A simple and highly sensitive spectrophotometric determination of Cr(VI) in food samples by using 3,4-dihydroxybenzaldehydeisonicotinoylhydrazone (3,4-DHBINH)

A simple, rapid, sensitive and inexpensive method has been developed for the determination of trace amounts of chromium(VI) using 3,4-dihydroxybenzaldehydeisonicotinoylhydrazone (3,4-DHBINH). The metal ion gives a yellow coloured complex with 3,4-DHBINH in acetate buffer of pH 5.5 with 1:1 (metal:ligand) composition. The complex shows a maximum absorption at 400 nm. Beer’s law is obeyed in the range 0.5–7.7 ppm of Cr(VI). The molar absorptivity, Sandell’s sensitivity and detection limit were found to be 1.35 × 10⁴ L mol⁻¹ cm⁻¹, 0.0075 μg cm⁻² and 0.0045 μg mL⁻¹, respectively. The correlation co-efficient and regression co-efficient of the Cr(VI)–3,4-DHBINH complex were 0.99 and 0.12, respectively. Major cations and anions did not show any interference. The developed method has been successfully applied for the analysis of Cr(VI) in food samples (leafy vegetables), comparing the results simultaneously with those obtained using an Atomic Absorption Spectrophotometer, whereby the validity of the method has been tested.     

Vibration damping and electrical conductivity of styrene–butyl acrylate random copolymers filled with carbon black

Emulsion‐polymerized poly(styrene‐rand‐butyl acrylate) (St–BA) copolymers exhibit damping capabilities over a wide temperature range with changes in the monomer ratio. Blending copolymers of different compositions results in a multidamping peak, further widening the effective damping temperature range. Adding carbon black (CB) reduces the peak damping intensity but enhances damping at higher temperatures. The addition of dodecyl benzene sulfonic acid to an St–BA/CB aqueous dispersion improves the dispersion of CB in the polymer, reducing the percolation threshold and improving the conductivity while slightly affecting the mechanical behavior. The electrical properties of the St–BA/CB system are affected by the copolymer composition, influencing the polymer surface tension. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

How important is the interfacial chemical bond for electron transport through alkyl chain monolayers?

We show that the electrode/molecule chemical bond does not change the tunneling barrier for charge transport through alkyl chain monolayers sandwiched between Si and Hg electrodes. This observation can be understood if the interfacial bond mainly governs the monolayer's structure, while the electronic states due to molecule-electrode bonding do not contribute significantly to tunneling. Yet, the nature of the bond affects the Schottky barrier inside the semiconductor due to changes in the interface dipole.     

Thermodynamic factors in partitioning and rejection of organic compounds by polyamide composite membranes

The paper analyzes the mechanism of partitioning and rejection of organic solutes by polyamide membranes for reverse osmosis and nanofiltration. The partitioning of homologous series of alcohols and polyols, in which polarity changes with size in opposite ways, was measured using attenuated total reflection IR spectroscopy. The results show that the partitioning of polyols monotonously decreases with size, whereas for alcohols it is not monotonous and slightly decreases for small C1-C3 alcohols followed by a sharp increase for larger alcohols. These results may be explained by assuming a heterogeneous structure of polyamide comprising a hydrophobic polyamide matrix and a polar internal aqueous phase. The partitioning data could consistently explain the results of rejection in standard filtration experiments. They clearly demonstrate that high/low partitioning may play a significant role in achieving a low/high rejection of organics. In particular, this points to the need to account for the partitioning effect while using molecular probes such as polyols or sugars for estimating the effective "pore" size or molecular weight cutoff of a membrane and for choosing/developing organic-rejecting membranes.     

Universal lossless source controlled channel decoding for i.i.d. sequences

Messages coded and transmitted over a channel usually contain some redundancy which is not utilized by channel decoding techniques, especially if its governing statistical parameters are unknown. We propose to integrate universal lossless source coding techniques into channel decoding of redundant sequences with unknown statistics to improve performance of Viterbi and turbo decoding. Simulation results demonstrate that we achieve identical bit error rate (BER) performance to nonuniversal techniques that utilize prior knowledge of the message statistics and that if redundancy exists even in an a-priori unknown form, we can improve the code performance over standard techniques.     

Efficient Cache Attacks on AES, and Countermeasures

We describe several software side-channel attacks based on inter-process leakage through the state of the CPU’s memory cache. This leakage reveals memory access patterns, which can be used for cryptanalysis of cryptographic primitives that employ data-dependent table lookups. The attacks allow an unprivileged process to attack other processes running in parallel on the same processor, despite partitioning methods such as memory protection, sandboxing, and virtualization. Some of our methods require only the ability to trigger services that perform encryption or MAC using the unknown key, such as encrypted disk partitions or secure network links. Moreover, we demonstrate an extremely strong type of attack, which requires knowledge of neither the specific plaintexts nor ciphertexts and works by merely monitoring the effect of the cryptographic process on the cache. We discuss in detail several attacks on AES and experimentally demonstrate their applicability to real systems, such as OpenSSL and Linux’s dm-crypt encrypted partitions (in the latter case, the full key was recovered after just 800 writes to the partition, taking 65 milliseconds). Finally, we discuss a variety of countermeasures which can be used to mitigate such attacks.     

Low-complexity sequential lossless coding for piecewise-stationarymemoryless sources

Three strongly sequential, lossless compression schemes, one with linearly growing per-letter computational complexity, and two with fixed per-letter complexity, are presented and analyzed for memoryless sources with abruptly changing statistics. The first method, which improves on Willems' (1994) weighting approach, asymptotically achieves a lower bound on the redundancy, and hence is optimal. The second scheme achieves redundancy of O(log N/N) when the transitions in the statistics are large, and O (log log N/log N) otherwise. The third approach always achieves redundancy of O (√log N/N). Obviously, the two fixed complexity approaches can be easily combined to achieve the better redundancy between the two. Simulation results support the analytical bounds derived for all the coding schemes     

Nanocomposite Hydrogels as Platform for Cells Growth,Proliferation, and Chemotaxis

The challenge of mimicking the extracellular matrix with artificial scaffolds that are able to reduce immunoresponse is still unmet. Recent findings have shown that mesenchymal stem cells (MSC) infiltrating into the implanted scaffold have effects on the implant integration by improving the healing process. Toward this aim, a novel polyamidoamine‐based nanocomposite hydrogel is synthesized, cross‐linked with porous nanomaterials (i.e., mesoporous silica nanoparticles), able to release chemokine proteins. A comprehensive viscoelasticity study confirms that the hydrogel provides optimal structural support for MSC infiltration and proliferation. The efficiency of this hydrogel, containing the chemoattractant stromal cell‐derived factor 1α (SDF‐1α), in promoting MSC migration in vitro is demonstrated. Finally, subcutaneous implantation of SDF‐1α‐releasing hydrogels in mice results in a modulation of the inflammatory reaction. Overall, the proposed SDF‐1α‐nanocomposite hydrogel proves to have potential for applications in tissue engineering.