An experimental study of the synergistic effects of BMIM.BF4, BMIM.DCA and TEACl aqueous solutions on methane hydrate formation

In this work, the effects of three ionic liquids (ILs), namely, 1-butyl-3-methylimidazolium tetrafluoroborate, 1-butyl-3-methylimidazolium dicyanamide and tetraethyl-ammonium chloride, on methane hydrate formation and dissociation kinetic parameters were studied. The kinetic parameters including the initial rate of hydrate formation, hydrate stability at atmospheric pressure and hydrate storage capacity were evaluated. The experimental measurements were performed in an initial pressure range of 3.5–7.1 MPa. It was found that both of ILs with imidazolium-based cation increase the initial methane hydrate formation rate while the IL with ammonium-based cation leads to a decrease in the initial methane hydrate formation rate. It was also interpreted from the results that all of the three studied ILs decrease methane hydrate stability at atmospheric pressure and increase methane hydrate storage capacity. Finally, both of ILs with imidazolium-based cations were found to have higher impacts on decreasing hydrate stability at atmospheric pressure and increasing the methane hydrate storage capacity than the applied IL with ammonium-based cation.     

Advanced Bioresponsive Multitasking Hydrogels in the New Era of Biomedicine

Advanced forms of hydrogels have many inherently desirable properties and can be designed with different structures and functions. In particular, bioresponsive multifunctional hydrogels can carry out sophisticated biological functions. These include in situ single-cell approaches, capturing, analysis, and release of living cells, biomimetics of cell, tissue, and tumor-specific niches. They can allow in vivo cell manipulation and act as novel drug delivery systems, allowing diagnostic, therapeutic, vaccination, and immunotherapy methods. In the present review of multitasking hydrogels, new approaches and devices classified into point-of-care testing (POCT), microarrays, single-cell/rare cell approaches, artificial membranes, biomimetic modeling systems, nanodoctors, and microneedle patches are summarized. The potentials and application of each format are critically discussed, and some limitations are highlighted. Finally, how hydrogels can enable an “all-in-one platform” to play a key role in cancer therapy, regenerative medicine, and the treatment of inflammatory, degenerative, genetic, and metabolic diseases is being looked forward to.     

A Novel Refined Track Initiation Algorithm for Group Targets Based on Group Model

Traditional refined track initiation methods for group targets have mistakes or loss of tracks when tracking irregular motions, for the reason that they rely on a stable relative position of group members. To solve the problem, a group dynamic model was introduced for proposing a new initiation algorithm and its whole framework. We made a self-adaptive improvement of the group separation on various group radii. After the pre-association of these groups, a state equation derived from the model was used for predictions of group members. Then a relational matrix was defined for refined data associations. Finally tracks were validated by logic-based method. Particular scenarios and Monte Carlo simulations showed that, compared with algorithms based on relative position, this algorithm has better performance on the adaptability to changes of a group structure and the correctness of initiation.     

On the mechanics of functional asymmetry in bipedal walking

This paper uses two symmetrical models, the passive compass-gait biped and a five-link 3-D biped, to computationally investigate the cause and function of gait asymmetry. We show that for a range of slope angles during passive 2-D walking and mass distributions during controlled 3-D walking, these models have asymmetric walking patterns between the left and right legs due to the phenomenon of spontaneous symmetry-breaking. In both cases a stable asymmetric family of gaits emerges from a symmetric family of gaits as the total energy increases (e.g., fast speeds). The ground reaction forces of each leg reflect different roles, roughly corresponding to support, propulsion, and motion control as proposed by the hypothesis of functional asymmetry in able-bodied human walking. These results suggest that body mechanics, independent of neurophysiological mechanisms such as leg dominance, may contribute to able-bodied gait asymmetry.     

High IIP3 and Low-Noise CMOS Mixer Using Non-linear Feedback Technique

A third-order intermodulation cancelation technique using a non-linear feedback is proposed to design a low-power low-distortion mixer in a 65 nm standard CMOS technology. The IM3 cancelation is achieved by estimating distorting error at a non-linear feedback element and subtracting it from the input. The linearization technique is utilized in the input trans-conductance of the mixer. The circuit functionality is analyzed using Volterra series. The covering frequency range of the mixer is 800 MHz to 5 GHz. The technique increases the input-referred third-order intercept point (IIP3) and input 1 dB compression point to +16.4 dBm and −1.87 dBm, respectively. It obtains a gain of 9 dB and an input-referred noise of 1.84 nV/?{}/\sqrt{}Hz while consumes 8.75 mA from 1.2 V supply. The layout of the mixer occupies 0.315 mm × 0.296 mm of silicon area.     

Organic field-effect transistor circuits using atomic layer deposited gate dielectrics patterned by reverse stamping

We report on a reverse stamping method to produce via-holes in circuits comprising acene-based top-gate organic field-effect transistors (OFETs) having a CYTOP/Al₂O₃ (by atomic layer deposition) bilayer gate dielectric. This method relies on the weak adhesive force that exists between a small molecule acene film and a polymer to enable easy delamination of the bilayer gate dielectric by using a PDMS stamp. We demonstrate the effectiveness of this method by fabricating simple circuits using top-gate triisopropylsilylethynyl pentacene (TIPS-pentacene)/poly (triarylamine) (PTAA) OFETs.     

The Role of Elastic and Plastic Anisotropy of Snin Recrystallization and Damage Evolution DuringThermal Cycling in SAC305 Solder Joints

Because failures in lead-free solder joints occur at locations other than the most highly shear-strained regions, reliability prediction is challenging. To gain physical understanding of this phenomenon, physically based understanding of how elastic and plastic deformation anisotropy affect microstructural evolution during thermomechanical cycling is necessary. Upon solidification, SAC305 (Sn-3.0Ag-0.5Cu) solder joints are usually single or tricrystals. The evolution of microstructures and properties is characterized statistically using optical and orientation imaging microscopy. In situ synchrotron x-ray measurements during thermal cycling are used to examine how crystal orientation and thermal cycling history change strain history. Extensive characterization of a low-stress plastic ball grid array (PBGA) package design at different stages of cycling history is compared with preliminary experiments using higher-stress package designs. With time and thermal history, microstructural evolution occurs mostly from continuous recrystallization and particle coarsening that is unique to each joint, because of the specific interaction between local thermal and displacement boundary conditions and the strong anisotropic elastic, plastic, expansion, and diffusional properties of Sn crystals. The rate of development of recrystallized microstructures is a strong function of strain and aging. Cracks form at recrystallized (random) boundaries, and then percolate through recrystallized regions. Complications arising from electromigration and corrosion are also considered.     

Virtual Machine Consolidation in Cloud Computing Systems: Challenges and Future Trends

Wireless Personal Communications - Cloud Computing Systems (CCSs) provides a computing capability through the Internet. It enables organizations or individuals to have a computing power without...