Fe掺杂LSCCF对中低温固体氧化物燃料电池ITSOFC短期输出性能的影响

柠檬酸盐法制备La0.7Sr0.15Ca0.15Co1-xFexO3-δ(x=0.2、0.4、0.6、0.8)阴极材料。该前驱体在900℃处理2h后,XRD证实已经形成完整的钙钛矿结构衍射峰。随Fe掺杂量增加,XRD谱图衍射峰的位置向小角度发生偏移,粉体的晶粒尺寸逐渐变大。SEM观察La0.7Sr0.15Ca0.15Co1-xFexO3-δ粉体其表面活性较高并出现了一定的团聚现象,颗粒尺寸约为5μm。以La0.7Sr0.15Ca0.15Co1-xFexO3-δ为阴极,在氢气/空气中研究了模压法制备的单电池性能,Fe掺杂量对开路电压的高低不起决定性作用,而最高功率密度随Fe掺杂量增加而降低,在650℃最高功率密度由x=0.2时的351.7mW/cm2降为x=0.8时的231.1mW/cm2。     

Stretch rate and deformation for pre-stretching aluminum alloy sheet

Numerical simulation combined with experimental test was carried out to analyze the pre-stretching process of the 7075 aluminum alloy sheet, from which the stress variation curves and residual stress of aluminum alloy sheet in different stretch rates were obtained. The results show that the residual stress in length direction is released after unloading the stretch force, while the residual stress in width direction is released during the stretching process. The study of residual stress elimination is beneficial for optimizing stretch rate on the basis of residual stress distribution law. By comparing the variation principle of residual stress in length direction, the size range of three deformation areas and elimination percentage of residual stress were obtained. The residual stresses of clamping area and transition area are not eliminated effectively, so sawing quantity should be the sum of both the areas. The elimination rate of residual stress in even deformation area could reach 90% after choosing a proper stretch rate, which is verified by both simulation and experiment.     

浸润度对低温下气膜产生的影响

针对气膜在沸腾过程中的低热导率以及能够降低流体流动阻力的特点,应用分子动力学模拟的方法在等温等压系综下模拟了气膜的形成过程,在较低的温度下得到了气膜.通过改变固液界面的接触角来改变固液界面的浸润度,进一步影响气膜的形成.结果表明,超疏水性固体壁面明显能够增强气膜形成,在较低温度下,一般的疏水性界面不能形成气膜,而超疏水性界面能够在较短时间内形成气膜,既可以减小流体流动阻力,又可以防止器件表面温度过高而烧坏.     

添加固体废弃物的硅藻土基多孔材料的制备

硅藻土作为主要基料,白云石为添加剂,加入其他固废物,制备了一种新型多孔材料。通过X射线衍射、扫描电镜及强度、吸水率等测试手段对制品进行了分析,探讨了硅藻土、白云石不同固体废弃物对多孔材料形成和性能的影响。研究表明,在硅藻土、白云石、粉煤灰、熟污泥的质量分数分别为45%、35%、10%、10%时,经1 020℃烧成并保温30min形成的多孔材料的密度为1.36g/cm3,孔隙率45%,吸水率为25%,抗折强度达12.43MPa,通过物相分析其多孔材料的成分主要晶相为莫来石与钙长石及透辉石。     

基于磁传感器的飞行器姿态测量方法

为近程自旋飞行器设计了一种基于地磁测量的姿态测量方法。根据此类飞行器飞行过程中偏航角较小,射程较近时偏航角可以忽略的特点,在偏航角可以忽略的情况下进行姿态角算法分析。由于第一种方法存在姿态角根取舍的问题,首先,利用空间转换矩阵推导出飞行器姿态角的表达式。然后,利用几何分析的方法推导出了飞行器姿态角表达式,并对该算法的误差进行仿真。仿真结果表明:误差在可接受范围。     

高质量密度储氢材料-氨基化合物的合成

采用真空蒸发法制备了氨基化锂LiNH2(+2·LiH)薄膜,即首先将Li真空镀膜到金属基板上,然后经氮化、氢化处理合成LiNH2薄膜.此外,真空蒸发法也用于Mg部分置换Li后薄膜的制备.实验结果证明,与传统的粉末状试样相比,薄膜状试样能够在更低的温度下释放出氢气.研究表明采用包括真空蒸发法等非传统方法合成金属络合物储氢材料对进一步提高其储放氢特性具有良好的效果.     

谐振开关电容变换器潜在电路路径分析

本文首先介绍了谐振开关电容变换器中普遍存在的潜电路现象，然后针对n阶谐振开关电容变换器的电路结构复杂的问题，提出了计算所有电路路径的连接矩阵算法以及辨别潜电路的法则。最后，以降压式开关电容变换器的潜电路为例，验证了该算法的可行性。     

浅谈建设项目决策及设计阶段的工程造价管理

工程造价管理是对建设项目在投资决策阶段、设计阶段、招标投标阶段和项目实施阶段以及建设结算阶段实行全过程的管理,投资决策阶段和设计阶段是对工程造价影响较大的两个阶段,其中决策阶段是工程造价管理的重中之重.     

主泵的全流道CFD分析

本文介绍了采用 CFD 技术首次对主泵机组进行的全流道计算分析。并将多个工况的全流道计算结果与试验结果进行比较,表明该计算方法是成功的。     

Existing State and Partitioning of Rare Earth on Weathered Ores

The existing state and partitioning of rare earth （RE） on weathered ores in Longnan County（LN）, Xingfeng County（XF） and Ninghua County（NH） were characterized systematically by standard geological analytical methods. It is found that RE in the weathered rare earth ores exist as four phases： （a） water soluble, （b） ion-exchangeable, （c） colloidal sediment （oxides）, （d） minerals, in which mainly as ion exchangeable phase, accounting for nearly 80% of total RE, with about 20% in the form of colloid sediment phase and mineral phase, but very little as aqueous soluble phase. These rare earth partitioning were mainly chosen mid-heavy RE elements, occupying above 60%, but not equal in the four phases. The mid-heavy RE elements were primarily enriched in the ion exchangeable phase up to 40%, while the containment of cerium dioxide is below 2 %. The cerium deficiency occurs in the ion exchangeable phase in weathered ore. It results from that the Ce^3＋ is oxidized into Ce^4＋ and changes into CeO2. For LN ore, the containment of Y is high in weathered ore because Y-minerals are abundant in original rock.