Analysis of multiple steady states of complex biochemical reactions

A general theory for the identification of criteria within which an enzymic reaction can exhibit multiplicity (i.e. multiple steady states) is reviewed. Application of the theory to four types of kinetic models encountered in biochemical reactions is illustrated and figures are presented to delineate the region of multiplicity. The stability of the steady states is analysed for small perturbation about the steady state.     

An Adjustable-Speed Induction Motor Drive with a Cycloconverter-Type Thyristor-Commutator in the Rotor

An adjustable-speed drive comprising a slip-ring induction motor and a cycloconverter-type thyristor-commutator in its rotor circuit has been developed. The thyristor-commutator acts as a frequency-changer like a conventional commutator in a stator-fed ac commutator motor, converting line-frequency injected voltages directly to slip-frequency at the rotor terminals. The circuit permits a reversible power flow naturally, and speed-control is possible for subsynchronous as well as supersynchronous operation by controlling the injected secondary voltage. A rotor position-detector is used to switch the thyristor configuration in a sequential manner to generate an output voltage having a predominant slip-frequency component. The control logic and triggering circuit developed for the experimental drive are described in some detail. Experimental results as obtained with a laboratory model are presented together with some results of computer simulation of the drive system. Major limitations of the scheme and the scope for improvement are discussed.     

Blends of polypropylene and ethylene octene comonomer with conducting fillers: Influence of state of dispersion of conducting fillers on electrical conductivity

Blends of polypropylene/ethylene octene comonomer (PP/EOC) with conducting fillers viz., carbon black (CB) and multiwall carbon nanotubes (MWNT) were prepared using melt mixing technique with varying filler concentration and blend compositions. Thermo gravimetric analysis studies indicated that presence of filler enhanced the thermal stability of PP/EOC blends. Morphological analysis revealed the formation of matrix‐dispersed droplet and co‐continuous type of morphology depending on the blend compositions. Significant reduction in droplet size and finer ligament thickness in co‐continuous structure were observed in the blends with filler due to compatibilization action. Fillers were found to be aggregated in the EOC phase irrespective of blends compositions and could be related to the affinity of the fillers toward EOC phase. The electrical conductivity of PP/EOC blends with CB and MWNT was found to be highest for 80/20 composition and decreased as EOC content increased. The percolation threshold of CB was between 10 and 15 wt% for the 80/20 and 70/30 blends whereas it was 15–20 wt% for blends with EOC content higher than 30 wt%. The percolation threshold was 2–3 wt% MWNT for PP/EOC blends. This was attributed to the aggregated filler network preferentially in the EOC phase. The melt‐rheological behavior of PP/EOC blends was significantly influenced in presence of both the fillers. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers     

The effect of processing conditions on the rheological properties of blends of ultra high molecular weight polyethylene with high‐density polyethylene

Blends of high‐density polyethylene (HDPE) with small amounts of ultra‐high molecular weight polyethylene (UHMWPE) were prepared by melt mixing in a twin‐screw microcompounder. Two types of UHMWPE differing in their states of chain entanglement were used. The blend composition, time of mixing, and rotation speed of the screws were varied. Rheological properties of the blends were studied in oscillatory shear and uniaxial elongational tests. Reduction in phase angle measured in dynamic shear rheology and increase in extensional strain hardening were found to be useful indicators for quantifying the extent of mixing of the two components. Although the disentangled UHMWPE showed reasonable mixing with HDPE during typical residence times of melt compounding operations, the entangled UHMWPE remained essentially undissolved. The extent of mixing increased with mixing time and screw speed. POLYM. ENG. SCI., 59:821–829, 2019. © 2018 Society of Plastics Engineers     

Multi-stage point estimation of the mean of an inverse Gaussian distribution

In this article, we develop two-stage, three-stage, and accelerated sequential procedures for the point estimation of the mean μ of an inverse Gaussian distribution when the scale parameter λ is unknown. Both minimum risk and bounded risk estimation problems are considered subject to a weighted squared error loss function. We aim at controlling the associated risk functions for all three procedures. Second-order approximations are obtained for the proposed procedures.     

Effect of LED Radiation Pattern on BER Performance in Indoor Multipath MIMO-VLC System

The present paper investigates the impact of three radiation patterns of LED namely Lambertian, Batwing, Elliptical on the BER performance of 4 × 4 indoor multiple-input multiple-output (MIMO) visible light communication (VLC) system. The BER simulation has been done using LOS and LOS plus first reflection (L-R1) signals for ceiling-mounted and wall-mounted LEDs. For the case of ceiling-mounted LEDs, impulse response and BER have been computed using those radiation patterns at the centre and corner of a room (5 m × 5 m × 3 m). It has been found that LED having Elliptical radiation profile is more suitable for LOS signal when receiver is placed at the centre position whereas, Batwing radiation is suitable for L-R1 signal, both at the centre and corner positions. In the case of wall-mounted LEDs, impulse response and BER have been determined at the centre of the room using LOS and L-R1 signals. The results show that Batwing has least BER using LOS signal due to its wide radiation beam, but for L-R1 signal, the Elliptical profile having its narrow radiation beam has provided better BER performance. The present study shows that the BER in MIMO-VLC system not only depends on the transmitter and receiver position but also on the radiation patterns of LED and higher order reflection signals.

     

Climate change impacts on natural resources and communities: A geospatial approach for management

Climate change causes environmental depletion, with threats to the global economy. The health and productivity of ecosystems underpin agriculture, with stable ecosystems being the foundation for economic livelihoods and food security. This study proposes adaptation measures, using geospatial technology, for conserving natural resources and improving livelihoods of the local community from climate change scenarios. Planning, policy decisions and resultant programmes are required for natural resource management, which must be based on broad citizen participation and the engagement of rural communities. The suggested adaptation measures will help the planning system to regulate development of natural resources and the socio‐economic environment. The major natural resources in the environment are land and water, both of which can be severely degraded by human interventions, as well as climate change. Various thematic maps are prepared with the use of geospatial technology, in order to be helpful for site‐suitability analysis directed to the preparation of land and water management action plans for socio‐economic development. The study area is a micro‐watershed of the catchment of Ansupa Lake in the Cuttack District of Odisha, India. To reduce climate change impacts on natural resources and economic livelihoods, some adaptation measures have been proposed (e.g., 68.9 ha for afforestation.; 13.94 ha for gap plantations and agro‐horticulture; 389.62 ha for farm ponds and renovation of existing ponds for pisciculture and duckery activities, etc.; 11.33 ha for land management, along with five bore wells, eight dug wells, 51 LBS/check dams, and four WHSs, etc., for water management for sustainable use).     

Hierarchical remeshing strategies with mesh mapping for topology optimisation

This work investigates the use of hierarchical mesh decomposition strategies for topology optimisation using bi‐directional evolutionary structural optimisation algorithm. The proposed method uses a dual mesh system that decouples the design variables from the finite element analysis mesh. The investigation focuses on previously unexplored areas of these techniques to investigate the effect of five meshing parameters on the analysis solving time (i.e. computational effort) and the analysis quality (i.e. solution optimality). The foreground mesh parameters, including adjacency ratio and minimum and maximum element size, were varied independently across solid and void domain regions. Within the topology optimisation, strategies for controlling the mesh parameters were investigated. The differing effects of these parameters on the efficiency and efficacy of the analysis and optimisation stages are discussed, and recommendations are made for parameter combinations. Some of the key findings were that increasing the adjacency ratio increased the efficiency only modestly – the largest effect was for the minimum and maximum element size parameters – and that the most dramatic reduction in solve time can be achieved by not setting the minimum element size too low, assuming mapping onto a background mesh with a minimum element size of 1. © 2016 The Authors. International Journal for Numerical Methods in Engineering Published by John Wiley & Sons, Ltd.     

3D Heteroatom‐Doped Carbon Nanomaterials as Multifunctional Metal‐Free Catalysts for Integrated Energy Devices

Sustainable and cost‐effective energy generation has become crucial for fulfilling present energy requirements. For this purpose, the development of cheap, scalable, efficient, and reliable catalysts is essential. Carbon‐based heteroatom‐doped, 3D, and mesoporous electrodes are very promising as catalysts for electrochemical energy conversion and storage. Various carbon allotropes doped with a variety of heteroatoms can be utilized for cost‐effective mass production of electrode materials. 3D porous carbon electrodes provide multiple advantages, such as large surface area, maximized exposure to active sites, 3D conductive pathways for efficient electron transport, and porous channels to facilitate electrolyte diffusion. However, it is challenging to synthesize and functionalize isotropic 3D carbon structures. Here, various synthesis processes of 3D porous carbon materials are summarized to understand how their physical and chemical properties together with heteroatom doping dictate the electrochemical catalytic performance. Prospects of attractive 3D carbon structural materials for energy conversion and efficient integrated energy systems are also discussed.