Impact of salts on polyacrylamide hydrolysis and gelation: New insights

Polyacrylamide (PAM) and its derivatives are the most commonly used polymers in the preparation of polymeric gels for water control in petroleum reservoirs. This study involved the use of polyethylenimine (PEI) as a crosslinker for PAM. In this study, we investigated PAM alkaline hydrolysis at high temperatures. The effects of salts [sodium chloride (NaCl) and ammonium chloride (NH₄Cl)] on the degree of hydrolysis (DH) of PAM were investigated. These salts were used as retarders to elongate the gelation time of the PAM/PEI system. The data obtained from ¹³C‐NMR was used to understand the retardation mechanisms by salts. We found that NH₄Cl accelerated the extent of hydrolysis more in comparison with NaCl. Moreover, the apparent viscosity of the hydrolyzed samples was measured. PAM hydrolysis in the presence of NH₄Cl resulted in a lower solution viscosity than that in the presence of NaCl. Therefore, NH₄Cl was more effective in shielding negative charges on the carboxylate groups of the partially hydrolyzed polyacrylamide (PHPA) chain. NaCl and NH₄Cl were compatible with the PHPA/PEI system, but sodium carbonate showed a white precipitate. In addition, high‐temperature/high‐pressure elastic modulus data were reported for the first time for this system. Differential scanning calorimetry was coupled with rheology to explain the PAM/PEI crosslinking in the presence of salts. Models were developed to assess the impact of the salts on the PAM DH and the induction period before gelation. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41185.     

Natural lipid-lowering agents and their effects: an update

Hyperlipidemia is one of the main contributing factors in the development of cardiovascular diseases. The hunt for effective antihyperlipidemic drugs is still on with an intention of finding potent agents with meager adverse effects. For the past several decades, medicinal plants have been evaluated for lipid-lowering effects apart from synthetic approaches to develop newer antihyperlipidemic agents. This article highlights the work carried out on potential antihyperlipidemic agents from plant sources from 2006 till 2012 that were archived in Google Scholar and Science Direct database. Seventy-nine articles were included in the review after manual content curation. The review summarizes the investigations on medicinal plants, compounds and herbal formulations using various hyperlipidemic animal models or in humans, the research findings and possibility of chemotaxonomic occurrence of secondary metabolites responsible for the antihyperlipidemic activities within certain plant families.     

The influence of process parameters on desulfurization of two Turkish lignites by selective oxidation

The chemical desulfurization of two high-sulfur Turkish lignites was investigated using a mixture of hydrogen peroxide in acetic acid. Sulfur removal was measured with respect to particle size, reaction time, reaction temperature and ultrasonic irradiation. In general, all inorganic sulfur and some organic sulfur were removed from these coals under mild conditions. Cayirhan lignite seemed more reactive towards peroxyacedic acid at slightly higher temperatures and longer reaction times, but under these conditions, solubility was high and yields of solid products declined. Reaction time and reaction temperature slightly changed the level of sulfur removal from Gediz lignite. The level of desulfurization was largely independent of the particle size for Gediz lignite, while sulfur removal from Cayirhan lignite seemed dependent of the particle size reaction temperature and reaction time.     

Comparison of estimates using record statistics from Weibull model: Bayesian and non-Bayesian approaches

This paper develops a Bayesian analysis in the context of record statistics values from the two-parameter Weibull distribution. The ML and the Bayes estimates based on record values are derived for the two unknown parameters and some survival time parameters e.g. reliability and hazard functions. The Bayes estimates are obtained based on a conjugate prior for the scale parameter and a discrete prior for the shape parameter of this model. This is done with respect to both symmetric loss function (squared error loss), and asymmetric loss function (linear-exponential (LINEX)) loss function. The maximum likelihood and the different Bayes estimates are compared via a Monte Carlo simulation study. A practical example consisting of real record values using the data from an accelerated test on insulating fluid reported by Nelson was used for illustration and comparison. Finally, Bayesian predictive density function, which is necessary to obtain bounds for predictive interval of future record is derived and discussed using a numerical example. The results may be of interest in a situation where only record values are stored.     

Lazy garbage collection of recovery state for fault-tolerantdistributed shared memory

We address the problem of garbage collection in a single-failure fault-tolerant home-based lazy release consistency (HLRC) distributed shared-memory (DSM) system based on independent checkpointing and logging. Our solution uses laziness in garbage collection and exploits consistency constraints of the HLRC memory model for low overhead and scalability. We prove safe bounds on the state that must be retained in the system to guarantee correct recovery after a failure. We devise two algorithms for garbage collection of checkpoints and logs, checkpoint garbage collection (CGC), and lazy log trimming (LLT). The proposed approach targets large-scale distributed shared-memory computing on local-area clusters of computers. The challenge lies in controlling the size of the logs and the number of checkpoints without global synchronization while tolerating transient disruptions in communication. Evaluation results for real applications show that it effectively bounds the number of past checkpoints to be retained and the size of the logs in stable storage     

An integrated approach for groundwater potential zoning in shallow fracture zone aquifers

This study presents an integrated approach for the identification of groundwater occurrences in shallow fracture zone (SFZ) aquifers using remote-sensing, geological, and geophysical data. The Central Eastern Desert of Egypt was selected as a test site for the present study. The distribution of major faults and shear zones was extracted from a fusion image generated by injecting high-spatial resolution phased array L-band synthetic aperture radar (PALSAR) images into Landsat Enhanced Thematic Mapper images. The Advanced Spaceborne Thermal Emission and Reflection Radiometer (ASTER) digital elevation model was processed to extract the drainage systems, slope, and topographic wetness index (TWI). The multidate PALSAR imagery acquired during rainy and dry seasons was used to estimate the relative soil moisture content. The lithology, fractures, drainage density, slope, TWI, and soil moisture content were used as thematic layers for groundwater occurrence in the SFZ aquifers. A GIS model of groundwater potential was developed by selecting the most probable locations for groundwater in each layer. The results indicate that the spatial distribution of the existing water wells is in agreement with the model where all wells fall in the regions of high groundwater potential zones. A geophysical survey was conducted using ground penetrating radar (GPR), indicating that the high groundwater potential zones are promising for drilling shallow wells. The adopted approach can be used as a cost-effective tool for groundwater exploration in the SFZ aquifers in the study area and in areas of similar geologic and hydrogeologic settings elsewhere.     

The lower and upper approximations in a quotient hypermodule with respect to fuzzy sets

This paper provides a continuation of ideas presented by Davvaz and Mahdavipour [B. Davvaz, M. Mahdavipour, Roughness in modules, Inform. Sci. 176 (2006) 3658-3674]. The notion of hypermodule is a generalization of the notion of module. In this paper, we consider the quotient hypermodule M/A and interpret the lower and upper approximations as subsets of the quotient hypermodule M/A. Then, we introduce the concept of quotient rough sub-hypermodule. Also, using the concept of fuzzy sets, we introduce and discuss the concept of fuzzy rough hypermodules and then we obtain the relation between fuzzy rough sub-hypermodules and level rough sets. This relation is characterized as a necessary and sufficient condition.     

Use of multisensor and multitemporal geospatial datasets to extract the foundation characteristics of a large building: a case study

Bulletin of Engineering Geology and the Environment - The assessment of the ground conditions for large buildings is important because the results are sensitive to the ground conditions, especially...