烧结温度对镍锌功率铁氧体磁性能的影响

为得到Zn含量不同时NiZn铁氧体材料的最佳烧结温度,用氧化物法制备了NiZn铁氧体材料,研究了烧结温度对材料起始磁导率、功耗、饱和磁感应强度和微结构的影响.结果表明,适宜的烧结温度对制备功耗低、饱和磁感应强度高和较优起始磁导率的NiZn铁氧体材料至关重要,而Zn含量不同时对应材料的最佳烧结温度也各不相同.     

磁性微电子机械系统(MMEMS)中的关键问题

磁性微电子机械系统(MMEMS)是在传统的微电子机械系统(MEMS)基础上发展的,它在科学研究及应用领域中有着巨大的潜力.磁性材料和MEMS技术的兼容性问题此前已作为一个重要的问题论述过.本文就磁性MEMS技术中的线圈制作、软磁膜制备及硬磁膜制备等关键性问题加以概述.     

Bi:YIG纳米薄膜的磁光特性

用射频磁控溅射和快速退火方法制备了纳米量级的Bi:YIG薄膜,研究了薄膜的磁光特性.当晶粒尺寸从150 nm降到80 nm时,透射率和Faraday角的值分别从75%和3.6°变成了80%和4.0°.结果表明:高的透射率和大Faraday角可以在晶粒尺寸为纳米量级的薄膜中共存.     

一类含查尔酮结构的光敏性二胺的合成研究

以醛、酮为原料经羟醛缩合反应合成了具有一类含查尔酮结构的光敏性二胺:1-(3-氨基苯基)-3-(4-氨基苯基)-2-丙烯-1-酮与对-二(间氨基肉桂酰)苯.通过优化实验得到最佳的合成工艺为:醛、酮在温度为0℃下,以乙醇为溶剂,氢氧化钠为催化剂,进行羟醛缩合反应3h.收率可达到86%,经液相色谱分析其纯度分别为99.92%,99.91%,紫外可见最大吸收波长分别为349nm、361nm.所得方法操作简便,收率较高,原料易得.并用元素分析、核磁共振、红外光谱等手段对产物的结构进行了表征.     

退火工艺对射频磁控溅射Bi:YIG薄膜磁性能的影响

对于用射频磁控溅射技术在Si基片上制备的Bi:YIG系薄膜,用快速循环退火方法对其进行晶化处理,研究了退火温度对Bi:YIG薄膜结晶状态和形貌的影响,以及退火气氛和循环周期对薄膜性能的影响.结果表明,用快速循环退火可以在si单晶基片上得到磁性能优良的薄膜(饱和磁化强度139 kA/m,矫顽力6.37 kA/m)并使薄膜形貌有较大改善,在石英基片上制备的薄膜法拉第角比常规退火的薄膜增大了约一倍.     

平面Z-型软磁铁氧体频率特性的研究

研究分析了Co2Z材料显微结构与磁性能的关系,在普通铁氧体工艺中引入预磁化处理方法,并适当控制二次再结晶现象,成功地研制出高性能的Co2Z型宽频材料,Z-型铁氧体材料的共振频率可达1.8GHz以上,截止频率在1GHz附近,起始磁导率在8-13之间,介电常数相对较低(ε'<30)。     

Cu对NiFe/Cu/NiFe层状薄膜的巨磁阻抗效应影响的研究

用直流磁控溅射方法制备了NiFe/Cu/NiFe层状薄膜 ,研究了Cu膜宽度对NiFe/Cu/NiFe层状薄膜的巨磁阻抗效应的影响 ,结果表明 ,层状薄膜的巨磁阻抗效应随Cu膜宽度发生振荡现象 ;并提出了一个等效电路模型直观地解释了层状薄膜增强巨磁阻抗效应的机理     

LTCC用低温烧结Mg-Cu-Zn铁氧体的研究

采用普通陶瓷工艺合成一系列低温烧结的Mg-Cu-Zn铁氧体(Mg0.5-xCuxZn0.5O)(Fe2O3)0.95(x=0.1、0.15、0.20、0.25、0.30),在900～1100℃研究了CuO加入量对磁性能和烧结特性的影响,在此基础上进一步研究了Bi2O3以及BaTiO3掺杂对900℃烧结Mg-Cu-Zn铁氧体的成相、致密化过程、显微结构和磁电性能的影响,结果显示,低温烧结的复合Mg-Cu-Zn铁氧体有望用作LTCC材料.     

Application of high-temperature permanent magnets Sm（Co,Fe, Cu,Zr）z in PPM focusing system

Rare earth permanent magnets Sm（Co, Fe, Cu, Zr）z with outstanding performance and high-temperature thermal stability were fabricated. Optimized by Fe content and process, Sm（Co0.72Fe0.15Cu0.1Zr0.03）7.5 magnet with B1〉0.75 T and Hci〉1300 kA/m at 300 ℃ can be obtained. According to the performance data of Sm（Co0.72Fe0.15Cu0.1Zr0.03）7.5, the magnetic field along central axis Bz in periodic permanent magnet （PPM） focusing system was simulated using electromagnetic field analysis software Maxwell 2D/3D. The Bz exhibited typical cosine curve along central axis, and the peak value of Bz was high enough to meet the demand of PPM focusing system at room temperature even at 200±20 ℃. Additionally, a kind of simple cooling structure for PPM focusing system was designed by setting cooling pipe between polepieces. Simulated results showed that smooth cosine curve of Bz was successfully achieved with good control of the thickness of cooling pipe.     

Rare earth doped CaCu_3Ti_4O_(12) electronic ceramics for high frequency applications

Ca1-xRxCu3Ti4O12(R=La,Y,Gd;x=0,0.1,0.2,0.3) electronic ceramics were fabricated by conventional solid-state reaction method.The microstructure and dielectric properties as well as impedance behavior were carefully investigated.XRD results showed that the secondary phases with the general formula R2Ti2O7 existed at grain boundaries of rare earth doped ceramics,which inhibited abnormal grain growth.The dielectric constant decreased from 4×105 in pure CaCu3Ti4O12(CCTO) ceramics to 2×103 with rare earth doping.However,all samples showed high dielectric constant in broad frequency range(10 MHz).The cutoff frequency(f0) was remarkably shifted to higher frequency from 13 MHz(pure CCTO ceramics) to 80 MHz(Gd-doped CCTO ceramics).Meanwhile,the dielectric loss tangent rapidly decreased approximately 10 times.These improvements of dielectric properties by rare earth doping are very useful in wide frequency chip capacitor and LTCC devices.