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71.
    
The harmonic distortion (HD) of MOSFETs operating in the triode regime is thoroughly investigated for the different device types of a multi-V/sub th/ deep-submicrometer 0.12-/spl mu/m silicon-on-insulator (SOI) CMOS process. The measurements performed in a wide temperature range (25/spl deg/C-220/spl deg/C) and on devices with different oxide thicknesses and channel dopings help to identify the relative impact of the different physical mechanisms at the origin of HD. A measurement-based and design-oriented methodology is finally developed to compare device types, biases and configurations responding to practical design targets.  相似文献   
72.
Carbon dioxide capture and storage (CCS) has been actively researched as a strategy to mitigate CO(2) emissions into the atmosphere. The three components in CCS are monitoring, verification, and accounting (MVA). Seismic monitoring technologies can meet the requirements of MVA, but they require a quantitative relationships between multiphase saturation distributions and wave propagation elastic properties. One of the main obstacles for quantitative MVA activities arises from the nature of the saturation distribution, typically classified anywhere from homogeneous to patchy. The emerging saturation distribution, in turn, regulates the relationship between compressional velocity and saturation. In this work, we carry out multiphase flow simulations in a 2-D aquifer model with a log-normal absolute permeability distribution and a capillary pressure function parametrized by permeability. The heterogeneity level is tuned by assigning the value of the Dykstra-Parson (DP) coefficient, which sets the variance of the log-normal horizontal permeability distribution in the entire domain. Vertical permeability is a 10th of the horizontal value in each gridcell. We show that despite apparent differences in saturation distribution among different realizations, CO(2) trapping and the V(p)-S(w) Rock Physics relationship are mostly functions of the DP coefficient. When the results are compared with the well accepted limits, Gassmann-Wood (homogeneous) (A Text Book of Sound; G. Bell and Suns LTD: London, 1941) and Gassmann-Hill (patchy) models, the V(p)-S(w) relationship never reaches the upper bound, that is, patchy model curve, even at the highest heterogeneity level in the model.  相似文献   
73.
Journal of Mechanical Science and Technology - This research introduces a 6-degree-of-freedom parallel manipulator with a reconfigurable fixed base; the manipulator performance has been evaluated...  相似文献   
74.
    
Poly(diethylaminoethyl methacrylamide) (PEAM), a dendronized polymer, was synthesized according to classical procedures. Monomers and polymers were characterized by spectroscopic measurements. The results obtained were in agreement with the expected chemical structure. The phase behavior of blends of PEAM with diclofenac (DCF), ibuprofen (IBU) , and paracetamol (PCM) were studied by different experimental techniques. FT‐IR, UV‐Vis, DSC , and TGA measurements suggested important interactions between the blended components. Thermogravimetric analysis (TGA) indicated the temperature at which the dendronized polymer released a small molecule. AFM measurements and molecular dynamics (MD) simulations were used to better understand the nature of the interactions and to estimate the distance between the components of the blends to explain the interaction involved. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42450.  相似文献   
75.
    
Dendronized poly(diethylaminoethyl methacrylamide) (PEAM) was studied in blends containing isomeric cyclic dialcohols. Monomers and polymers were characterized by spectroscopic measurements. The phase behaviors of blends of PEAM with 1,2‐, 1,3‐ and 1,4‐cyclohexanediols (1,2‐CHD, 1,3‐CHD and 1,4‐CHD, respectively) were established. Transparent films of the blends exhibited a single glass‐transition temperature (Tg). Thermogravimetric analysis (TGA) revealed the temperature at which the polymer releases the small molecules. UV‐vis spectra of 1,3‐CHD and 1,4‐CHD derivatives showed an isosbestic point that indicated the association of the alcohols. FT‐IR measurements showed shifts in several absorption bands. The results were analyzed in terms of the side‐chain structure and the interactions involved. AFM measurements revealed differences between the polymer and the blends. Compatibilization of blends of PEAM/CHDs occurred via the formation of hydrogen bonds, although hydrophobic interactions could not be disregarded. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42267.  相似文献   
76.
    
Highly concentrated inverse anionic polymeric emulsions (with a solid content of up to 63 wt %) were prepared using a two‐step methodology: (i) First, acrylamide, acrylic acid, and its ammonium salts crosslinked copolymers were obtained by inverse emulsion polymerization, (ii) The water/volatile oil mixture was then separated from the heterogeneous system by vacuum distillation. To maintain sufficient stability during the reaction and distillation processes, a ternary surfactant mixture was used. A surface response methodology was employed to obtain the optimal values of the factors involved in both process and product specifications, and to maximize the high performance of these inverse anionic polymer emulsions. This yielded a product containing up to 63.2 wt % solids capable of achieving Brookfield viscosities as high as 40.3 Pa·s, using an aliquote of these concentrated inverse polymer emulsions (1.8 wt % in deionized water). Rheological characterization (oscillatory and rotational measurements) was carried out to evaluate the behavior of the diluted inverse anionic polymer emulsion in water thickening. The methodology developed can be used to formulate a wide range of viscoelastic (G″/G′) water‐based products from anionic water soluble polymers. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43502.  相似文献   
77.
    
In this study, antioxidant food‐packaging materials were developed by the incorporation of merkén, an aboriginal Chilean spice, into a biodegradable polymer matrix, poly(lactic acid). Antioxidant activity assays and the phenolic content of merkén showed interesting results compared to other condiments, such as oregano and parsley. Active materials with merkén at 3 and 5 wt % were successfully obtained by extrusion. Chromatographic analysis revealed the chemical composition of merkén, and its active material was based on interesting flavonoids and organic acids, such as catechin, myricetin, and gallic and ellagic acids. Scanning electron micrographs showed that the merkén particles accumulated in aggregates; this resulted in an increase in the permeability values and a reduction in the crystallinity and mechanical properties of the polymer matrix. Nevertheless, these materials presented interesting antioxidant activities as radical scavengers on aqueous food simulants. The kinetics of release was dependent on the type of food and the nominal content of merkén in the films. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44692.  相似文献   
78.
    
Biorefineries are considered as an integrative thinking that focuses on the possibility of obtaining as many added‐value products as technically and economically feasible. However, in practice most biorefineries comprise only enzymatic or chemical pretreatment followed by biofuel generation. The drop in oil prices may menace the development of this young industry, as has happened before in history. This has become a fundamental reason for which the biofuel industry should not consider only biofuels production, but enzyme and non‐fuel based chemicals as well. Hence, this work aims at overviewing the most important enzymes involved in biotechnological processes and to describe their role in biorefineries. Bioethanol, biogas and biodiesel biorefineries are overviewed, along with the integrated and industrial types. Finally separation and purification processes in biorefineries are discussed. © 2016 Society of Chemical Industry  相似文献   
79.
    
In this paper, a Cox proportional hazard model with error effect applied on the study of an accelerated life test is investigated. Statistical inference under Bayesian methods by using the Markov chain Monte Carlo techniques is performed in order to estimate the parameters involved in the model and predict reliability in an accelerated life testing. The proposed model is applied to the analysis of the knock sensor failure time data in which some observations in the data are censored. The failure times at a constant stress level are assumed to be from a Weibull distribution. The analysis of the failure time data from an accelerated life test is used for the posterior estimation of parameters and prediction of the reliability function as well as the comparisons with the classical results from the maximum likelihood estimation. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
80.
The advancement of experimental and computational resources has facilitated the use of computational fluid dynamics (CFD) models as a predictive tool for mixing behaviour in full-scale waste stabilization pond systems. However, in view of combining hydraulic behaviour with a biokinetic process model, the computational load is still too high for practical use. This contribution presents a method that uses a validated CFD model with tracer experiments as a platform for the development of a simpler compartmental model (CM) to describe the hydraulics in a full-scale maturation pond (7 ha) of a waste stabilization ponds complex in Cuenca (Ecuador). 3D CFD models were validated with experimental data from pulse tracer experiments, showing a sufficient agreement. Based on the CFD model results, a number of compartments were selected considering the turbulence characteristics of the flow, the residence time distribution (RTD) curves and the dominant velocity component at different pond locations. The arrangement of compartments based on the introduction of recirculation flow rate between adjacent compartments, which in turn is dependent on the turbulence diffusion coefficient, is illustrated. Simulated RTD’s from a systemic tanks-in-series (TIS) model and the developed CM were compared. The TIS was unable to capture the measured RTD, whereas the CM predicted convincingly the peaks and lags of the tracer experiment using only a minimal fraction of the computational demand of the CFD model. Finally, a biokinetic model was coupled to both approaches demonstrating the impact an insufficient hydraulic model can have on the outcome of a modelling exercise. TIS and CM showed drastic differences in the output loads implying that the CM approach is to be used when modelling the biological performance of the full-scale system.  相似文献   
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