Practical Thermal Multi–Scale Analysis for Composite Materials–Mechanical-Orientated Approach

This paper describes a thermal multi-scale formulation for composite materials based on a mechanical homogenization approach. The presented formulation evaluates the effective macroscopic thermal conductivity of the composite materials and also the microscopic heat flux field by scaling down to the micro-scale level. The effective thermal conductivity of the composite materials was calculated by applying the homogenization theory over the unit cell. The uniqueness of the presented multi-scale analysis related to the elastic problems solved at the microscopic scale (unit cell). This method has the advantage of applying periodic boundary conditions and uniform macroscopic temperature gradient over the unit cell. The proposed thermal multi-scale analysis was verified and its efficiency was demonstrated on large scale problem.     

Defining the relationship between fetal Doppler indices,abdominal circumference and growth rate in severe fetal growth restriction using functional linear discriminant analysis

The relationship between Doppler measurements, size and growth rate in fetal growth restriction has not been defined. We used functional linear discriminant analysis (FLDA) to investigate these parameters taking account of the difficulties inherent in exploring relationships between repeated observations from a small number of cases. In 40 fetuses with severe growth restriction, serial abdominal circumference (AC), umbilical, middle cerebral artery (MCA) and ductus venosus Doppler pulsatility index measurements were recorded. In 11 singleton fetuses with normal growth, umbilical artery pulsatility index only was measured. Data were expressed as z-scores in relation to gestation and analysed longitudinally using FLDA. In severe growth restriction, the Spearman correlation coefficients between umbilical artery pulsatility index and AC z-score, MCA pulsatility index and AC z-score and ductus venosus pulsatility index z-score and AC z-score were, respectively: −0.36, p = 4.4 × 10⁻⁷; 0.70, p = 1.1 × 10⁻¹⁷ and −0.50, p = 8.1 × 10⁻⁴. No relationship was seen between Doppler parameters and growth rate. There was no relationship between umbilical artery pulsatility index and AC nor growth rate in normally grown fetuses. In severe fetal growth restriction, Doppler changes are related to absolute fetal AC size, not growth rate.     

Local versus Global in Quasi-Conformal Mapping for Medical Imaging

A method and algorithm of flattening folded surfaces, for two-dimensional representation and analysis of medical images, are presented. The method is based on an application to triangular meshes of classical results of Gehring and Väisälä regarding the existence of quasi-conformal and quasi-isometric mappings.The proposed algorithm is basically local and, therefore, suitable for extensively folded surfaces encountered in medical imaging. The theory and algorithm guarantee minimal distance, angle and area distortion. Yet, the algorithm is relatively simple, robust and computationally efficient, since it does not require computational derivatives. Both random-starting-point and curvature-based versions of the algorithm are presented.We demonstrate the algorithm using medical data obtained from real CT images of the colon and MRI scans of the human cortex. Further applications of the algorithm, for image processing in general are also considered. The globality of this algorithm is also studied, via extreme length methods for which we develop a technique of computing straightest geodesics on polyhedral surfaces.     

Digital library information-technology infrastructures

This paper charts a research agenda on systems-oriented issues in digital libraries. It focuses on the most central and generic system issues, including system architecture, user-level functionality, and the overall operational environment. With respect to user-level functionality, in particular, it abstracts the overall information lifecycle in digital libraries to five major stages and identifies key research problems that require solution in each stage. Finally, it recommends an explicit set of activities that would help achieve the research goals outlined and identifies several dimensions along which progress of the digital library field can be evaluated.     

Modelling the dynamics of log‐domain circuits

Log‐domain filters are an intriguing form of externally linear, internally nonlinear current‐mode circuits, in which a compression stage is first used to convert the input currents to the logarithmic domain, then analogue processing is carried out on the resulting voltages, and finally input–output linearity is restored by mapping the output voltages to current form through an expansion stage. The compressing and expanding operations confer on log‐domain filters a number of desirable features, but they may be responsible for the loss of external linearity. In this paper, sufficient conditions for the external linearity of log‐domain LC‐ladders are established, and the local nature of this external linearity is highlighted. Certain log‐domain LC‐ladders employing floating capacitors may exhibit externally nonlinear behaviour even for zero input and very small initial conditions. We show how transistor parasitic capacitances are central to the emergence of this behaviour, and must be incorporated in the circuit model. Copyright © 2006 John Wiley & Sons, Ltd.     

Langevin-schroedinger formulation of electronic tunneling through a molecular bridge with a dissipative acceptor

Modeling electronic tunneling through molecular bridges is desired in order to understand the mechanism of long-range electron transfer reactions in nature, as well as for the design of novel molecular electronics devices. Particularly interesting is the effect of the nuclear motion at the molecular bridge on the electron transfer mechanism and rate. In this work we study the effect of electronic nuclear coupling at the molecular bridge on a unidirectional electronic tunneling process from an electron donor into a dissipative acceptor, as may appear in controlled electron transfer reactions at biological membranes, or in heterogeneous electron transfer reactions. The model includes a collection of harmonic bath modes coupled to the dissipative acceptor site and a single mode at the molecular bridge. The parameters of the dissipative bath are tuned such that the electronic population decays from the donor to the acceptor. This process is simulated using a time-dependent nonlinear Langevin-Schroedinger equation, based on a mean-field approximation for the electronic-nuclear coupling at the acceptor site and a numerically exact treatment of the electronic-nuclear coupling at the molecular bridge. The simulations at zero temperature and weak electronic-nuclear coupling demonstrate that electronic tunneling is promoted by coupling to the nuclear mode at the bridge. This result is consistent with our previous studies of electronic tunneling oscillations in a symmetric donor-bridge-acceptor complex, and it emphasizes the importance of electronic nuclear coupling in analyzing long-range electron transfer processes through molecular bridges or wires.     

Synthesis of Zirconia Colloids from Aqueous Salt Solutions

We monitor the synthesis of ZrO₂ colloids from dissolved ZrOCl₂·8H₂O using quasi-elastic light scattering and cryo-transmission electron microscopy (cryo-TEM). We investigate the effects of both precursor salt concentration and pH on the final size distribution. We find that the initial pH plays the most important role in the final particle size and yield. These trends and cryo-TEM observations help elucidate the roles of nucleation, aggregation, and recrystallization.     

4D printing shape memory polymers for dynamic jewellery and fashionwear

4D printing is a novel approach that enables dynamic functionality in ordinary static object. We used a methacrylated semicrystalline polymer to print objects exhibiting thermally triggered shape memory behaviour. By exploring various molecular weights, it was found that a methacrylated polycaprolactone polymer with a number average molecular weight of 10,000?g?mol^?1 exhibited the best thermal and mechanical behaviour. The effect of dyes’ addition to the ink formulation on the photopolymerisation and on the printing processes was evaluated. The ink was utilised for demonstrating fabrication of dynamic jewellery and a shoe accessory by Digital Light Processing printing.