全文获取类型
收费全文 | 1933篇 |
免费 | 78篇 |
国内免费 | 8篇 |
专业分类
电工技术 | 37篇 |
综合类 | 1篇 |
化学工业 | 473篇 |
金属工艺 | 67篇 |
机械仪表 | 31篇 |
建筑科学 | 17篇 |
矿业工程 | 3篇 |
能源动力 | 93篇 |
轻工业 | 78篇 |
水利工程 | 22篇 |
石油天然气 | 17篇 |
无线电 | 252篇 |
一般工业技术 | 427篇 |
冶金工业 | 223篇 |
原子能技术 | 2篇 |
自动化技术 | 276篇 |
出版年
2023年 | 15篇 |
2022年 | 35篇 |
2021年 | 47篇 |
2020年 | 32篇 |
2019年 | 41篇 |
2018年 | 66篇 |
2017年 | 49篇 |
2016年 | 45篇 |
2015年 | 33篇 |
2014年 | 72篇 |
2013年 | 163篇 |
2012年 | 85篇 |
2011年 | 104篇 |
2010年 | 78篇 |
2009年 | 65篇 |
2008年 | 78篇 |
2007年 | 86篇 |
2006年 | 56篇 |
2005年 | 56篇 |
2004年 | 39篇 |
2003年 | 52篇 |
2002年 | 45篇 |
2001年 | 30篇 |
2000年 | 32篇 |
1999年 | 25篇 |
1998年 | 74篇 |
1997年 | 55篇 |
1996年 | 32篇 |
1995年 | 30篇 |
1994年 | 30篇 |
1993年 | 37篇 |
1992年 | 23篇 |
1991年 | 30篇 |
1990年 | 34篇 |
1989年 | 17篇 |
1988年 | 14篇 |
1987年 | 20篇 |
1986年 | 17篇 |
1985年 | 16篇 |
1984年 | 19篇 |
1983年 | 15篇 |
1982年 | 15篇 |
1981年 | 19篇 |
1980年 | 18篇 |
1979年 | 15篇 |
1978年 | 9篇 |
1977年 | 9篇 |
1976年 | 11篇 |
1975年 | 5篇 |
1973年 | 6篇 |
排序方式: 共有2019条查询结果,搜索用时 15 毫秒
101.
Freestanding fiber mats of zeolitic imidazolate framework 7 via one‐step,scalable electrospinning
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Seongpil An Ji Sun Lee Bhavana N. Joshi Hong Seok Jo Kirill Titov Jong‐San Chang Chul‐Ho Jun Salem S. Al‐Deyab Young Kyu Hwang Jin‐Chong Tan Sam S. Yoon 《应用聚合物科学杂志》2016,133(32)
We demonstrated the fabrication of freestanding zeolitic imidazolate framework 7 (ZIF‐7) nanofiber (NF) mats by means of one‐step, scalable electrospinning. The formation of ZIF‐7 nanoparticles embedded in polymer fibers was unambiguously pinpointed via X‐ray diffraction, transmission electron microscopy, and adsorption studies. The NF mats exhibited excellent characteristics, with an average diameter of 245 nm, in the adsorption and desorption of carbon dioxide (CO2); this makes them attractive candidates for gas separation and other selective filtration applications. This excellent property of the ZIF‐7 mats was explained by the gate‐opening phenomenon of ZIF‐7, which yielded a stepwise increase in the overall CO2 uptake capacity. The mechanical strength of the NF mats was also obtained via large‐strain uniaxial tensile deformation, which enabled preliminary assessment of the mat's suitability for textiles and membranes in targeting separation and filtration applications with large‐area permeability. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43788. 相似文献
102.
The effect of through thickness reinforced open-hole laminates was analysed in terms of laminate behaviour under in-plane tensile loading based on continuum mechanics. Stitches around the notch were oriented in the longitudinal and transverse directions. To obtain the macroscopic damage and the local stress–strain constitutive behaviour, laminates were modelled on a lamina-wise basis. Interfaces between lamina and stitch yarns were assumed to be perfectly glued and modelled by the contact capability. Discretisation procedures using the principle of virtual work were applied in addition to discretisation of the contact traction. Progressive failure analysis with Puck’s failure criteria was conducted to characterise the failure behaviour of the laminate. In both cases, damage was initiated by a matrix crack in the perpendicular direction of the loading axis on the notch. The longitudinally stitched laminate showed a 14.29% higher strength compared to the transversely stitched laminate by suppressing damage propagation. The results obtained using this finite element technique was consistent with the experimental results. 相似文献
103.
Akshay V. Joshi Christoph Dettke Joseph Steingraeber 《Journal of Coatings Technology and Research》2016,13(2):375-383
Gravure is a high throughput printing process, normally associated with speed, quality, and long print runs. It is widely used for printing on shrink films and other substrates. The shrink films, in particular, polyvinyl chloride (PVC) and glycol-modified polyethylene terephthalate (PET-G), are two dominant substrates widely consumed and printed by gravure process. The PVC and PET-G offer different properties which greatly influence the printability. The surface energy of the substrate determines the adhesion and wettability of ink, while electrical properties such as surface and volume resistivity impact electrostatic assist (ESA) performance. The introduction of ESA in gravure further improved the print quality by eliminating dot skips with reduced impression pressure. However, print defects such as print mottle is inevitable. Print mottle occurs due to a discrepancy between substrate, ink, and process parameters which degrade the print quality. These complexities need to be addressed to deliver higher productivity with less print waste. Therefore, the study investigates the effect of process parameters, i.e., substrate type, line screen, air gap (distance between charge bar and impression roller), viscosity, voltage, and speed, and aims to quantify their effect numerically on defect minimization. The Design of Experiments (DOE) was generated for the above-mentioned parameters and analyzed to extract the best combination of process parameters. The optimized setting showed a reduction in solid mottle by 54% and 57% for PET-G and PVC, respectively. 相似文献
104.
Sapana Guru Deepti Mishra Manju Singh Sudhir Sitaram Amritphale Smita Joshi 《Protection of Metals and Physical Chemistry of Surfaces》2016,52(4):627-631
In the present work iron oxide nanoparticles have been prepared by microwave assisted synthesis with the influence of different precursor salts and synthesis of magnetite, hematite, Iron oxide hydroxide and maghemite nanoparticles. Synthesized iron oxide nanoparticles were characterized with Infrared Spectroscopy (FTIR), Field Emission Scanning Electron Microscopy (FESEM), and Energy-dispersive X-ray Spectroscopy (EDX). XRD measurements show that the peaks of diffractogram are in agreement with the theoretical data of magnetite, hematite, FeO(OH) (Iron oxide hydroxide) and maghemite. Crystallite size of the particles was found to be 33, 45, 36 and 43.5 nm for Fe3O4, α-Fe2O3, FeO(OH) and γ-Fe2O3. FESEM studies indicated that size of the particles is observed in the range of about 19.4 to 46.7 nm (Fig. 2a, average 32 nm), 29.1 to 67.6 nm (Fig. 2b average 45 nm), 29.1 to 40.8 (Fig. 2c average 36.6 nm), 29.1 to 80 nm (Fig. 2d average 43.5) for Fe3O4, α-Fe2O3, FeO(OH) and γ-Fe2O3 respectively. EDX spectral analysis reveals the presence of carbon, oxygen, iron in the synthesized nanoparticles. The FTIR graphs indicated absorption bands due to O–H stretching, C–O bending, C–H stretching and Fe–O stretching vibrations. 相似文献
105.
Shashank S. Tiwari Swapnil V. Ghatage Jyeshtharaj B. Joshi Bo Kong 《American Institute of Chemical Engineers》2022,68(8):e17725
Multifluid model (MFM) simulations have been carried out on liquid–solid fluidized beds (LSFB) consisting of binary and higher-order polydisperse particle mixtures. The role of particle–particle interactions was found to be as crucial as the drag force under laminar and homogenous LSFB flow regimes. The commonly used particle–particle closure models are designed for turbulent and heterogeneous gas–solid flow regimes and thus exhibit limited to no success when implemented for LSFB operating under laminar and homogenous conditions. A need is perceived to carry out direct numerical simulations of liquid–solid flows and extract data from them to develop rational closure terms to account for the physics of LSFB. Finally, a recommendation flow regime map signifying the performance of the MFM has been proposed. This map will act as a potential guideline to identify whether or not the bed expansion characteristics of a given polydisperse LSFB can be correctly simulated using MFM closures tested. 相似文献
106.
Flow and temperature patterns in an inductively coupled plasma reactor: Experimental measurements and CFD simulations
下载免费PDF全文
![点击此处可从《American Institute of Chemical Engineers》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Sangeeta B. Punjabi Sunil N. Sahasrabudhe S. Ghorui A. K. Das Narendra K. Joshi Dushyant C. Kothari Arijit A. Ganguli Jyeshtharaj B. Joshi 《American Institute of Chemical Engineers》2014,60(10):3647-3664
Measurements of temperature patterns in an inductively coupled plasma (ICP) have been carried out experimentally. Plasma torch was operated at different RF powers in the range of 3–14 kW at near atmospheric pressure and over a wide range of sheath gas flow rate (3–25 lpm). Measurements were made at five different axial positions in ICP torch. The chordal intensities were converted into a radial intensity profile by Abel Inversion technique. Typical radial temperature profile shows an off‐axis temperature peak, which shifts toward the wall as the power increases. Temperatures in the range of 6000–14,000 K were recorded by this method. The temperature profiles in the plasma reactor were simulated using computational fluid dynamics (CFD). A good agreement was found between the CFD predictions of the flow and temperature pattern with those published in the literature as well as the temperature profiles measured in the present work. © 2014 American Institute of Chemical Engineers AIChE J, 60: 3647–3664, 2014 相似文献
107.
Sangram K. Rath Vinod K. Aswal Chandan Sharma Kapil Joshi Manoranjan Patri G. Harikrishnan Devang V. Khakhar 《Polymer》2014
The objective of the present work is to get insights into the mechanistic origin of the reinforcement effects of nanoclay on a segmented polybutadiene polyurethane-urea system. To this end, a convergent analysis of the hard domain morphology and conformational state of soft segment in the nanocomposites was carried out by using a combination of complementary characterization techniques, namely, Fourier transform infrared spectroscopy, small angle neutron scattering, transmission electron microscopy, modulated differential scanning calorimetry and dynamic mechanical analysis. Analysis of small angle neutron scattering data by a combination of Percus–Yevick hard sphere and Zernike-Ornstein model coupled with direct visualization of the dispersed hard domain morphology from transmission electron microscopy provided insight on clay induced changes in the hard domain morphology. A monotonic decrease in the domain size as well as the average interdomain distance was observed with increasing nanoclay content in the polymer matrix. Analysis of the carbonyl stretching region from FTIR showed increased degree of hydrogen bonding for the urethane carbonyl groups of the nanocomposites compared to the neat matrix. A combination of calorimetric and dynamic mechanical analysis revealed the existence of a constrained amorphous region; quantified to be ≈ 16% at the highest clay content experimented. The manifestation of these morphological and conformational changes on the nano-, micro- and macro scale reinforcements in the nanocomposites was investigated by mechanical properties at these length scales using nanoindentation, DMA and tensile testing, respectively. 相似文献
108.
Drug‐loaded polyurethane/clay nanocomposite nanofibers for topical drug‐delivery application
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
In this study, polyurethane/nanoclay nanocomposite nanofibrous webs were prepared by electrospinning. An antiseptic drug, chlorhexidine acetate (CA), was loaded onto montmorillonite clay and was then incorporated into polyurethane nanofibers. For comparison, the CA drug was loaded directly into the polyurethane solution dope used to electrospin the nanofibers. The emphasis was on investigating the effect of the drug loading into the nanoclay vis‐à‐vis direct drug loading on the drug‐release behavior of nanofibrous webs. The nanofibrous webs were also evaluated for other properties, such as moisture vapor transmission, porosity determination, contact angle measurement, and antibacterial activity, which are important for topical drug‐delivery application. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40230. 相似文献
109.
Anoop K. Mukhopadhyay Keshaw D. Joshi Arjun Dey Riya Chakraborty Ashok K. Mandal Amit Rav Jiten Ghosh Sandip Bysakh Sampad K. Biswas Satish C. Gupta 《Ceramics International》2011,37(7):2365-2376
Shock recovered samples of a coarse grain (10 μm), high density (>99.9% theoretical) alumina from asymmetric impact tests conducted at 6.5 GPa (e.g. 3.2 times its Hugoniot Elastic Limit) in a single stage gas gun and characterized by X-ray diffractometry, scanning and field emission scanning electron microscopy, and transmission electron microscopy showed prolific presence of reduced crystallite size, higher average microstrain, grain localized micro/nano-scale deformations, micro-cleavages, grain-boundary microcracks, micro-wing crack formation, extensive shear induced deformations and fractures localized at grains, grain boundaries and triple grain junctions, grain localized entanglement of dislocations and their pile up impeded at grain boundaries. A new qualitative model based on micro-shear and micro-twist induced deformation and fracture in single and/or multiple planes in suitably oriented grain and/or grain assembly was developed to explain the experimentally observed damage evolution process. 相似文献
110.
A rat epididymal protein of 27 kDa was identified using neonatal tolerization. This study reports the production and characterization of a polyclonal antiserum to this protein. ELISA was used to demonstrate that this antiserum reacts strongly with epididymal sperm proteins, but has little or no reactivity with testicular proteins. Western blot analysis revealed that this polyclonal antiserum recognized a 27 kDa protein extracted from the corpus epididymidis as well as from spermatozoa from the corpus and cauda epididymides, and immunostaining revealed the presence of the protein in the corpus to cauda epididymides. Stronger reactivity was observed in the supranuclear region and stereocilla of principal cells of the corpus epididymidis and in the luminal content of the corpus and cauda epididymides. The testicular section showed no reactivity. Treatment with the antiserum resulted in time- and dose-dependent agglutination of rat spermatozoa. By indirect immunofluorescence, the antiserum localized proteins in the mid-piece region of rat spermatozoa. Studies were carried out to determine the age at which the protein first became apparent during postnatal development. The protein was expressed from day 40 onwards, as demonstrated by western blot analysis. The androgen regulation of this protein was ascertained by castration and supplementation studies. Expression of this protein showed a decline starting at day 14 after castration and by day 21 the protein was absent; however, androgen replacement resulted in the reappearance of the protein. The results of these studies indicate that the protein identified is specific to the epididymis, and is regulated by development and androgens. The importance of epididymis-specific proteins that are regulated by androgens in sperm maturation is discussed, and the need to ascertain the sequence of the protein and clone the cognate gene is indicated. 相似文献