全文获取类型
收费全文 | 121686篇 |
免费 | 9917篇 |
国内免费 | 5468篇 |
专业分类
电工技术 | 6215篇 |
技术理论 | 1篇 |
综合类 | 9061篇 |
化学工业 | 21065篇 |
金属工艺 | 5913篇 |
机械仪表 | 7123篇 |
建筑科学 | 8770篇 |
矿业工程 | 2318篇 |
能源动力 | 4068篇 |
轻工业 | 9956篇 |
水利工程 | 2196篇 |
石油天然气 | 4890篇 |
武器工业 | 766篇 |
无线电 | 14323篇 |
一般工业技术 | 14896篇 |
冶金工业 | 5995篇 |
原子能技术 | 1560篇 |
自动化技术 | 17955篇 |
出版年
2024年 | 386篇 |
2023年 | 1505篇 |
2022年 | 2807篇 |
2021年 | 4254篇 |
2020年 | 3337篇 |
2019年 | 3084篇 |
2018年 | 3396篇 |
2017年 | 3627篇 |
2016年 | 3528篇 |
2015年 | 4186篇 |
2014年 | 5734篇 |
2013年 | 7535篇 |
2012年 | 7989篇 |
2011年 | 8493篇 |
2010年 | 7564篇 |
2009年 | 7416篇 |
2008年 | 7195篇 |
2007年 | 6912篇 |
2006年 | 6774篇 |
2005年 | 5717篇 |
2004年 | 4522篇 |
2003年 | 4055篇 |
2002年 | 4571篇 |
2001年 | 3960篇 |
2000年 | 3057篇 |
1999年 | 2547篇 |
1998年 | 2237篇 |
1997年 | 1804篇 |
1996年 | 1666篇 |
1995年 | 1373篇 |
1994年 | 1061篇 |
1993年 | 899篇 |
1992年 | 655篇 |
1991年 | 501篇 |
1990年 | 467篇 |
1989年 | 331篇 |
1988年 | 289篇 |
1987年 | 216篇 |
1986年 | 172篇 |
1985年 | 155篇 |
1984年 | 127篇 |
1983年 | 125篇 |
1982年 | 107篇 |
1981年 | 90篇 |
1980年 | 78篇 |
1979年 | 60篇 |
1978年 | 50篇 |
1977年 | 64篇 |
1976年 | 103篇 |
1974年 | 46篇 |
排序方式: 共有10000条查询结果,搜索用时 500 毫秒
101.
Md. Abdur Rahim Shamim Mahbub Md. Kamrul Islam Sk. Md. Ali Ahsan Shahed Rana Malik Abdul Rub Anish Khan Md. Anamul Hoque 《Journal of surfactants and detergents》2020,23(2):457-470
Conductometric and cloud point (CP) measurement studies have been performed to investigate the interaction of tetradecyltrimethylammonium bromide (TTAB) and Triton® X-100 (TX-100) with ciprofloxacin hydrochloride (CFH) in different solvents over the temperature range of 295.15–315.15 K. CFH is used for the treatment of various bacterial infections. The observed critical micelle concentration (CMC) values of TTAB were found to be reduced in the presence of electrolytes (Na2SO4/Na3PO4), and this reduction proceeds with the elevation of salt concentration. The order of the CMC of TTAB follows the trend: > >. The observed CMC values of TTAB were found to increase with increasing temperature and decrease with increasing concentration of CFH in aqueous medium. The values of Gibbs free energy of micellization () for the TTAB/TTAB + CFH mixture were found to be negative, implying spontaneous micellization. The estimated CP of TX-100 decreases with increasing concentration of TX-100 in aqueous medium. The CP values first decrease with increasing concentration of CFH and then increase at higher concentration of CFH almost in all cases investigated. The values of free energy of clouding were found to be positive in all cases studied implying that phase separation of TX-100 was nonspontaneous. The other thermodynamic parameters associated with the micellization of TTAB and the phase separation of TX-100 were estimated and explained. 相似文献
102.
Seyedeh Nooshin Banitaba Dariush Semnani Elahe Heydari‐Soureshjani Behzad Rezaei Ali A Ensafi Ahmadreza Taghipour‐Jahromi 《Polymer International》2020,69(8):675-687
In this study, solvent‐free nanofibrous electrolytes were fabricated through an electrospinning method. Polyethylene oxide (PEO), lithium perchlorate and ethylene carbonate were used as polymer matrix, salt and plasticizer respectively in the electrolyte structures. Keggin‐type hetero polyoxometalate (Cu‐POM@Ru‐rGO, Ni‐POM@Ru‐rGO and Co‐POM@Ru‐rGO (POM, polyoxometalate; rGO, reduced graphene oxide)) nanoparticles were synthesized and inserted into the PEO‐based nanofibrous electrolytes. TEM and SEM analyses were carried out for further evaluation of the synthesized filler structures and the electrospun nanofibre morphologies. The fractions of free ions and crystalline phases of the as‐spun electrolytes were estimated by obtaining Fourier transform infrared and XRD spectra, respectively. The results showed a significant improvement in the ionic conductivity of the nanofibrous electrolytes by increasing filler concentrations. The highest ionic conductivity of 0.28 mS cm?1 was obtained by the introduction of 0.49 wt% Co‐POM@Ru‐rGO into the electrospun electrolyte at ambient temperature. Compared with solution‐cast polymeric electrolytes, the electrospun electrolytes present superior ionic conductivity. Moreover, the cycle stability of the as‐spun electrolytes was clearly improved by the addition of fillers. Furthermore, the mechanical strength was enhanced with the insertion of 0.07 wt% fillers to the electrospun electrolytes. The results implied that the prepared nanofibres are good candidates as solvent‐free electrolytes for lithium ion batteries. © 2020 Society of Chemical Industry 相似文献
103.
Qiang Wang Lei Shen Tong Xue Gao Cheng Cheng Zhi Huang Hong Jin Fan Yuan Ping Feng 《Advanced functional materials》2021,31(2):2002187
The {100} facet of single-crystalline TiO2(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO2(B) nanobelts from H2Ti3O7 with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO2 formula with specific capacity up to 335 mAh g−1, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g−1 after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures. 相似文献
104.
Oktaviana Laily Tong Van-Canh Hong Seong-Wook 《Journal of Mechanical Science and Technology》2019,33(2):837-845
Journal of Mechanical Science and Technology - Skidding is a phenomenon that frequently occurs in ball–raceway contact areas of bearings and often leads to their early failure. This paper... 相似文献
105.
A novel dual-rotation bobbin tool friction stir welding (DBT-FSW) was developed, in which the upper shoulder (US) and lower shoulder (LS) have different rotational speeds. This process was tried to weld 3.2 mm thick aluminum-lithium alloy sheets. The metallographic analysis and torque measurement were carried out to characterize the weld formability. Experimental results show that compared to conventional bobbin tool friction stir welding, the DBT-FSW has an excellent process stability, and can produce the defect-free joints in a wider range of welding parameters. These can be attributed to the significant improvement of material flow caused by the formation of a staggered layer structure and the unbalanced force between the US and LS during the DBT-FSW process. 相似文献
106.
Effect of Supports and Promoters on the Performance of Ni-Based Catalysts in Ethanol Steam Reforming
Thanh Khoa Phung Thong Le Minh Pham Anh-Nga T. Nguyen Khanh B. Vu Ha Ngoc Giang Tuan-Anh Nguyen Thanh Cong Huynh Hong Duc Pham 《化学工程与技术》2020,43(4):672-688
Ethanol steam reforming (ESR) is one of the potential processes to convert ethanol into valuable products. Hydrogen produced from ESR is considered as green energy for the future and can be an excellent alternative to fossil fuels with the aim of mitigating the greenhouse gas effect. The ESR process has been well studied, using transition metals as catalysts coupled with both acidic and basic oxides as supports. Among various reported transition metals, Ni is an inexpensive material with activity comparable to that of noble metals, showing promising ethanol conversion and hydrogen yields. Additionally, different promoters and supports were utilized to enhance the hydrogen yield and the catalyst stability. This review summarizes and discusses the influences of the supports and promoters of Ni-based catalysts on the ESR process. 相似文献
107.
108.
The objective of this paper is to review and document the mine fleet management systems’ models and algorithms. The purpose is to understand the algorithms behind the fleet management systems and the proposed academic solutions in this area to identify any gaps in the current literature and to open up opportunities to establish research questions that need to be addressed in an integrated simulation and optimisation operational planning research framework. In this paper, we review industrial fleet management systems and the main academic algorithms behind such systems. The fleet management systems are divided into three subsequently related problems to review: shortest path, production optimisation and real-time dispatching. Finally, the limitations of current algorithms for fleet management systems are documented in terms of mining practice feasibility and optimality of the solution on large-scale problems. The results of this literature review enable us to evaluate the logical links between major components of an integrated simulation and optimisation operational planning framework with current theory of fleet management systems. 相似文献
109.
User Modeling and User-Adapted Interaction - Personality plays a pivotal role at work. Many scholars have investigated the association between personality and language usage habits in the English... 相似文献
110.
Inam Ridha Ali Basiri Sudhakar Godeshala Md Zubair Ebne Rafique Deepanjan Ghosh Jason Williams Nikhilesh Chawla Jung Keun Lee Jacquelyn Kilbourne Yu Yao Kaushal Rege 《Advanced functional materials》2021,31(6):2007811
Poor strength, infection, leakage, long procedure times, and inflammation limit the efficacy of common tissue sealing devices in surgeries and trauma. Light-activated sealing is attractive for tissue sealing and repair, and can be facilitated by the generation of local heat following absorption of nonionizing laser energy by chromophores. Here, the inherent ability of biomaterials is exploited to absorb nonionizing, mid-infrared (midIR) light in order to engender rapid photothermal sealing and repair of soft tissue wounds. In this approach, the biomaterial simultaneously acts as a photothermal convertor as well as a biosealant, which dispenses the need for exogeneous light-absorbing nanoparticles or dyes. Biomechanical recovery, mathematical modeling, histopathology analyses, tissue strain mapping using digital imaging correlation, and visualization of the biosealant-tissue interface using hyperspectral imaging indicate superior performance of midIR sealing in live mice compared to conventional sutures and glue. The midIR-biosealant approach demonstrates rapid sealing of soft tissues, improves cosmesis, lowers potential for scarring, obviates safety concerns because of the nonionizing light used, and allows adoption of a wide diversity of biomaterials. Taken together, the studies demonstrate a novel advance both in biomaterials for surgical sealing along with the use of nonionizing midIR light, with high potential for clinical translation. 相似文献