全文获取类型
收费全文 | 3635篇 |
免费 | 132篇 |
国内免费 | 6篇 |
专业分类
电工技术 | 40篇 |
综合类 | 5篇 |
化学工业 | 809篇 |
金属工艺 | 63篇 |
机械仪表 | 97篇 |
建筑科学 | 151篇 |
矿业工程 | 17篇 |
能源动力 | 63篇 |
轻工业 | 327篇 |
水利工程 | 28篇 |
石油天然气 | 13篇 |
无线电 | 296篇 |
一般工业技术 | 615篇 |
冶金工业 | 693篇 |
原子能技术 | 21篇 |
自动化技术 | 535篇 |
出版年
2023年 | 23篇 |
2022年 | 45篇 |
2021年 | 74篇 |
2020年 | 63篇 |
2019年 | 47篇 |
2018年 | 69篇 |
2017年 | 65篇 |
2016年 | 96篇 |
2015年 | 65篇 |
2014年 | 102篇 |
2013年 | 239篇 |
2012年 | 187篇 |
2011年 | 227篇 |
2010年 | 149篇 |
2009年 | 151篇 |
2008年 | 152篇 |
2007年 | 161篇 |
2006年 | 118篇 |
2005年 | 85篇 |
2004年 | 92篇 |
2003年 | 98篇 |
2002年 | 91篇 |
2001年 | 57篇 |
2000年 | 40篇 |
1999年 | 65篇 |
1998年 | 112篇 |
1997年 | 68篇 |
1996年 | 48篇 |
1995年 | 51篇 |
1994年 | 40篇 |
1993年 | 49篇 |
1992年 | 29篇 |
1991年 | 27篇 |
1990年 | 40篇 |
1989年 | 41篇 |
1988年 | 26篇 |
1987年 | 29篇 |
1986年 | 24篇 |
1985年 | 41篇 |
1984年 | 26篇 |
1983年 | 35篇 |
1982年 | 30篇 |
1981年 | 33篇 |
1980年 | 32篇 |
1979年 | 33篇 |
1978年 | 34篇 |
1977年 | 35篇 |
1976年 | 35篇 |
1975年 | 42篇 |
1974年 | 24篇 |
排序方式: 共有3773条查询结果,搜索用时 15 毫秒
141.
This paper describes the process of modifying and validating a hunger index developed in the United States by Wehler et al (1992). It is part of a research whose main objective is to develop and validate a simple method that measures both quantitative (food sufficiency) and qualitative (female self-perception) dimensions of household food insecurity. In a pilot study, the original instrument was modified from a 2 point 8 item to a 4 point 12 item scale. Precision measured with Alpha Chronbach's coefficient was high (0.871) suggesting consistency in the scale's items. The instrument was applied to a sample of 238 poor and very poor households in a peri-urban barrio of Caracas. To determine overall internal validity of the scale the relationship between possible economic, social and behavioral determinants and food security level measured with the scale, was analyzed. Construct validity of the scale was established with factor and principal components analysis. Finally, with multiple regression analysis evidence is presented for overall validity of the scale. Four determinants: predictors of food sufficiency score, monthly income per capita, social class, and number of children in the household predict in the expected direction self-perceived food security level (R2 = 0.343). Results suggest that this instrument, together with an abbreviated measure of food sufficiency, based on strategic foods may be a valid, precise, and simple method for identifying and monitoring households that suffer from some degree of food insecurity in poor urban communities. 相似文献
142.
Variable temperature13C MAS NMR spectra are reported for13CO-enriched KFe2Mn(CO)12 as a solid and also as dispersed clusters on a carbon support. The spectrum of KFe2Mn(CO)12 at 300 K agrees with the proposed structure for this cluster and shows that the cluster is static. Two bridging carbonyl resonances are clearly resolved and, by comparison with13C MAS NMR spectra of Mn2(CO)10 and Fe2(CO)9, all terminal resonances for the cluster can be assigned. When the cluster is supported on carbon, two broad resonances are observed at room temperature which are assignable to KFe2Mn(CO)12 and a decomposition product, Mn2(CO)10. The carbonyl ligands in both supported clusters are completely averaged, and KFe2Mn(CO)12 on the carbon surface demonstrates fluxional behavior similar to that observed for the cluster in solution. For this fluxional process, activation energies of 0.6 kcal/mol and 0.5 kcal/mol are estimated for carbon-supported KFe2Mn(CO)12 and Mn2(CO)10, respectively. 相似文献
143.
Analysis of exempt paint solvents by gas chromatography using solid-phase microextraction 总被引:1,自引:0,他引:1
Rosemarie R. Bodrian Albert C. Censullo Dane R. Jones Mark J. Rashkin Max T. Wills 《Journal of Coatings Technology》2000,72(900):69-74
Acetone, methyl acetate, and parachlorobenzotrifluoride (PCBTF or Oxsol? 100) have been exempted as VOC solvents by the U.S. Environmental Protection Agency. In measuring coating VOC content, separate methods for determining exempt solvents are required. One such method utilizes solid-phase microextraction (SPME) to sample the headspace of solvent-based coatings to which the surrogates acetone-d6, methyl acetate-d3, and/or metachlorobenzotrifluoride have been added. The sampled exempt coating solvents are thermally desorbed and analyzed using gas chromatography with flame ionization or mass spectral detection. The SPME headspace method has also been used to analyze MEK, butyl acetate, tert-butyl acetate, toluene, and xylene in solventborne coatings, and alcohols in waterborne systems. This paper presents the results obtained for acetone and toluene in a large number of aerosol paints. Additionally, the results from a round-robin study for acetone, methyl acetate, and parachlorobenzotrifluoride in commercial solvent-based coatings are reported. 相似文献
144.
145.
146.
S. K. Albert C. R. Das V. Ramasubbu A. K. Bhaduri S. K. Ray Baldev Raj 《Journal of Materials Engineering and Performance》2002,11(3):243-249
A root-cracked blade in a high-pressure steam turbine of a nuclear power plant had to be replaced with a new blade by cutting
the shroud to remove the cracked blade. This necessitated in situ welding of a new shroud piece with the existing shroud after
the blade replacement. The in situ welding of the shroud, a 12% Cr martensitic stainless steel with tempered martensite microstructure,
was carried out using gastungsten arc welding and 316L austenitic stainless steel filler metal followed by localized postweld
heat treatment at 873 K for 1 h using a specially designed electrical resistance-heating furnace. Mock-up trials were carried
out to ensure that sound welds could be made under the constraints present during the in situ repair welding operation. In
situ metallography of the repair weld after postweld heat treatment confirmed the adequate tempering of the martensitic structure
in the heat-affected zone. Metallurgical investigations carried out in the laboratory on a shroud test-piece that had been
welded using the same procedure as employed in the field confirmed the success of the in situ repair operation. The alternate
option available was replacing the cracked blade and the shroud piece to which it is riveted with a new one, reducing the
height of all the blades attached to the shroud by machining, riveting the blades with reduced height to the new shroud, and,
finally, dynamic balancing of the entire turbine after completion of the repair. This option is both time-consuming and expensive.
Hence, the successful completion of this repair welding resulted in enormous savings both in terms of reducing the downtime
of the plant and the cost of the repair. The turbine has been put back into service and has been operating satisfactorily
since December 2000. 相似文献
147.
Lysophosphatidylcholine (LysoPtdCho) levels are elevated in sera in patients with atherosclerosis and in atherosclerotic tissue.
Previous studies have shown that reactive chlorinating species attack plasmalogens in human coronary artery endothelial cells
(HCAEC), forming lysoPtdCho and lysoPtdCho–chlorohydrin (lysoPtdCho–ClOH). The results herein demonstrate for the first time
that lysoPtdCho–ClOH is elevated over 60-fold in human atherosclerotic lesions. In cultured HCAEC, 18:0 lysoPtdCho–ClOH led
to a statistically significant increase in P-selectin cell-surface expression, but unlike 18:1 lysoPtdCho did not lead to
cyclooxygenase-2 protein expression. These data show that 18:0 lysoPtdCho–ClOH is elevated in atherosclerotic tissue and may
have unique pro-atherogenic properties compared to lysoPtdCho. 相似文献
148.
Negative ion mass spectrometric techniques, for compounds having good ionization properties, such as pentafluorobenzyl derivatives,
are believed to be more sensitive than positive ion methods. Preparation of PFB oximes of fatty aldehydes from crude lipid
extracts is problematic due to the release of free aldehydes from plasmalogens during derivatization. Accordingly, in these
studies plasmalogens were removed by silicic acid column chromatography prior to pentafluorobenzyl derivatization. This simple
purification step to remove plasmalogens is shown to facilitate the quantification of long-chain aldehydes by analysis of
their pentafluorobenzyl oxime derivatives utilizing gas chromatography–mass spectrometry in the negative ion chemical ionization
mode. The limit of detection for long chain fatty aldehydes using this method is 0.5 pmol and it is linear over two orders
of magnitude. Silicic acid column chromatography followed by electrospray ionization mass spectrometry demonstrated that plasmalogens
were removed (the detection limit for this analyses was ≤0.3 pmol). Furthermore, we have exploited the utility and sensitivity
of this method to identify increases in hexadecanal and octadecanal in 3-amino-1,2,4-triazole treated human neutrophils.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
149.
Reactivation of a Carbon-supported Gold Catalyst for the Hydrochlorination of Acetylene 总被引:1,自引:0,他引:1
Acetylene hydrochlorination using a carbon-supported gold catalyst is studied. Reactivation of the catalyst is demonstrated using a brief treatment of the spent catalyst with boiling aqua regia and the process of reactivation and deactivation is characterised using X-ray photoelectron spectroscopy. Deactivation is considered to be due to loss of Au3+ which is restored by the aqua regia treatment. 相似文献
150.
A range of Pt supported catalysts have been evaluated for the total oxidation of naphthalene. Catalysts contained 0.5 wt% Pt on a range of supports (γ-Al2O3, TiO2, SiO2, SnO2, and CeO2). SiO2 was the best support, the 0.5%Pt/SiO2 catalyst showing a conversion to carbon dioxide of over 90% at 200 °C (100 vppm naphthalene, GHSV = 45,000 h−1). The catalyst also showed a considerably higher activity (in the temperature range 100–175 °C) than a CeO2 catalyst recently reported to be one of the most effective catalysts for the total oxidation of naphthalene. The high activity of the 0.5%Pt/SiO2 catalyst has been attributed to the relatively low dispersion and relatively large size of Pt particles. Furthermore, due to the acidic and non-reducible nature of the SiO2, platinum is expected to have a weak interaction with the support. XPS data identified the presence of Pt0 on the surface and this contributes to the high activity. 相似文献