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991.
This paper examines the need for a return to a systemic,holistic,and normative approach to designing human settlements that has been neglected with the decline of the Welfare State and the shift to iecemeal,freewheeling,marked-based development during the unprecedented explosion of construction in the last thirty years.The need for a change is brought about by the current ecological and economic crises linked to a high degree to the current belief that the quality of cities emerges from the added-value of individual buildings or through the assemblage of individual structures put together like a building.This paper argues that a city is not like a building.The contemporary city is characterized by an unprecedented number of problems.These problems cannot be handled by individual good will or simple preventive or corrective actions by architects and developers as it has been done the last three decades.What is needed is an overall systemic framework of planning that ① is driven by normative criteria,② can handle a high degree of complexity and interdependence of factors,and ③ can deal with unanticipated,unintended,long-term irreversible environmental impacts that characterize the "third ecology," the inseparable complex of the natural and the human-made.  相似文献   
992.
Structures subjected to cyclic loads show alternative tension-compression stress states; in such a case, even if certain damage (fracture) is reached during the tension cycle, the computational model of the structure should maintain its capacity to withstand subsequent compression based only on the contact effect in the damaged area (opening, closing and reopening of cracks). In order to control this behavior, a phenomenological constitutive model able to consider the contact as a structural limitation is required. From the constitutive point of view, geomaterials have different damage thresholds for tension and compression and, from the structural point of view, it must be ensured that the material damaged in tension still resist compression. In this case, it is accepted that cracks behave as a contact surface at the structural level. To meet the above mentioned phenomenology, a modification of the damage model differentiated in tension and compression proposed by Faria et al. [Faria R, Oliver J, Cervera M. A strain-based plastic viscous-damage model for massive concrete structures. Int J Solids Struct 1998; 35:1533-58] is performed in this paper, considering independent strength thresholds in each of these processes, controlled with two independent discontinuity threshold functions. Also, in this work an elasto-plastic constitutive model is used to represent the behaviour of the steel bars.  相似文献   
993.
994.
The detailed chemical changes in bitumen brought about over a one year period by an in situ combustion process in an oil sands reservoir have been investigated. Relative to a core sample, the fireflood-produced oils exhibited a significant reduction in density and viscosity which began early in the production cycle. This behaviour was correlated with a marked increase in material boiling in the naphtha and middle distillate ranges and a concomitant decrease in the residue cut. The sulfur and nitrogen contents in the produced oils decreased relative to the core sample. A reduction in the acid number of the produced oil samples was coupled with an increase in the oxygen content as the firefiood proceeded. The relationship between these changes and the dynamics of the in situ combustion process are discussed.  相似文献   
995.
The 2653 PGC device is discussed, which can provide error checking when data is being transferred via a communications link. The device can operate at speeds up to 500, 000 characters per second and because it includes built-in intelligence it can detect special characters and character sequences.  相似文献   
996.
Factors affecting flocculation of brewing yeast, our current understanding of the process and traditional methods of assessing flocculence are discussed in this review. In spite of extensive study during the last two decades, a number of uncertainties and controversies regarding yeast flocculation still remain. This confusion is due in part to the polyploid or aneuploid nature of most brewing strains studied. At present, uncertainty exists as to the number of genes involved in flocculation as well as the nature and mode of action of the resulting gene products. Another restriction to our investigation of flocculation is the lack of a fundamental and standard test method. Along with a general discussion of yeast flocculation, this report will note conflicting reports concerning the influence of temperature, the effect of metal ions such as magnesium and barium, and the importance of the carboxyl and phosphate groups in yeast cell—cell interactions. As well, past and current methods employed for the assay of brewing yeast flocculation will be discussed.  相似文献   
997.
In this review, areas of colloid science including the DLVO theory, flocculation kinetics and suspension rheology are outlined and their applicability to the study of yeast flocculation discussed. Specifically, fundamental methods of predicting cell-cell interaction energies, orthokinetic flocculation rates and rheological flow properties of flocculent suspensions are detailed. While the application of these theories to brewing systems is somewhat difficult, they may aid our understanding of brewing yeast flocculation. The limited information available on the colloidal nature and properties of brewing yeast cells is also summarized.  相似文献   
998.
    
The use of transition-metal complexes as photocatalysts have allowed the performance of diverse organic transformations in an outstanding manner, characterized not only by high yields, TOF, and selectivity values, but also by modulating and providing access to novel molecular structures that, without them, would be difficult if not impossible. However, one of the biggest concerns regarding the use of these photocatalysts relies on the difficulties associated with their isolation from reaction media and reutilization once the chemical process ends. The above, besides contaminating reaction products and requiring out tedious purification processes, prompts the inevitable loss of the catalyst, directly affecting its recyclability. In addition, this situation results in negative outcomes from an economic and environmental perspective, since transition-metal complexes are usually expensive materials, and their unsuccessful recovery could result in leakage into the environment. These drawbacks served as inspiration for the elaboration of the present review focused on the development of novel strategies developed during the last decade for the successful recovery of these species. The strategies summarized herein, whether for homogeneous or heterogeneous systems, are based on the use of thermotropic solvents, changes in the hydrophilic balance of the catalyst, the employment of polymers, copolymers, porous macromolecular structures, and inorganic nanostructures as support of these entities. Moreover, the use of organized and confining media, such as micelles and gels in this context, is also discussed. We hope that this review will motivate the search for new strategies to develop novel catalytic systems, understanding that high performance is based not only on yields but also on recyclability, sustainability, and responsibility to the environment.

  相似文献   

999.
    
Since the discovery of superconductivity at temperatures above the technologically promising liquid nitrogen temperatures, applications based on superconductors have expanded and are being put to commercial use. However, superconductivity at higher temperatures typically occurs in complex materials requiring stringent material and environmental constraints. Such restraints make the realization and integration of these materials with normal materials a nontrivial aspect. In this progress report, unique features of these superconductors in terms of their synthesis, physical properties determining interface electrical transport, and their applications are discussed. A detailed progress report on these applications with remarks on efforts taken to integrate these devices with traditional platforms and semiconducting materials is provided.  相似文献   
1000.
    
The early detection of bone microdamages is crucial to make informed decisions about the therapy and taking precautionary treatments to avoid catastrophic fractures. Conventional computed tomography (CT) imaging faces obstacles in detecting bone microdamages due to the strong self‐attenuation of photons from bone and poor spatial resolution. Recent advances in CT technology as well as novel imaging probes can address this problem effectively. Herein, the bone microdamage imaging is demonstrated using ligand‐directed nanoparticles in conjunction with photon counting spectral CT. For the first time, Gram‐scale synthesis of hafnia (HfO2) nanoparticles is reported with surface modification by a chelator moiety. The feasibility of delineating these nanoparticles from bone and soft tissue of muscle is demonstrated with photon counting spectral CT equipped with advanced detector technology. The ex vivo and in vivo studies point to the accumulation of hafnia nanoparticles at microdamage site featuring distinct spectral signal. Due to their small sub‐5 nm size, hafnia nanoparticles are excreted through reticuloendothelial system organs without noticeable aggregation while not triggering any adverse side effects based on histological and liver enzyme function assessments. These preclinical studies highlight the potential of HfO2‐based nanoparticle contrast agents for skeletal system diseases due to their well‐placed K‐edge binding energy.  相似文献   
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