Effect of rolling deformation on the structures and properties of multi‐walled carbon nanotube filled isotactic polypropylene

Isotactic polypropylene filled with various contents of multi‐walled carbon nanotubes (MWCNTs) were fabricated by the injection molding technique and then rolled at room temperature. The unrolled samples (URS) and rolled samples (RS) were characterized by X‐ray diffraction studies, scanning electron microscopy, mechanical and micromechanical tests and differential thermal analyses. Although the URS exhibit the lamellar α‐crystal with a*‐axis orientation, the RS show the same crystals with both a*‐ and c‐axis orientation, which is explained by interlamellar and intralamellar slips and lamellar destruction. Scanning electron micrographs display distinct surface morphological features for both URS and RS. While the tensile strength of RS is higher than that of URS, the Young's modulus (Y) is found to be lower than that of URS. Anisotropy in microharness (H) parallel and perpendicular to the rolled direction has been detected, although H for both samples increases with increasing MWCNT contents. The average relationship H/Y ≈ 0.18 as estimated for URS is closer to the predicted value of 0.10 for polymers than the H/Y ≈ 0.22 obtained for RS. The lamellar thickness for URS increases with increase of MWCNT content and that for RS decreases, as evaluated from both differential thermal analyses and X‐ray diffraction data. Copyright © 2011 Society of Chemical Industry     

Evidence of nano-galvanic couple formation on in-situ formed nano-aluminum amalgam surfaces for passivation-bypassed water splitting

Reaction of Al metal with water is a well-known technique for large scale production of hydrogen. However, this method suffers from kinetic limitations due to formation of a passivation layer on Al, preventing optimal operations. Using high resolution Scanning Kelvin Probe Force Microscopy (SKPFM), we show the origin of formation of 'nano-galvanic couple' on in situ formed nano-aluminum amalgam surfaces in a water splitting system; passivation based limitations are completely bypassed in this approach. Furthermore, they offer an opportunity to beneficiate and recover mercury in contaminated water. The nano-galvanic corrosion due to substantial lateral variation in surface contact potential is responsible for the observed high throughput of hydrogen production (720 mL/min per 0.5 g Al salt). It may be noted that this process fares better than in situ prepared nano-Al based hydrogen production, wherein 600 mL/min of hydrogen is obtained for 0.5 g Al salt. Investigations using Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) provide evidence for passivation-bypassed hydrolysis and favourable kinetics for in situ derived nano-AlHg hydrolytic agents (when compared to nano-Al). This study, to the best of our knowledge, reports the first direct proof of nano-galvanic couple formation on in-situ prepared nanoaluminum amalgam surface; paving a direct way to overcome the long standing passivation problem in Al hydrolysis. It is found that the hydrogen production rate and standard deviation (SD) of the contact potential of nanoaluminum amalgam are directly related to the rate of addition of the reducing agent, offering an opportunity for kinetic control for the in situ hydrolytic process.     

Optimize adaptive media playout using dynamic fuzzy logic control for video streaming

Multimedia Tools and Applications - Adaptive Media Playout (AMP) controls adapt playout rate to prevent buffer outage and to reduce delay in playout. Most AMP techniques use buffer fullness or its...     

Exercise classification and event segmentation in Hammersmith Infant Neurological Examination videos

Image and video processing techniques are being frequently used in medical science applications. Computer vision-based systems have successfully replaced various manual medical processes such as analyzing physical and biomechanical parameters, physical examination of patients. These systems are gaining popularity because of their robustness and the objectivity they bring to various medical procedures. Hammersmith Infant Neurological Examinations (HINE) is a set of physical tests that are carried out on infants in the age group of 3–24 months with neurological disorders. However, these tests are graded through visual observations, which can be highly subjective. Therefore, computer vision-aided approach can be used to assist the experts in the grading process. In this paper, we present a method of automatic exercise classification through visual analysis of the HINE videos recorded at hospitals. We have used scale-invariant-feature-transform features to generate a bag-of-words from the image frames of the video sequences. Frequency of these visual words is then used to classify the video sequences using HMM. We also present a method of event segmentation in long videos containing more than two exercises. Event segmentation coupled with a classifier can help in automatic indexing of long and continuous video sequences of the HINE set. Our proposed framework is a step forward in the process of automation of HINE tests through computer vision-based methods. We conducted tests on a dataset comprising of 70 HINE video sequences. It has been found that the proposed method can successfully classify exercises with accuracy as high as 84%. The proposed work has direct applications in automatic or semiautomatic analysis of “vertical suspension” and “ventral suspension” tests of HINE. Though some of the critical tests such as “pulled-to-sit,” “lateral tilting,” or “adductor’s angle measurement” have already been addressed using image- and video-guided techniques, scopes are there for further improvement.     

SQC and the fluency hypothesis

Students’ Quality Circles (SQCs) are considered in the context of English Language Teaching in Pakistan, with a focus on oral expression. SQCs offer many educational benefits.     

Technical note Temporal remote sensing data and GIS application in landslide hazard zonation of part of Western ghat,India

Spatial and temporal multi-layered information is required to assess landslide hazard susceptibility. The manual method of data integration for targeting potential zones susceptible to landslide hazard is time consuming. The present study highlights the utility of temporal remotely-sensed data and knowledgebased Geographical Information Systems for collection, integration and analysis of spatially-oriented data, as well as in finding out the inherent relation between separate entities in parts of West ghat in India.     

Interaction Between Two Mutually Orthogonal Heat-Generating Baffles in a Square Cavity

Laminar free convection induced by two mutually orthogonal discrete heat-generating baffles in a two-dimensional square cavity is analyzed numerically. The computations were carried out for different locations and combinations of heat source strengths of the baffles for a fixed Grashof number of 10⁶and Prandtl number of 0.71. The coupled governing equations were solved bya finite-difference method using alternating direction implicit technique and successive overrelaxation methods. The obtained results clearly show that the hydrodynamic and thermal fields in the cavity depend on both the location and strength of the heat-generating baffles. Though the flow inhibition is caused by both the baffles, the baffle with higher source strength plays a decisive role in inducing the flow. The locations of baffles with unequal source strengths produce significant changes in the net heat transfer rate. This is further magnified for higher contrast in source strengths. This study provides qualitative suggestions that may improve the thermal design of sealed enclosures, which are encountered frequently in the electronics industry.     

Error diffusion in cell-oriented Fourier-transform computer-generated holograms to compensate for printing constraints

Abstract

Error-diffused quantization has been applied to the generation of cell-oriented computer-generated Fourier transform holograms, resulting in reduced reconstruction errors. Improvements are demonstrated when applied to the algorithms of Lohmann, Lee and Burckhardt after invoking realistic constraints on the minimum size of the printable spot for an electrophotographic laser printer.     

Estimation of Desired Motion Intention and compliance control for upper limb assist exoskeleton

International Journal of Control, Automation and Systems - In this paper, we have addressed two issues for upper limb assist exoskeleton. 1) Estimation of Desired Motion Intention (DMI); 2) Robust...