Preparation op metal borides in an aprotic system

A novel technique to prepare Nickel Borides using Diborane-THF complex generated “in-situ” as reducing agent, is presented. The Nickel Bondes series were prepared using two ways, the HETEROGENEOUS and HOMOGENEOUS route. Solid NiCls of different mesh size was added to the reducing complex to prepare nickel boride by HETEROGENEOUS route. While Ni(AcO)₂·4H₂O dissolved in methanol was used to obtain nickel boride by the HOMOGENEOUS one. The advantage of this technique is that by using an aprotic medium, borides of metals which form stable oxoanions are obtained.     

The HLD Study of Surfactant Partitioning for Oilfield Corrosion Inhibitors

The partitioning of corrosion inhibitor (CI) products is a measure of their potential to protect oilfield pipelines. In this paper the hydrophilic–lipophilic deviation (HLD) model is first used to quantify their partitioning in terms of the characteristic curvature (C _c,act) of a series of anionic (alkoxylated phosphate esters) and cationic (alkoxylated amines, aromatic amines, imidazoline acetates and quaternary amines) actives. This parameter is expressed over a range of pHs within which pipeline corrosion occurs. The HLD model is next used to predict the partitioning of each active from water into toluene at increased salinities. Linear mixing rules are lastly used to predict the characteristic curvature of Product A (C _c,mix) as a function of the C _c,act of a subset of actives.     

The indications for the appropriate use of magnetic resonance. The Health Technologies Evaluation Service of the Department of Health of the Basque Government, Osteba

Magnetic resonance imaging (MRI) allows the non-invasive obtention of diagnostic images, with no ionizing radiation emission and in any space plane. It has a great capacity to differentiate anatomic structures, and it is very useful for planning surgery or radiotherapy. It is the first choice diagnostic technique in conditions involving the central nervous system, useful for establishing diagnosis, surgery planning, and following lesions involving the spinal cord and spine. In the musculoskeletal system it may become and appropriate alternative to arthroscopy. Nevertheless, it is of limited use for the diagnosis of chest, abdominal and pelvic pathology.     

Estimation of Circulating Blood Volume from a Tracer-Response Curve

A method is developed for analyzing sudden injection dye (tracer) curves in order to obtain the distribution of first passage times in the mammalian circulation. The moments of the distribution yield useful quantities such as circulating blood volume. The method involves the use of Liouville-Neumann series. The calculation of the first passage time distribution (FPD) also requires a deconvolution through the use of Fourier transforms, but the calculation of moments does not.     

Acroleindiethylacetal: Reaction with free radicals and copolymerization

The reaction between acroleindiethylacetal (3.3-diethoxypropene) and free radicals and the behaviour of this acetal in the free radical copolymerization with unsaturated monomers has been investigated. The decomposition of benzoyl peroxide and tert.-butyl peroxide in acroleindiethylacetal has been studied in the liquid phase. On the basis of the obtained products a mechanism is proposed which involves the abstraction of a hydrogen atom by a primary radical from a carbon atom which is adjacent to oxygen. We also tried to copolymerize the acetal with several conventional comonomers but copolymers were only obtained when acrylonitrile and maleic anhydride were used. The remarkably uniform composition of the copolymers from the acetal and maleic anhydride is explained through a donor-acceptor complex between the two monomers.     

Sizing of a solar/hydrogen system for high altitude long endurance aircrafts

High altitude long endurance (HALE) aircrafts are aerial platforms operating in the stratosphere, providing relay services for wireless communication networks. These platforms are an alternative to increase the effectiveness of future communication. Nevertheless, the power system is a key part that determines the implementation and feasibility of these platforms. One effective and renewable option to power an HALE aircraft is a photovoltaic system (PVS) with hydrogen storage. In this paper, the simulation of the solar/hydrogen closed loop system is carried out for a parametric combination of the subsystems power. Power consumption of the propeller was determined as a function of the aircraft weight in steady flight and in still air. In order to obtain the optimal nominal powers the efficacies are calculated at hourly intervals over the course of the year by means of an analytical energy balance. The proposed method was implemented in an algorithm, which allows fast estimation of the actual time of flight and the system efficiency. Finally, the energy system of three HALE aircrafts was analyzed in relation of their wing area and total and empty mass.     

Linker-based bio-compatible microemulsions

In this work we have studied the formulation of biocompatible microemulsions using lecithin as the main surfactant and bio-compatible linker molecules (hexyl polyglucoside asthe hydrophilic linker and sorbitan monoleate as the lipophilic linker). These bio-compatible systems are discussed as potential substitutes for chlorinated solvents in dry-cleaning applications and as solvent delivery systems for pharmaceutical applications. Formulation parameters and conditions were evaluated using isopropyl myristate (IPM) as the model oil. It was found that the proposed linker-based formulations were able to form alcohol-free microemulsions while achieving higher solubilization capacity than similar systems reported in the literature. In addition, these lecithin/linker formulations were able to form microemulsions with a wide range of oils, from polar chlorinated hydrocarbons to hydrophobic oils such as squalene. These microemulsions were achieved under isotonic conditions (0.9% NaCl) by only varying the relative proportions of the linkers. The "solvency" power of these bio-compatible formulations was tested for the removal of hexadecane (used as model oil) from cotton fabrics and compared to the solvency power of a typical dry cleaning solvent tetrachloroethylene (PCE). While PCE and the linker-based lecithin formulation removed the same amount of hexadecane at low loading ratios (less than 1% oil volume fraction), at higher loading ratios the linker-based lecithin formulation retained its oil removal capacity while the efficiency of the PCE system declined rapidly. These initial results thus demonstrate the remarkable oil solubilization capacity of these bio-compatible linker-based lecithin formulations and illustrate their potential as environmentally friendly replacements for organic solvents.