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21.
Chemical injections are used in a variety of applications in civil and mining engineering, including ground stabilization, support anchoring, strata sealing, reduction and diversion of groundwater flow and water ingress, and creation of a load-bearing ring during tunneling. Historically, injection application without pressure was first employed by the Romans. Polyurethane injections have been used in coal mines to stabilize roofs and to reduce problems regarding water ingress in shafts and tunnels. This paper focuses on chemical injection, which was employed to prevent ground settlement induced by groundwater drainage from the shaft. As a result of the drainage of 4.5 l/s groundwater from the Shaft 4, which was sunk for service at Guzelyali station of Izmir Metro Project, the groundwater level dropped 4 m from the original level, and ground settlement reached 98 mm, while the inner tunnel vertical convergence was 23 mm. This can be explained with the closure of pore volumes in the overburden. Ground settlement was stopped and groundwater level approached its original level after chemical injection.  相似文献   
22.
    
This study focused on fabrication of the thermochromic microcapsules and their application to the cotton fabric. In this study, thermochromic systems composed of crystal violet lactone, bisphenol A, and 1-tetradecanol were prepared and microencapsulated by emulsion polymerization method in poly(methyl methacrylate-co-ethylene glycol dimethacrylate-co-glycidyl methacrylate) wall. The microcapsules were analyzed by Fourier transform infrared spectroscopy, scanning electron microscope, transmission electron microscope, differential scanning calorimetry, and thermogravimetric analysis. Their thermoregulating property was tested by T-history test. The results revealed that microcapsules with smooth surfaces, core–shell structured, and spherical shape were successfully produced. The latent heat storage capacity of the microcapsules decreased from 202 J g−1 to 167 J g−1 when their shell/core ratio changed from 0.5/1 to 2/1. Microcapsules were adequately had sufficient thermal resistance to the temperatures they will encounter during their application to textile products and their usage. According to the UV–visible spectroscopy analysis and color measurements, the microcapsules exhibited reversible color change from blue to colorless and vice versa. Besides, the microcapsule impregnated fabric was able to absorb latent heat energy of 21.79 J g−1 at around 35 °C and had cooling effect. According to the colorimetric parameters, the fabric was at blue color at room temperature and became colorless when heated to the temperature above the melting point of thermochromic system. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48815.  相似文献   
23.
Boron/nitrogen substituted carbons were synthesized by co-pyrolysis of polyborazylene/coal tar pitch blends to yield a carbon with a boron and nitrogen content of 14 at% and 10 at%, respectively. The presence of heteroatoms in these carbons shifted the hydrogen evolution overpotential to −1.4 V vs Ag/AgCl in aqueous electrolytes, providing a large electrochemical potential window (∼2.4 V) as well as a specific capacitance of 0.6 F/m2. An asymmetric capacitor was fabricated using the as-prepared low surface area carbon as the negative electrode along with a redox active manganese dioxide as the positive electrode. The energy density of the capacitor exceeded 10 Wh/kg at a power density of 1 kW/kg and had a cycle life greater than 1000 cycles.  相似文献   
24.
Ground settlement is the most significant environmental impact of the tunnels excavated in intensively urbanized regions. A Considerable amount of ground settlement occurs by pre-convergence, formed during the time of support setting followed by the excavation, and movement of tunnel face into the tunnel. The risk of damage on the buildings by the ground settlement can be catastrophically high. Therefore, rock engineers bear an important duty to prevent the potential damage on buildings by controlling the ground settlement while excavating the tunnels. This has been accomplished by applying umbrella arch with face bolt technique recently in various important areas. In this method, the ground settlements can substantially be decreased by limiting the tunnel face movement into the tunnel, by creating a pseudo shell around the tunnel face with umbrella arch and then increasing the stability with face bolts. In this study, as part of the 2nd phase of Izmir metro construction in densely populated Poligon district of Izmir the effects of umbrella arch-face bolt applications on ground settlements have been determined using numerical modeling and in situ measurements. Results indicated that the umbrella arch and face bolt applications have significantly diminished the risk of settlement damage on buildings by reducing the ground settlements and convergence as 69% and 57%, respectively.  相似文献   
25.
    
In this work, novel antibacterial composites were prepared by using poly(ε‐caprolactone) (PCL) as the main matrix material, and gentamicin‐loaded microspheres composed of β‐tricalcium phosphate (β‐TCP) and gelatin. The purpose is to use this biodegradable material as a support for bone tissue. This composite system is expected to enhance bone regeneration by the presence of β‐TCP and prevent a possible infection that might occur around the defected bone region by the release of gentamicin. The effects of the ratio of the β‐TCP/gelatin microspheres on the morphological, mechanical, and degradation properties of composite films as well as in vitro antibiotic release and antibacterial activities against Escherichia coli and Staphylococcus aureus were investigated. The results showed that the composites of PCL and β‐TCP/gelatin microspheres had antibacterial activities for both bacteria. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013  相似文献   
26.
    
Adhesion of root canal filling materials to root dentin is important for the long-term success of the treatment. Push-out bond strength test is used to evaluate the adhesion capacity of root canal filling materials to root canal walls. The aim of the present study is to compare the bond strength of root canal filling materials to root dentin after irrigation with EDTA, chitosan and the combination of chitosan and PIPS irridation using push-out bond strength test. Forty-eight extracted teeth were resected until 13-mm long roots were obtained. Root canals were prepared with a size-25 OneShape instrument. Samples were divided into three groups each including 15 roots. Group 1: Canals were rinsed with 0.2% chitosan and subjected to laser irridation with PIPS at the same time. Group 2: Canals were rinsed with 0.2% chitosan. Group 3: Canals were rinsed with EDTA. All canals were filled with .06 tapered gutta-percha and AH-plus sealer. One-mm thick slices were taken from coronal, middle and apical one-thirds of the roots. Push-out bond strength was determined using a Universal Testing Machine. One root from each group was observed under SEM to evaluate the degree of smear removal. Statistical analysis was performed with Kruskall-Wallis test. Results showed that bond strength values were statistically similar in overall evaluation for all groups (p > .05). In segmental evaluation, group 1 revealed the highest bond strength in apical one-third compared to other groups (p < .05).  相似文献   
27.
Determination of the limit angle at the Manisa-Soma-Eynez coal field, a major coal production area in Turkey, is difficult because of the presence of a landslide caused by the waste from a neighboring open-pit site being dumped over the underground mine at the Soma-Eynez basin. In fact, it is not possible to determine the effect of extraction on the surface from field studies. Thus, in order to determine the limit angle, in-situ subsidence measurements, geophysical measurements, rock-based tests in the laboratory and the data obtained from a physical model have supported numerical modeling studies. The software, LAMODEL, used for the numerical modeling was developed by National Institute for Occupational Safety and Health (NIOSH), and is based on the Boundary Element Method. The results obtained from modeling have been found to be compatible with other studies and as a result the limit angle has been determined.  相似文献   
28.
29.
Downhole pumps are being used increasingly more often in low-enthalpy geothermal wells. The depth at which these pumps are installed depends on the physical and chemical characteristics of the geothermal fluid, the production flow rate, and the reservoir pressure and permeability. In this study we have investigated the factors affecting pump setting depths in low-temperature, liquid-dominated geothermal systems and defined the relationship between flow rate and pressure drawdown based on multi-rate test results. The methodology proposed was applied to the Balcova-Narlidere geothermal field, Turkey. It was found that the most important parameters for determining the capacity and setting depth of a downhole pump were flow performance, non-condensable gas concentration, and temperature. The implementation of the methodology is illustrated.  相似文献   
30.
CdO film has been deposited by sol–gel spin coating method on the glass substrate and then the film has been annealed at 400, 500, 600 °C for 1 h. Effect of annealing temperature on the structural and optical properties of the film has been investigated. The crystal structure and orientation of the as-grown and annealed CdO films have been investigated by X-ray diffraction method. Annealed CdO films are polycrystalline with (111) preferential orientation. The information on strain and grain size is obtained from the full width-at-half-maximum (FWHM) of the diffraction peaks. Texture coefficient and lattice constant have been calculated. The surface morphology of the films has been analyzed. The optical band gap value decreased with increasing the annealing temperatures.  相似文献   
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