745万元,故采用了沥青混凝土心墙堆石坝方案,金平水电站已投产发电,运行良好。     

On the behaviour of tin-containing species in cryolite–alumina melts

Tin oxide (SnO2) dissolves in cryolite–alumina melts forming tetravalent tin species, but under reducing conditions it is reduced to divalent tin and, further, to metallic tin. Freezing point depression data for SnF2 and SnO in molten cryolite (Na3AlF6) corresponded to the formation of one and two new particles, respectively. By anodic dissolution of tin into cryolite-alumina melts divalent as well as tetravalent tin was formed, depending on current density and composition. During electrolysis of SnO2-based oxygen-evolving anodes, the condensate above the melt contained both divalent (SnF2) and tetravalent (SnO2) tin species.