RAPID PYROLYSIS OF EASTERN CANADIAN COALS BY FREE FALL REACTORS

Abstract

The effect of temperature was investigated on the rapid pyrolysis of Prince, Lingan and No. 26 coals in the temperature range of 525^° to 750^°C using a 600 cm high stainless-steel free fall reactor at atmospheric pressure.

The yields of char, condensibles and gaseous products were determined at 25^°C intervals. Gaseous products were analysed for H₂, CO, CO₂, CH₄ and C₂+.

Volatile product (condensible and gas) yields exceeded the volatile product in the A.S.T.M. methods at and above 700^°C.

Some experiments using Prince coal were repeated at reduced pressure (50 mm mercury) in both the 600 cm height stainless-steel and a 140 cm height quartz reactor in order to find out the effect of pressure and retention time.

The experimental results indicated that the condensable yield was higher at the lower pressure and at the shorter retention time. The effect of retention time was far more pronounced.     

Prediction of heavy oil viscosity using a radial basis function neural network

Heavy oil and extra heavy oil resources comprise about 75% of petroleum resources. The most important characteristic of heavy oils is their viscosity. Consequently, to extract and prepare these kinds of crude oil for use, great emphasis should be put on viscosity. The present study highlights the application of intelligent model named radial basis function (RBF) network optimized by genetic algorithm for estimation of diluted heavy oil viscosity in presence on kerosene. The input parameters of model were temperature and mass fraction of kerosene. The output of model was viscosity of heavy oil. Genetic algorithm was utilized to optimize the tuning parameters of RBF model. The outcomes of this study showed that the proposed model is accurate in estimation of target data.     

From MEMS to NEMS： Smart Chips with Senses and Muscles

The last half-century was transformed by the electronic revolution that essentially reproduced the human brain and its computing capacity on a chip. But over time, scientists have realized that something was missing to give life, so to speak, to the small chip with a brain： One needed to awaken its senses and develop its muscles! This challenge was solved through MEMS （micro electro mechanical systems）. Indeed, MEMS today are equipped with the sense of sight, smell, hearing, taste and touch through microsensors. They are also capable of physical exertion through small muscles called microactuators. These new capabilities open wide fields of imagination and important specific applications.     

Detection of Leakage Freshwater and Friction Factor Calibration in Drinking Networks Using Central Force Optimization

Inverse Transient Analysis (ITA) is a powerful approach for leak detection and calibration of friction factors in pressurized pipes. Through this method, a transient flow is initiated and pressures are measured somewhere in the system. Then, a nonlinear programming (NLP) problem with a least-squares criterion objective function is developed to minimize discrepancies between the measured and calculated pressures at measurement sites. Solving the raised NLP results in the problem’s unknowns being leakage specifications and pipe friction factors. For this purpose, various optimization techniques may be utilized. This issue is a major challenge for ITA-based methods. The present work aims at applying the new method of Central Force Optimization (CFO) to the problem of ITA. CFO is a deterministic metaheuristic inspired by gravitational kinematics in which small objects in space are dragged by bigger ones. Herein, the concept and main structure of CFO are represented as well as of CFO. A reference pipe-network is considered to be solved using the ITA equipped with CFO. The results are then discussed compared to the previous works. It is concluded that CFO is easy to implement, computationally efficient and has a remarkable performance in solving leak detection problem.     

Multiple responses analysis and modeling of Fenton process for treatment of high strength landfill leachate

Landfill leachate is one of the most recalcitrant wastes for biotreatment and can be considered a potential source of contamination to surface and groundwater ecosystems. In the present study, Fenton oxidation was employed for degradation of stabilized landfill leachate. Response surface methodology was applied to analyze, model and optimize the process parameters, i.e. pH and reaction time as well as the initial concentrations of hydrogen peroxide and ferrous ion. Analysis of variance showed that good coefficients of determination were obtained (R2 > 0.99), thus ensuring satisfactory agreement of the second-order regression model with the experimental data. The results indicated that, pH and its quadratic effects were the main factors influencing Fenton oxidation. Furthermore, antagonistic effects between pH and other variables were observed. The optimum H2O2 concentration, Fe(II) concentration, pH and reaction time were 0.033 mol/L, 0.011 mol/L, 3 and 145 min, respectively, with 58.3% COD, 79.0% color and 82.1% iron removals.     

Temporal Regionalization of 7-Day Low Flows in the St. Lawrence Watershed in Quebec (Canada)

Winter and summer 7-day low flows of eighteen natural rivers in the St. Lawrence River watershed of Quebec were analyzed over the period from 1934 to 2000. The rivers were first subdivided into three modes using principal component analysis. Two of these modes are located on the south shore of the St. Lawrence River, respectively south (Southeast mode) and north (East mode) of the 47°N, and the third (Southwest mode) is located on the north shore. The Southeast mode shows a significant increase in 7-day low flows in winter and summer due to increasing summer and fall precipitation, whereas the Southwest mode shows a significant decrease in summer 7-day low flows due to an increase in evapotranspiration. No significant change in winter and summer 7-day low flows is observed in the East mode. Results show that the variability of 7-day low flows and their link with climate indices are mainly seasonally dependent. The North Atlantic Oscillation (NAO) is the only index which is correlated to 7-day low flows in all three modes. This correlation is positive for north shore rivers and negative for south shore rivers. Furthermore, only north shore rivers are correlated to NAO in both winter and summer.     

Technical and cost assessment of energy efficiency improvement and greenhouse gas emission reduction potentials in Thai cement industry

The cement industry is one of the most energy-consuming industries in Thailand, with high associated carbon dioxide (CO₂) emissions. The cement sector accounted for about 20.6 million tonnes of CO₂ emissions in 2005. The fuel intensity of the Thai cement industry was about 3.11 gigajoules (GJ)/tonne cement; the electricity intensity was about 94.3 kWh/tonne cement, and the total primary energy intensity was about 4.09 GJ/tonne cement in 2005 with the clinker to cement ratio of around 82%. In this study, the potential application of 47 energy-efficiency measures is assessed for the Thai cement industry. Using a bottom-up electricity conservation supply curve model, the cost-effective electricity efficiency improvement potential for the Thai cement industry is estimated to be about 265 gigawatt hours (GWh), which accounts for 8% of total electricity use in the cement industry in 2005. Total technical electricity-saving potential is 1,697 GWh, which accounts for 51% of total electricity use in the cement industry in 2005. The CO₂ emission reduction potential associated with the cost-effective electricity savings is 159 kilotonne (kt) CO₂, while the total technical potential for CO₂ emission reductions is 902 ktonne CO₂. The fuel conservation supply curve model shows a cost-effective fuel-efficiency improvement potential of 17,214 terajoules (TJ) and a total technical fuel efficiency improvement potential equal to 21,202 TJ, accounting for 16% and 19% of the total fuel use in the cement industry in 2005, respectively. CO₂ emission reduction potentials associated with cost-effective and technical fuel-saving measures are 2,229 ktonne and 2,603 ktonne, respectively. Sensitivity analyses were conducted for discount rate, electricity and fuel prices, and exchange rate that showed the significant influence of these parameters on the results. Hence, the results of the study should be interpreted with caution.     

Effect of some BED blends on the equivalence ratio, exhaust oxygen fraction and water and oil temperature of a diesel engine

Nowadays, natural-based oxygenated fuels, especially biodiesel and ethanol, have been considered as substitutes for fossil fuels. Because of relatively lower energy content of oxygenated fuels, it is necessary to blend them with fossil ones. In this research, authors conducted an investigation on some BED blends to determine and compare their effects on equivalence ratio, exhaust oxygen fraction and water and oil temperature in a diesel engine. For this purpose, 18 different blendes of ethanol and biodiesel with net diesel fuel were tested in a MT4-244 engine¹ considering two engine speeds in full load condition. In almost all samples the equivalence ratio decreased with increasing of biodiesel and ethanol percents. Exhaust oxygen fraction in all of samples increased with increasing of biodiesel and ethanol percents, whereas the engine water and oil temperatures slightly reduced.     

Highly reflective coatings for interior and exterior steel cladding and the energy efficiency of buildings

The effect of surface heat-radiation properties of coil-coated steel cladding material on the energy efficiency of buildings in Nordic climate is addressed by parallel temperature and energy usage measurements in a series of test cabins with different exterior solar reflectivity and interior thermal reflectivity. During one year, a number of one- or two-week experiments with air conditioner cooling and electrical floor heating were made while logging air-, radiation- and surface temperatures, energy consumption and weather conditions. Measurements show significant energy savings in the test cabins by the use of high thermal reflectivity interior surfaces both during heating and cooling and a strongly reduced cooling demand by the use of high solar reflectivity exterior surfaces. Results are interpreted within the context of a steady-state energy flux model, to illuminate the importance of surface resistance properties (radiation and convective heat dissipation).     

Exergo‐economic analysis of micro pin fin heat sinks

A parametric study of thermoeconomic performance over four micro pin fin heat sinks of different spacing and shapes was conducted. Unit cost per product exergy, relative cost difference, and exergo‐economic factor were utilized to evaluate the thermoeconomic performance. The effect of working fluid on the thermoeconomic performance was also investigated using R‐123 and water as working fluids. Unit costs per product exergy were obtained to evaluate the product costs (total exergy change between exit and inlet streams) in micro pin fin heat sinks at fixed mass flow rate and fixed pressure drop. The results of the thermoeconomic analysis were compared with the results of a past exergy performance study by the author. In the light of raw experimental data acquired from the past studies of the author, important differences between the results of exergy and exergo‐economic performances were observed. It was found that the unit cost of exergy change decreased as electrical power increased and the relative cost difference approached to unity at high electrical powers (greater than 20 W). Moreover, high exergo‐economic factor values (more than 0.5) were obtained at low electrical powers while exergo‐economic factors had a small value at high electrical powers. When looking at the effect of the working fluid, higher cost per Watts of the products (up to the double of R‐123) was obtained with water compared with R‐123 at both fixed mass flow rate and pressure drop. No significant effect of pin fin spacing on the unit cost of exergy change was observed at fixed mass flow rate, while higher unit costs (up to 102%) were recorded at fixed pressure drop for scarcely packed pin fin heat sinks. Finally, the unit cost of exergy change was found to be independent of pin fin shape at fixed mass flow rate, whereas at fixed pressure drop, the hydrofoil‐based pin fin heat sink had higher unit costs (up to 1.8 times as much) when compared with the unit costs of pin fin heat sinks having flow separation promoting pin fins. Copyright © 2010 John Wiley & Sons, Ltd.