Synthesis and characterization of Cu-Cr-O nanocomposites

Cu-Cr-O nanocomposites that can be used as additives for the catalytic combustion of AP（ammonium perchlorate）-based solid-state propellants were synthesized via a citric acid（CA） complexing approach. Techniques of TG-DTA, XRD as well as TEM were employed to characterize the thermal decomposition procedure, crystal phase, micro-structural morphologies and grain size of the as-synthesized materials respectively. The results show that well-crystallized Cu-Cr-O nanocomposites can be produced after the CA-Cu-Cr precursors are calcined at 500℃ for 3 h. Phase composition of the as-obtained Cu-Cr-O nanocomposites depends on the molar ratio of Cu to Cr in the starting reactants. Addition of the as-synthesized Cu-Cr-O nanocomposites as catalysts enhances the burning rate as well as lowers the pressure exponent of the AP-based solid-state propellants considerably. Noticeably, catalyst with a Cu/Cr molar ratio of 0.7 exhibits promising catalytic activity with high burning rate and low pressure exponent at all pressures, due to the effective phase interaction between the spinel CuCr2O4 and delafossite CuCrO2 contained in the as-synthesized Cu-Cr-O nanocomposites.     

CdS/CdTe叠层太阳电池的制备及其性能

CdS/CdTe太阳电池是薄膜太阳电池研究工作的一个重要方向.为了提高开路电压Voc、改善电池的光谱响应,进而提高电池的转换效率,在此提出CdS/CdTe叠层太阳电池结构.文中,叠层电池的顶电池由CdS/CdTe超薄层构成;底电池由CdS/CdTe薄膜层构成.经分析测试,实验制备的CdS/CdTe叠层太阳电池具有明显的叠层结构,开路电压最高达到了852mV,短路电流密度最大为13mA/cm2,填充因子最高为55.2%,这种叠层电池的效率达到了8.16%(0.071cm2).研究表明相对于传统的单层CdS/CdTe太阳电池,CdS/CdTe叠层电池的制备对研究如何提高CdS/CdTe太阳电池的光伏性能有一定的参考价值.     

一次模压成形生产的高性能NdFeB径向多极环

分别用模压 等静压二次成型和一次模压成形工艺制备了烧结钕铁硼多极磁环,用NIM-2000测量了样品的磁性能,用磁力显微镜观测了取向方向和垂直去向方向的磁畴结构,用多极环与导磁环构成磁路测试了各极的气隙磁场.结果表明,一次成型比二次成型制备的多极环气隙磁场高,而且各极的磁密均匀度也要优于二次成型工艺制备的多极环,同时,一次成型工艺简单,因此有利于制备高性能的多极环.     

Sol-gel synthesis and photoluminescence of LaPO_4:Eu~(3+) nanorods

Monoclinic LaPO4 nanostructures with uniform rod shape have been successfully synthesized by a simple sol-gel method.The procedure involves formation of homogeneous,transparent,metal-citrate-EDTA gel precursors,followed by calcination to promote thermal decomposition of the gel precursors to yield the LaPO4 nanoparticles.Their morphologies and structures were characterized by XRD,TEM,TG-DSC and HRTEM.The results indicate that single monoclinic phase LaPO4 nanorods are readily obtained at 800 ℃ within 3 h.Furthermore,photoluminescence(PL) characterization of the Eu3+-doped LaPO4 nanocrystals was carried out.The effects of calcination temperatures and Eu3+ doping content on the PL properties were elaborated in detail.Room-temperature photoluminescence(PL) characterization reveals that the optical brightness as well as the intensity ratio of 5D0-7F1 to 5D0-7F2 is highly dependent on the calcination temperature,and the Eu0.05La0.95PO4 nanophosphor shows the relatively promising PL performance with the most intense emission.     

浅析如何在当前的体育教学中渗透心理健康教育

体育不仅能使人在健身活动中体验到运动对身体形态、机能的良好功效，还能使人在活动中相互交往，宣泄压抑。尤其面对当前青少年学生心理健康问题日趋严峻的情形，学校体育作为全面发展教育的重要组成部分，也必须承担起促进学生心理健康发展的重担，提高学生的心理素质。鉴于此，本文对当前学校体育融合心理健康教育进行了探讨。     

相位畸变的自判读与校正

利用非线性相共轭波干涉术形成的相应畸变自判读加上形变反射镜,构成一种新的非线性自适应光学系统。     

电石生产的自动称重配料系统

本文简单介绍了电石的生产工艺，依据其特点，提出了一种自动配料系统的设计方案来实现电石生产的自动化。     

锂离子电池高镍三元正极材料LiNi0.9Co0.05Mn0.05O2的制备与改性

采用La掺杂和固态电解质Li_1.3Al_0.3Ti_1.7(PO4)₃包覆对LiNi_0.9Co_0.05Mn_0.05O₂进行改性，研究掺杂和包覆对LiNi_0.9Co_0.05Mn_0.05O₂结构与性能的影响。结果表明：适量的La掺杂可以降低LiNi_0.9Co_0.05Mn_0.05O₂材料的离子迁移阻抗，提高Li⁺扩散系数，稳定材料的结构，从而提高材料的放电比容量及循环性能，当La掺杂量为0.1 wt%时，首次放电比容量为180.1 mAh·g^-1，经过100次循环后的容量保持率高达93.34%，远高于未掺杂样品的86.20%。Li_1.3Al_0.3Ti_1....     

粗轧变频电机主轴一字键槽加工工艺

粗轧变频电动机频繁正反转,对传递扭矩的一字键材料、接触面等要求较高。西南铝粗轧电动机为日本东芝三菱公司(TMEIC)设计,对一字键加工提出了超高要求,本文主要介绍了东方电机制造该一字键的加工工艺。