Unleashing the Potential of Sodium-Ion Batteries: Current State and Future Directions for Sustainable Energy Storage

Rechargeable sodium-ion batteries (SIBs) are emerging as a viable alternative to lithium-ion battery (LIB) technology, as their raw materials are economical, geographically abundant (unlike lithium), and less toxic. The matured LIB technology contributes significantly to digital civilization, from mobile electronic devices to zero electric-vehicle emissions. However, with the increasing reliance on renewable energy sources and the anticipated integration of high-energy-density batteries into the grid, concerns have arisen regarding the sustainability of lithium due to its limited availability and consequent price escalations. In this context, SIBs have gained attention as a potential energy storage alternative, benefiting from the abundance of sodium and sharing electrochemical characteristics similar to LIBs. Furthermore, high-entropy chemistry has emerged as a new paradigm, promising to enhance energy density and accelerate advancements in battery technology to meet the growing energy demands. This review uncovers the fundamentals, current progress, and the views on the future of SIB technologies, with a discussion focused on the design of novel materials. The crucial factors, such as morphology, crystal defects, and doping, that can tune electrochemistry, which should inspire young researchers in battery technology to identify and work on challenging research problems, are also reviewed.     

Energy Efficient Broadcast in Wireless Ad hoc Networks with Hitch-hiking

In this paper, we propose a novel concept called Hitch-hiking in order to reduce the energy consumption of broadcast application for wireless networks. Hitch-hiking takes advantage of the physical layer design that facilitates the combining of partial signals to obtain the complete information. The concept of combining partial signals using maximal ratio combiner [15] has been used to improve the reliability of the communication link but has never been exploited to reduce energy consumption in broadcasting over wireless ad hoc networks. We study the advantage of Hitch-hiking for the scenario when the transmission power level of nodes is fixed as well as the scenario when the nodes can adjust their power level. For both scenarios, we show that Hitch-hiking is advantageous and have proposed algorithms to construct broadcast tree with Hitch-hiking taken into consideration. For fixed transmission power case, we propose and analyze a centralized heuristic algorithm called SPWMH (Single Power Wireless Multicast with Hitch-hiking) to construct a broadcast tree with minimum forwarding nodes. For the latter case, we propose a centralized heuristic algorithm called Wireless Multicast with Hitch-hiking (WMH) to construct an energy efficient tree using Hitch-hiking and also present a distributed version of the heuristic. We also evaluate the proposed heuristics through simulation. Simulation results show that Hitch-hiking can reduce the transmission cost of broadcast by as much as 50%. Further, we propose and evaluate a protocol called Power Saving with Broadcast Tree (PSBT) that reduces energy consumption of broadcast by eliminating redundancy in receive operation. Finally, we propose an algorithm that takes advantage of both Hitch-hiking and PSBT in conserving energy. Manish Agarwal is an engineer at Microsoft, Redmond. He received his Masters degree in Electrical and Computer Engineering from University of Massachusetts, Amherst in 2004. He received his undergraduate degree from Indian Institute of Technology, Guwahati. His research interest lies in the field of mobile ad hoc networks. Lixin Gao is an associate professor of Electrical and Computer Engineering at the University of Masschusetts, Amherst. She received her Ph.D. degree in computer science from the University of Massachusettes at Amherst in 1996. Her research interests include multimedia networking and Internet routing. Between May 1999 and January 2000, she was a visiting researcher at AT&T Research Labs and DIMACS. She is an Alfred P. Sloan Fellow and received an NSF CAREER Award in 1999. She is a member of IEEE, ACM, and Sigma Xi. Joon Ho Cho received the B.S. degree (summa cum laude) in electrical engineering from Seoul National University, Seoul, Korea, in 1995 and the M.S.E.E. and Ph.D. degrees in electrical and computer engineering from Purdue University, West Lafayette, IN, in 1997 and 2001, respectively. From 2001 to 2004, he was with the University of Massachusetts at Amherst as an Assistant Professor. Since July 2004, he has been with Pohang University of Science and Technology (POSTECH), Pohang, Korea, where he is presently an Assistant Professor in the Department of Electronic and Electrical Engineering. His research interests include wideband systems, multiuser communications, adaptive signal processing, packet radio networks, and information theory. Dr. Cho is currently an Associate Editor for the IEEE Transactions on Vehicular Technology. Jie Wu is a Professor at Department of Computer Science and Engineering, Florida Atlantic University. He has published over 300 papers in various journal and conference proceedings. His research interests are in the area of mobile computing, routing protocols, fault-tolerant computing, and interconnection networks. Dr. Wu served as a program vice chair for 2000 International Conference on Parallel Processing (ICPP) and a program vice chair for 2001 IEEE International Conference on Distributed Computing Systems (ICDCS). He is a program co-chair for the IEEE 1st International Conference on Mobile Ad-hoc and Sensor Systems (MASS'04). He was a co-guest-editor of a special issue in IEEE Computer on “Ad Hoc Networks”. He also editored several special issues in Journal of Parallel and Distributing Computing (JPDC) and IEEE Transactions on Parallel and Distributed Systems (TPDS). He is the author of the text “Distributed System Design” published by the CRC press. Currently, Dr. Wu serves as an Associate Editor in IEEE Transactions on Parallel and Distributed Systems and three other international journals. Dr. Wu is a recipient of the 1996–97 and 2001–2002 Researcher of the Year Award at Florida Atlantic University. He served as an IEEE Computer Society Distinguished Visitor. Dr. Wu is a Member of ACM and a Senior Member of IEEE.     

Reducing Encoder Bit-Rate Variation in MPEG Video

A shortcoming of current video transmission using the MPEG standard is that its encoder produces a variable bit rate (VBR). Due to this, the encoder output has to be buffered and released over the network at a constant rate. This buffering of the encoder output introduces an additional delay between the encoding and decoding phases of the video transmission. To remedy this problem, we present a strategy to distribute the load produced by the encoder as evenly as possible, i.e., try to have a constant bit rate (CBR). This is done by treating the slices in each frame separately while compressing them and then mixing the different kinds of slices that are sent over the network. The resulting load variation is much more uniform, reducing the buffering delay and making future bandwidth requirement estimates more accurate.This material is based upon work supported in part by the National Science Foundation under Award No. IRI-9526004, by the Texas Advanced Research Program under Grant No. 3652270, and by a grant from the University of Houston Institute of Space Systems Operations. Rajat Agarwal is now with Lucent Technologies. This paper is an extended version of a shorter paper presented at IEEE ICMCS 1999.Albert Mo Kim Cheng received the B.A. with Highest Honors in Computer Science at age 19, graduating Phi Beta Kappa, the M.S. in Computer Science with a minor in Electrical Engineering at age 21, and the Ph.D. in Computer Science at age 25, all from The University of Texas at Austin, where he held a GTE Foundation Doctoral Fellowship. Dr. Cheng is currently a tenured Associate Professor in the Department of Computer Science at the University of Houston, where he is the founding Director of the Real-Time Systems Laboratory. He has served as a technical consultant for several organizations, including IBM, and was also a visiting faculty in the Departments of Computer Science at Rice University (2000) and at the City University of Hong Kong (1995).He is the author/co-author of over seventy refereed publications in IEEE Transactions on Software Engineering, IEEE Transactions on Knowledge and Data Engineering, Real-Time Systems Symposium, Real-Time and Embedded Technology and Applications Symposium, and other leading conferences. One of his recent work presents a timing analysis of the NASA X-38 Space Station Crew Return Vehicle Avionics, which contains a fault-tolerant distributed system.Dr. Cheng has received numerous awards, including the National Science Foundation Research Initiation Award (now known as the NSF CAREER award). He has been invited to present seminars and tutorials at over 30 conferences, and has given invited seminars/keynotes at over 20 universities and organizations, most recently at ICEIS, Ecole Superieure de l Ouest (ESEO), Angers, France, April 2003. His next invited keynote speech will be at the 1st Intl. Conf. on Informatics in Control, Automation and Robotics (ICINCO), Setubal, Portugal, August 2004.He is an Associate Editor of the IEEE Transactions on Software Engineering (1998-2003), a Guest Co-Editor of two IEEE TSE Special Issues on Software and Performance (Nov. and Dec. 2000), an Associate Editor of the International Journal of Computer and Information Science, the work-in-progress program chair of the 2001 IEEE-CS Real-Time Technology and Applications Symposium, the work-in-progress session chair of the 2003 IEEE-CS Real-Time Systems Symposium, and the invited special panel chair for the software engineering for multimedia session at the 1999 IEEE-CS International Conference on Multimedia Computing Systems (ICMCS). Currently, he is a member of the program committees of RTSS, RTAS, ICEIS, ICECCS, RTAS, LCN, COMPSAC, ICCCN, AIA, DBA, PDCN, SE, and ICINCO. Dr. Cheng is an Honorary Member of the Institute for Systems and Technologies of Information, Control and Communication (INSTICC). He is a Senior Member of the IEEE.Dr. Cheng is the author of several book chapters on E-commerce/Enterprise Information Systems, and an article entitled Embedded OS, in the upcoming Encyclopedia of Computer Science and Engineering (John Wiley & Sons). He is the author of the new senior/graduate-level textbook entitled Real-Time Systems: Scheduling, Analysis, and Verification (John Wiley & Sons). cheng@cs.uh.eduRajat Agarwal received the M.S. in Computer Science from the University of Houston. He is currently a Member of the Technical Staff at Lucent Technologies. His research interest is in real-time multimedia systems.     

Assimilation of altimeter significant wave height into a third-generation global spectral wave model

Data from three different altimeters (Topex/Poseidon, Jason-1, and European Remote Sensing Satellite 2) have been assimilated in a third-generation global spectral wave model forced by winds observed by scatterometer onboard QuikSCAT. Two different approaches of assimilation have been discussed. In the first approach, a simple scaling has been used to generate wave spectrum from altimeter-derived significant wave heights for assimilation in the model. In the second approach, the influence of altimeter observation has been spread to nearby grid points. Assimilation has been carried out every 6 h for five days. After the expiry of the assimilation phase, the model has been run in pure hindcast mode. Assimilation experiments have been carried out for the months of September and December 2002. Impact of assimilation has been found to be quite high in the Indian Ocean. It has been also found that the model is able to retain the memory of assimilation for a period of two and a half days as far as global ocean is concerned. This memory is more for the Indian Ocean. The wave spectrum generated by the model in the hindcast mode has been validated against the buoy-observed wave spectrum in the high sea conditions. The more significant impact has been seen in the case of altimeter track in the vicinity of the buoy.     

Optimal Non-Invasive Fault Classification Model for Packaged Ceramic Tile Quality Monitoring Using MMW Imaging

Millimeter wave (MMW) frequency has emerged as an efficient tool for different stand-off imaging applications. In this paper, we have dealt with a novel MMW imaging application, i.e., non-invasive packaged goods quality estimation for industrial quality monitoring applications. An active MMW imaging radar operating at 60 GHz has been ingeniously designed for concealed fault estimation. Ceramic tiles covered with commonly used packaging cardboard were used as concealed targets for undercover fault classification. A comparison of computer vision-based state-of-the-art feature extraction techniques, viz, discrete Fourier transform (DFT), wavelet transform (WT), principal component analysis (PCA), gray level co-occurrence texture (GLCM), and histogram of oriented gradient (HOG) has been done with respect to their efficient and differentiable feature vector generation capability for undercover target fault classification. An extensive number of experiments were performed with different ceramic tile fault configurations, viz., vertical crack, horizontal crack, random crack, diagonal crack along with the non-faulty tiles. Further, an independent algorithm validation was done demonstrating classification accuracy: 80, 86.67, 73.33, and 93.33 % for DFT, WT, PCA, GLCM, and HOG feature-based artificial neural network (ANN) classifier models, respectively. Classification results show good capability for HOG feature extraction technique towards non-destructive quality inspection with appreciably low false alarm as compared to other techniques. Thereby, a robust and optimal image feature-based neural network classification model has been proposed for non-invasive, automatic fault monitoring for a financially and commercially competent industrial growth.     

Model-based seizure detection for intracranial EEG recordings

This paper presents a novel model-based patient-specific method for automatic detection of seizures in the intracranial EEG recordings. The proposed method overcomes the complexities in the practical implementation of the patient-specific approach of seizure detection. The method builds a seizure model (set of basis functions) for a priori known seizure (the template seizure pattern), and uses the statistically optimal null filters as a building block for the detection of similar seizures. The process of modeling the template seizure is fully automatic. Overall, the detection method involves the segmentation of the template seizure pattern, rejection of the redundant and noisy segments, extraction of features from the segments to generate a set of models, selection of the best seizure model, and training of the classifier. The trained classifier is used to detect similar seizures in the remaining data. The resulting seizure detection method was evaluated on a total of 304 h of single-channel depth EEG recordings from 14 patients. The system performance is further compared to the Qu-Gotman patient-specific system using the same data. A significant improvement in the proposed system, in terms of specificity, is observed over the compared method.     

Mechanical Properties of Conjugated Polymers and Polymer‐Fullerene Composites as a Function of Molecular Structure

Despite the importance of mechanical compliance in most applications of semiconducting polymers, the effects of structural parameters of these materials on their mechanical properties are typically not emphasized. This paper examines the effect of length of the pendant group on the tensile modulus and brittleness for a series of regioregular poly(3‐alkylthiophenes) (P3ATs) and their blends with a soluble fullerene derivative, PCBM. The tensile modulus decreases with increasing length of the alkyl side‐chain, from 1.87 GPa for butyl side chains to 0.16 GPa for dodecyl chains. The moduli of P3AT:PCBM blends films are greater than those of the pure polymers by factors of 2–4. A theoretical model produces a trend in the effect of alkyl side chain on tensile modulus that follows closely to the experimental measurements. Tensile modulus correlates with brittleness, as the strain at which cracks appear is 6% for P3BT and >60% for P3OT. Adhesion of the P3AT film to a polydimethylsiloxane (PDMS) substrate is believed to play a role in an apparent increase in brittleness from P3OT to P3DDT. The additive 1,8‐Diiodooctane (DIO) reduces the modulus of P3HT:PCBM blend by a factor of 3. These results could enable mechanically robust, flexible, and stretchable electronics.     

Data fusion with flexible message composition in Driver-in-the-Loop vehicular CPS

This work addresses a unique data fusion problem in Vehicular Cyber-Physical Systems (VCPS) arising from Human Factors (HF) considerations. Typically, a VCPS message intended for human drivers is composed of many data elements (DEs), and different messages can be fused by the sender before transmission e.g., by eliminating identical (or redundant) DEs in order to save transmission bandwidth in the wireless network. Still, not all distinct DEs can be received properly due to the limited transmission resources available to the sender and/or transmission errors. Subsequently, some of the messages intended for a driver cannot be delivered. On the other hand, a partially delivered message may still be beneficial (in terms of generating some utility) to a driver. More specifically, when considering HF, the DEs can be grouped into two distinct parts: essential and auxiliary. While a partially reconstructed message missing even a single essential DE fails to produce any benefit (or utility) for a driver, each auxiliary DE can independently produce an additional utility so long as all the essential DEs of the message are also available.In this paper, we deal with a new Driver-in-the-Loop Data Fusion Problem (DDFP) with the primary issue being: given a list of out-going messages and a limit on the number of DEs that can be transmitted, how does the sender choose which DEs (each carrying a different utility) to transmit, in order to maximize the system-wide utility at the receiver. We formulate DDFP mathematically, and prove it to be NP-Complete. We study DDFP in both ideal and lossy communication networks, and propose several efficient algorithms for them. Besides the Single-Sender-Single-Receiver model, we also look into DDFP in Multiple-Sender-Single-Receiver and Single-Sender-Multiple-Receiver models with several practical considerations. Numerical results from large scale simulations are also presented.     

Pure Blue Electroluminescence by Differentiated Ion Motion in a Single Layer Perovskite Device

Blue electroluminescence is highly desired for emerging light-emitting devices for display applications and optoelectronics in general. However, saturated, efficient, and stable blue emission has been challenging to achieve, particularly in mixed-halide perovskites, where intrinsic ion motion and halide segregation compromises spectral purity. Here, CsPbBr_3−xCl_x perovskites, polyelectrolytes, and a salt additive are leveraged to demonstrate pure blue emission from single-layer light-emitting electrochemical cells (LECs). The electrolytes transport the ions from salt additives, enhancing charge injection and stabilizing the inherent perovskite emissive lattice for highly pure and sustained blue emission. Substituting Cl into CsPbBr₃ tunes the perovskite luminescence from green through blue. Sky blue and saturated blue devices produce International Commission on Illumination coordinates of (0.105, 0.129) and (0.136, 0.068), respectively, with the latter meeting the US National Television Committee standard for the blue primary. Likewise, maximum luminances of 2900 and 1000 cd m⁻², external quantum efficiencies (EQEs) of 4.3% and 3.9%, and luminance half-lives of 5.7 and 4.9 h are obtained for sky blue and saturated blue devices, respectively. Polymer and LiPF₆ inclusion increases photoluminescence efficiency, suppresses halide segregation, induces thin-film smoothness and uniformity, and reduces crystallite size. Overall, these devices show superior performance among blue perovskite light-emitting diodes (PeLEDs) and general LECs.     

Flexible,Mechanically Stable,Porous Self-Standing Microfiber Network Membranes of Covalent Organic Frameworks: Preparation Method and Characterization

Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m² g⁻¹), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future.