Water activity at 35 °C in 'sugar ' + water and 'sugar ' + sodium chloride + water systems

Water activities of aqueous solutions of xylose, glucose, fructose and sucrose, and of these sugars with sodium chloride, were measured and correlated with a simple empirical equation proposed by Lin et al . (1996) . Parameters for the equation were obtained and, from them, values of water activity were calculated with an average relative deviation of less than 0.14% for all the systems studied.     

FEM modelling and experimental characterization of microbeams in presence of residual stress

Out-of-plane bending tests are here used to experimentally validate some numerical models of microbeams actuated by the electric field. Out-of-plane bending microcantilevers and clamped–clamped microbeams often suffer the presence of residual strain and stress, respectively, which affect their static and dynamic behaviour and pull-in voltage. In case of microcantilever an accurate modelling has to include the effect of an initial curvature due to microfabrication process, while in double clamped microbeams constraints may impose a pre-loading caused by a tensile stress. So-called geometrical nonlinearity sometimes occurs, when microcantilever exhibits large displacement, or because of the mechanical coupling between axial and flexural behaviours in double clamped microbeams. Modelling this kind of nonlinearity is an additional goal of this study. Experiments demonstrated a good agreement with results of FEM approaches proposed. In the case of microbridges numerical models are used to identify the residual stress. A reverse analysis is implemented, the axial pre-stress is calculated by means of the measured pull-in voltage.     

Analysis of the current methods used to size a wind/hydrogen/fuel cell‐integrated system: A new perspective

As an alternative to the production and storage of intermittent renewable energy sources, it has been suggested that one can combine several renewable energy technologies in one system, known as integrated or hybrid system, that integrate wind technology with hydrogen production unit and fuel cells. This work assesses the various methods used in sizing such systems. Most of the published papers relate the use of simulation tools such as HOMER, HYBRID2 and TRNSYS, to simulate the operation of different configurations for a given application in order to select the best economic option. But, with these methods one may not accurately determine certain characteristics of the energy resources available on a particular site, the profiles of estimated consumption and the demand for hydrogen, among other factors, which will be the optimal parameters of each subsystem. For example, velocity design, power required for the wind turbine, power required for the fuel cell and electrolyzer and the storage capacity needed for the system. Moreover, usually one makes excessive use of bi‐parametric Weibull distribution function to approximate the histogram of the observed wind to the theoretical, which is not appropriate when there are bimodal frequency distributions of wind, as is the case in several places in the world. A new perspective is addressed in this paper, based on general system theory, modeling and simulation with a systematic approach and the use of exergoeconomic analysis. There are some general ideas on the advantages offered in this method, which is meant for the implementation of wind/hydrogen/fuel cell‐integrated systems and in‐situ clean hydrogen production. Copyright © 2009 John Wiley & Sons, Ltd.     

Nanofabrication of Self-assembled Molecular-scale Electronics

Single electron tunneling devices were made by combiningstandard electron beam lithography and the self-assembly ofchemically synthesized gold clusters. These clusters, withdiameters from 2 to 5 nm, were captured in a 5–10 nm gapbetween two gold electrodes. The gold particles as well as theelectrodes were covered with self-assembled monolayers (SAM)of organic molecules which served as tunnel barriers.Operating devices show a suppressed current due to the Coulombblockade of tunneling at room temperature. When cooled to4.2 K, a Coulomb staircase was observed. By applying a voltageto an oxidized aluminum gate beneath the electrodes and thetrapped gold cluster the current voltage characteristics weremodulated. Anomalous effects are observed such as constantcurrent plateaus whose positions are gate-voltage dependent.An electrodeposition method for gold has been used tofabricate gaps between electrodes smaller than 2 nm. A self-assembled monolayer was used successfully on the electrodes inorder to prevent the gold atoms from migrating on the surfacebetween the electrodes and thereby short-circuiting thejunction. The conductance of such a tunnel junction has beenmeasured and compared to the theory with good agreement. Fromthis comparison the capacitance of the junction was estimated,and we could use that value to calculate a rough estimation ofthe distance between the electrodes.     

On the Cyclic Softening Mechanisms of Reduced Activity Ferritic/Martensitic Steels

Low‐cycle fatigue tests were performed in three different ferrite/martensite steels, i.e., the European RAFM steel EUROFER 97 and the commercials AISI 410 and AISI 420, at room temperature (RT) and at 550°C. After the first few cycles, a cyclic softening that continues up to failure is observed for all these steels. The cyclic softening exhibited by AISI 420 is less pronounced than for the other two steels. The comparison between the mechanical responses of the materials was based on the study of the flow stress components, i.e., the friction and the back stresses, and their correlation with the microstructure evolution. In most cases, the strong cyclic softening observed is produced by the decreasing stress values exhibited by both stress components. However, at RT, for AISI 420, the back stress does not present variation during cycling. The decrease of the free dislocation density inside the subgrains and the growth of the mean subgrain size represent the main microstructural evolution.     

Retrofitting of R/C shear walls by means of high performance jackets

A new technique for the strengthening of existing R/C shear walls based on the application of thin high performance jackets is presented in this paper. The strengthening jacket is made of high performance concrete, having a compression resistance higher than 150 MPa, and reinforced by means of an high strength steel mesh. The experimental study is carried out on a 1:3 scale R/C wall, proportioned to resist vertical loads only, and reinforced by means of a 15 mm thick high performance jacket. Cyclic loads of increasing magnitude are applied to the experimental shear wall up to collapse. The effectiveness of the technique is also verified numerically. The results show the efficiency of the proposed solution in significantly increasing the structure resistance, deformation capacity and ductility.     

Transient response analysis and modeling of near wall flow conditions in a micro channel: evidence of slip flow

An experimental tool for determination of the near wall transport parameters in a micro channel, supported by flow simulation, is presented. The method is based on the transient flow response due to convective diffusion, in absence of specific adsorption. An approximately step-function type temporal solute concentration variation serves as the input signal. The associated response signal of a surface plasmon resonance sensor, acting as an integral part of a micro channel, has been taken as the output signal. It provides the flow-dependent change of the NaOH solute concentration in the channel within the optical detection and near wall distance interval 0 < d < 0.5 μm. The temporal signal evolution and response time, until an initially plain aqueous solution is replaced by the solute, varies inversely with solute concentration and flow rate. In the asymptotic limits, the near wall forced convective and diffusive channel transit times, along with the associated velocities, can be extracted and separated. A low convective near wall flow speed would account for 100% adsorption efficiency. The validity of the scaling relation for Fickian diffusive transport has been confirmed by experiments. Convective near wall flow reveals a distorted parabolic flow profile. This indicates relaxation of the no-slip condition, and presence of slip flow. Neither boundary layer formation, nor near wall micro turbulences have been observed. Eventually, a compact mathematical transient flow model, outlined in the Laplace domain for the electrical equivalent analogue circuit and applicable to the convective diffusion equation, has been developed for the flow transients.     

Comparison of Multivariate Control Charts for Process Dispersion

In this article we compare four multivariate control charts for process dispersion in the retrospective analysis of a historical data set. Among the schemes compared, a new control chart based on a robust estimation of the variance-covariance matrix proved to be very effective in detecting changes in the process dispersion matrix.     

Numerical modelling of impact rupture in polysilicon microsystems

A 2D geometrical model for polycrystals was developed in this paper by means of a Voronoi tessellation in which each crystal is assumed to be elastic anisotropic. An implicit–explicit FE dynamic code coupled with an automatic procedure for the introduction of cohesive interface elements with cohesive traction-jump softening laws was used in order to simulate intergranular and transgranular fracture. Accidental drop simulations were performed with the principal aim to capture the maximum acceleration and to simulate local rupture phenomena in MEMS. In order to reduce the excessive problem size, a simplified, decoupled global–local three level multi-scale approach was used.