Tautomerism and Reactions of 1H-1,2,4-Triazole-5-thiones with Hydrazonoyl Halides

The acid dissociation constants (K_a) of a series of 3,4-diaryl-1H-1,2,4-triazole-5-thiones ( 1 ) were determined and were found to correlated linearly with Hammett substituent constants; log K_a = 1.06 σ_x − 11.01. Such a result indicates that 1 exists essentially in one tautomeric form namely the thione form. Reactions of 1 with hydrazonoyl chlorides 2 gave the thiohydrazides 5 . Similiar reaction of 3-phenyl-1H(4H)- 1,2,4-triazole-5-thione 1g with 2a gave the thiohydrazide 5h which was converted into 1,3,5-triphenyl-1,2,4-triazolo[3,4-c]-1,2,4-triazole ( 9 ). The latter was also prepared from 3-phenyl-5-methylthio-4H-1,2,4-triazole ( 6 ) and 2a . The mechanism of the reaction of 1 with 2 is discussed.     

Rheological behavior of Algerian crude oil: effect of temperature and refined product

Abstract

The rheological behavior and its variation with temperature and refined product concentration of a crude oil sample coming from a quagmire of the separation station of Tin Fouye Tabankort oilfield/southern Algeria were investigated experimentally. The experiments were carried out at various temperatures (20, 30 and 50?°C) over the shear rate range of 0 to 700?s^?1 by using a controlled stress rheometer (AR 2000, TA Instrument). The results showed that the crude oil exhibit non-Newtonian of shear thinning behavior at low shear rate and Newtonian behavior at high shear rate and was adequately described by Casson and Herschel–Bulkley models. The rheological measurements through the steady flow test and viscoelastic behavior, including the storage modulus (G′), loss modulus (G″), and complex modulus (G*), has indicated that the rheological properties of the crude oil were greatly influenced by the temperature and the additive concentration.     

Improvement of rheological properties of Algeria crude oil by addition of extra-light crude oil and a surfactant agent

Abstract

Effect of surfactant and extra-light crude oil addition on the rheological behaviors of an Algeria crude oil in order to improving its flowability were studied at low temperature. These rheological properties include steady flow behavior, yield stress and viscoelastic behavior. An AR-2000 rheometer was employed in all of the rheological examination tests. Results show that Toluene and extra-light crude oil addition causes a strong reduction in viscosity, the yield stress and can effectively increase of crude oil transport capacity. The toluene addition gets its best flow capacity and lowest viscosity at 6%. The extra-light crude oil addition obtains its best flow capacity and lowest viscosity at 50%. The viscoelasticity character of the crude oil has indicate a significantly influence by the addition of Toluene and extra-light crude oil.     

A Comparative Study of Localization Methods in Indoor Environments

A comparative study, based on three different measurements (direction of ray arrival, time difference of arrival and received signal strength), to compute the unknown position of mobile stations in indoor environments is presented in this paper. The comparison is carried out considering the results of analyses in a real building in Madrid. To overcome the problems that arise in indoor areas due to the presence of non line of sight conditions, the fingerprinting technique is applied in each of the cases. Data for computations are provided by a simulation tool based on the uniform theory of diffraction and ray-tracing techniques. This information is stored in the fingerprinting database and contains information related to every mobile station, every reference node and every access point located inside the environment under analysis. Experimental results compare the mean error when localizing several mobile stations by using the three different approaches. The goal is to obtain high precision in the localization by means of alternative methods to the received signal strength classical measurement. These techniques will be useful in critical environments where high operational security requirement are demanded.     

MedHySol: Future federator project of massive production of solar hydrogen

Mediterranean Hydrogen Solar (MedHySol) is a federator project for development of a massive hydrogen production starting from solar energy and its exportation within a framework of a Euro–Maghrebian Cooperation project for industrial and energetic needs in the Mediterranean basin. The proposal of this project is included in the Algiers Declaration's on Hydrogen from Renewable Origin following the organization of the first international workshop on hydrogen which was held in 2005. Algeria is the privileged site to receive the MedHySol platform. The objective of the first step of the project is to realize a technological platform allowing the evaluation of emergent technologies of hydrogen production from solar energy with a significant size (10–100 kW) and to maintain the development of energetic rupture technologies. The second step of the project is to implement the most effective and less expensive technologies to pilot great projects (1–1000 MW). In this article we present the potentialities and the feasibility of MedHySol, as well as the fundamental elements for a scientific and technical supervision of this great project.     

Study of the recrystallization process of AlMgSi alloys containing transition elements

The addition of small amounts of the transition elements such as Zr, Mn and Cr, which have a low solubility in the α-aluminium solid solution and thus form dispersoids, to AlMgSi alloys showed that these elements inhibit recrystallization when the alloys are pre-heated prior to deformation. The formation of coarse particles during casting is mainly due to the presence of Fe. This type of particles found, even, in solution treated samples. The particles, with a diameter exceeding 3 μm, accelerate the recrystallization as they provide good sites for nucleation of recrystallization. Precipitate free zones (PFZ's) developed around the coarse particles favour nucleation of recrystallization by subgrain growth. The presence of dispersoid particles is found to shift the recrystallization energy peak towards higher temperatures. Intermediate annealing before deformation allowed to achieve a high rate of deformation by cold rolling due to the removal of the solute from the matrix by the formation of the hardening phases. Optical and transmission electron microscopy, hardness measurements and differential scanning calorimetry (DSC) were used to study the kinetics of precipitation and recrystallization of the AlMgSi alloys.     

Preparation and catalytic activity of nanostructured Pd catalysts supported on hydrogenotitanate nanotubes

Nanostructured palladium particles (nanorods, icosahedra, cubes) were synthesized in aqueous solution using a seeding-mediated approach with a structure-directing agent. These nanostructured Pd particles were then impregnated onto hydrogenotitanate nanotubes using two different impregnation procedures. The as-prepared catalysts were then tested in the selective hydrogenation of cinnamaldehyde at 323 K under 10 bars of H₂. The selectivity is influenced by the morphology of the Pd nanostructured particles with a higher selectivity into saturated alcohols when the proportion of (111) Pd sites increases.     

Multipolarized Antennas Channel Model of URA Based on SW Massive MIMO Systems in UpLink Transmission

Wireless Personal Communications - Multipolarized Uniform Rectangular Array (mURA) Massive Multiple Input Multiple Output systems (mMIMOs) is a promising technology in 5G wireless communications....