A novel heteropolyacid-doped carbon nanotubes/Nafion nanocomposite membrane for high performance proton-exchange methanol fuel cell applications

A novel proton-exchange polymer composite membrane was synthesized using Nafion^®, tetraethoxysilane-modified carbon nanotubes (CNTs) and phosphotungstic acid-modified carbon nanotubes with the aim of using direct methanol fuel cells (DMFCs). Physicochemical properties of the modified CNTs and fabricated composite membranes were investigated by Fourier transform infrared spectroscopy, field emission scanning electron microscopy, water uptake, thermogravimetric analysis, ion exchange capacity, proton conductivity and methanol permeability tests. It was demonstrated that chemical surface modification of CNTs and introduction of the phosphotungstic acid (PWA) groups effectively improved the performance of DMFC. It was found that the presence of PWA groups on the surface of CNTs led to the formation of strong electrostatic interactions between the PWA groups and clusters of sulfonic acid in Nafion^® macromolecules. Hence, the incorporation of inorganic phosphotungstic super-acid-doped silicon oxide-covered carbon nanotubes (CNT@SiO₂-PWA) into Nafion^® matrices enhanced the proton conductivity of the prepared membranes. Moreover, the methanol permeability was reduced to 2.63 × 10^?7 cm² s^?1 in comparison with the recast Nafion^® membrane (2.25 × 10^?6 cm² s^?1). Enhancing the proton conductivity and reducing the methanol permeability, the selectivity of the prepared nanocomposite membranes was enhanced to a greater value of 330,700 S s cm^?3 as compared to the value of 38,222 S s cm^?3 for recast Nafion^®.     

UVA-LED assisted persulfate/nZVI and hydrogen peroxide/nZVI for degrading 4-chlorophenol in aqueous solutions

Photocatalytic degradation of 4-chlrophenol (4-CP) using UVA-LED assisted persulfate and hydrogen peroxide activated by the nZVI (Nano Zero Valent Iron) in a batch photocatalytic reactor was investigated. The reaction involved a lab-scale photoreactor irradiated with UVA-LED light emitted at 390 nm. The efficiency of the reaction was evaluted in terms of 4-CP degradation and mineralization degree at different pH of solution, initial concentrations of nZVI, persulfate, hydrogen peroxide and 4-CP. In UVA-LED/H₂O₂/nZVI process, complete degradation of 4-CP (>99%) and 75% mineralization was achieved at pH of 3, hydrogen peroxide concentration of 0.75 mM, nZVI dosage of 1mM and initial 4-CP concentration of 25mg/L at the reaction time of 30 min. The optimum conditions obtained for the best 4-CP degradation rate were at an initial concentration of 25mg/l, persulfate concentration of 1.5mM, nZVI dosage of 1mM, pH of 3 and reaction time of 120min for UVA-LED/persulfate/nZVI process. It was also observed that the 4-CP degradation rate is dependent on initial 4-CP concentrations for both processes. The pseudo-first-order kinetic constant at 25mg/L initial concentration of 4-CP was found to be 1.4×10^?1 and 3.8×10^?2 in UVA-LED/H₂O₂/nZVI and UVA-LED/persulfate/nZVI processes, respectively. Briefly, the UVA-LED/H₂O₂/nZVI process enhanced the degradation rate of 4-CP by 3.67-times in comparison to UVA-LED/persulfate/nZVI process at 30min contact time, which serves as a new and feasible approach for the degradation of 4-CP as well as other organic contaminants containing wastewater.     

Hydrogen Production from Co‐Gasification of Coal and Biomass in the Presence of CaO as a Sorbent

Among the options for clean energy production, the gasification process is receiving increasing attention as it offers the best combination of investment and value of produced electricity compared to other methods. An Aspen Plus model of co‐gasification of biomass and coal with in situ CO₂ capture was developed to evaluate its potential for hydrogen production and cracking of organic impurities, i.e., tars. The effects of some critical operational variables on gas composition and yields of hydrogen gas and tar were investigated. The obtained results indicate that the fuel particle size plays a minor role in the process; smaller particles favor the conversion of tar and production of more hydrogen gas.     

Mechanics of Intermittent Plasticity Punctuated by Fracture During Shear Deformation of Mg Alloys at Near-Ambient Temperatures

Microstructure evolution of basal-textured Mg alloy AZ31B (Mg: Al: Zn; 96: 3: 1 wt pct) during simple shear deformation at near-ambient temperatures was studied by plane-strain machining. Using Schmid factor calculations in conjunction with quantitative electron microscopy, it was found that plastic deformation in AZ31B in the primary deformation zone of machining commences by extension twinning followed by basal slip. Characteristics of twinning in individual grains were described by correlating the direction of twinning with the principal stress state. The implications of these deformation mechanics for the microstructure inherited by the freshly generated surfaces in shear-based material removal processes are examined. These include the identification of extensive surface texture reorientation at machined surfaces via extension twins, limits on surface integrities wrought by fracture events that punctuate plastic deformation, and their relationship to the cutting tool geometry.     

Effectively designed shell‐tube heat exchangers considering cost minimization and energy management

Cost optimization, which is expressed as a set of analytical variables, is a key objective in economic design approaches of shell‐and‐tube heat exchangers. This study has provided new design techniques based on tube bundle effect on the economic optimization design of shell‐and‐tube heat exchangers. Also the objective of this paper is to develop the cost estimating for the new modified shell‐and‐tube heat exchangers by introducing new objective functions. According to the results the best configuration choice will obviously be the one with the least irreversibility, that is, with the lowest exergy destruction rate and lower annual capital cost. Also, the combined reduction of annual capital investment and operating cost by the new design technique led to a decrease in the overall costs of about 10% to 24% in comparison with original design. So the proposed design technique shows potential for improvement and economic optimization of shell‐and‐tube heat exchangers.     

N-Containing Carbons Derived from Microporous Coordination Polymers for Use in Post-Combustion Flue Gas Capture

Herein, novel carbons that, owing to a high density of micropores (up to 79%) and N-content (up to 14.9%), offering exciting potential for post-combustion CO₂ capture are reported. Given that little is known about how starting materials impact the structure and performance of carbons, three different microporous materials are pyrolyzed. These include a Co-(metal-organic framework) (MOF), a Co-MOF-polymer composite, and a coordination polymer derived from the same monomer and cobalt ions. Notably, the cobalt, which is required to drive the polymerization, is subsequently leached from the carbons via acid for its reuse in MOF synthesis. Next, various metrics including CO₂ capacity, selectivity, isosteric heat of adsorption, breakthrough time and cyclability are assessed. The acid treated carbons adsorb 0.21, 0.99, and 1.11 mmol CO₂ g⁻¹, respectively, (313 K, 0.15 bar) with CO₂/N₂ selectivity ranging from 37 to 52. Due to superior capacity, the polymer-derived carbons also reveal impressive breakthrough times in simulated flue gas mixtures (15% CO₂/85% N₂, 80% RH, 313 K) ranging from 33 to 40 min g⁻¹. Similar performance is also observed under dry conditions and after pre-saturation with water for 1.5 h. Remarkably, no loss in working capacity is observed after 100 CO₂ TSA cycles (313 K/393 K).     

Nanomechanical characterization of the hydrogen effect on pulsed plasma nitrided super duplex stainless steel

Pulsed plasma nitriding (PPN) is used to nitride super duplex stainless steel (SDSS). Different analytical techniques are used to characterize the nitride layer on both ferrite and austenite phases existing in the SDSS. In-situ electrochemical nanoindentation is used to examine the effect of electrochemically charged hydrogen on the mechanical properties of both the SDSS substrate metal and the nitride layer. By applying this method, we were able to trace the changes in the mechanical properties due to the absorption of atomic hydrogen. The results clearly show that the hydrogen charging of the nitriding layer can soften the layer and reduce the hardness within both the compound and diffusion layers. The effect is completely reversible, and removal of the hydrogen causes the hardness to recover to its original value. The findings show that nitriding is a promising way to control the hydrogen embrittlement of SDSS.     

A Comparison of MVDR and LCMV Beamformers’ Floating Point Implementations on FPGAs

Adaptive beamformers are designed with the aim of detection of noise and intentional destructive interference and then removing them from the desired signal. This is done by placing high attenuation in the direction of the destructive signal in the radiation pattern of antenna arrays without attenuating the signal from a known direction. Minimum variance distortionless response and linearly constrained minimum variance are among such algorithms in mobile communications. A short explanation of the theory and weights formulae of these beamformers will be given. Two designs for weights calculations in Simulink with the added library of DSP-Builder tool from Altera will be presented. Quadrature Rectangular decomposition with Modified Gram-Schmidt algorithm is used instead of the direct matrix inversion. All calculations are done in single floating point mode for the required high accuracy. Modelsim has been used for hardware simulation and measuring the required clock cycles. The target FPGA is Aria10 from Altera which has floating point DSP blocks for high-performance computations. Hardware resources usage, power consumption, maximum clock frequency and update rate for different matrix sizes of these two beamformers are compared and discussed. The results are also compared with some other relevant reported works.     

Multi‐step solution for QoS management in wireless mesh networks

Wireless mesh networks (WMNs) as community‐ and city‐wide type networks are required to extend their capability to offer real‐time multimedia services. While technologies exist to support quality of service (QoS) at node level, we propose here a network‐wide multi‐step solution to manage and offer QoS across a WMN. From a provider perspective, the provisioning and fulfillment of QoS‐based services fall under the realms of service management, network and traffic engineering functions. We describe the relevant functions required to design, implement and operate a WMN for providing a qualitative QoS to end‐users. Our proposed solution considers network planning aspects, including node placement, node clustering and frequency assignments, route discovery between ingress–egress points and appropriate QoS provisioning across the network. Route‐level QoS provisioning is defined as the process of allocating resources to the nodes along the identified routes to meet a priori known aggregated traffic demands in order to satisfy the QoS requirements for different types of application. Simulation and experimental tests are conducted to validate the correct behavior of processes/algorithms and to access the solution in achieving QoS for aggregate user traffic. Copyright © 2012 John Wiley & Sons, Ltd.     

Catalytic ozonation of ethyl benzene using modified pumice with magnesium nitrate from polluted air

This paper reports a novel technology developed for a Catalytic Ozonation Process (COP) to treat polluted air streams containing ethyl benzene. Raw pumice was modified with magnesium nitrate, and then used as a catalyst in the COP. The best removal efficiency of ethyl benzene for single ozonation and single modified pumice was 58–80%, respectively at 50 ppm of this pollutant, while the maximum removal efficiency of ethyl benzene was 90% for COP (6 L/min of flow rate of inlet air, 15 g of the adsorbent, and 50 ppm of ethyl benzene). The saturation and breaking point of the catalyst in low concentrations occurred after 12 h, which was later than single ozonation. According to the results obtained, pumice modified with magnesium can be used as a cost effective, efficient and suitable catalyst to treat polluted air containing volatile organic compounds in the oil refining industries.