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31.
32.
Harukazu Yoshino Zeynel Bayindir Joydeep Roy Ben Shaw Heon-ick Ha Andrei Lebed Michael J. Naughton 《Journal of Low Temperature Physics》2006,142(3-4):323-326
A new TTP donor, Me-DH-TTP (2-methyl-5-(1,3-dithiolan-2-yliden)-1,3,4,6-tetrathiapentalene), was designed to realize a system
with large on-site Coulomb repulsion as compared with the previously known bis-fused type TTP donors. Probably as a consequence,
(Me-DH-TTP)2AsF6 exhibits semiconducting behavior from room temperature to liquid helium temperature. By increasing pressure, metallic behavior
appears below 300 K, and with distinct metal-insulator (M-I) transition up to 2.2 GPa. This M-I transition suddenly disappears
beyond 2.5 GPa, and metallic state is stabilized down to 2.6 K. We discuss the possibility of quantum critical point around
2.4 GPa. 相似文献
33.
Petru Andrei 《Journal of Computational Electronics》2006,5(4):315-318
A calibration method is developed for the electron effective mass in the Density-Gradient model. This method uses the two- and three-dimensional effective-mass Schrödinger equations, which are solved for bounded quantum systems. The electron effective mass is computed by fitting the electron concentration computed by using the Density-Gradient model to the electron concentration computed by using the Schrödinger equation. Results for strongly confined silicon system with (100), (110), and (111) crystallographic orientations are presented. It is shown that the effective mass varies with the shape and dimensions of the quantum box. In device simulations, one should use the value of m_n that corresponds to the right shape and dimensions of the confinement region in the device. 相似文献
34.
Creating and Rendering Convolution Surfaces 总被引:6,自引:0,他引:6
Implicit surfaces obtained by convolution of multi-dimensional primitives with some potential function, are a generalisation of popular implicit surface models: blobs, metaballs and soft objects. These models differ in their choice of potential function but agree upon the use of underlying modelling primitives, namely, points. In this paper a method is described for modelling and rendering implicit surfaces built upon an expanded set of skeletal primitives: points, line segments, polygons, arcs and planes. An analytical solution to the convolution is described. This solution offers a more accurate and robust representation of the resultant implicit surface than previous methods. An algorithm for ray-tracing the surfaces formed through convolution of any combination of these primitives is also outlined. 相似文献
35.
About the Collatz conjecture 总被引:1,自引:0,他引:1
This paper refers to the Collatz conjecture. The origin and the formalization of the Collatz problem are presented in the
first section, named “Introduction”. In the second section, entitled “Properties of the Collatz function”, we treat mainly
the bijectivity of the Collatz function. Using the obtained results, we construct a (set of) binary tree(s) which “simulate(s)”–
in a way that will be specified – the computations of the values of the Collatz function. In the third section, we give an
“efficient” algorithm for computing the number of iterations (recursive calls) of the Collatz function. A comparison between
our algorithm and the standard one is also presented, the first being at least 2.25 “faster” (3.00 in medium). Finally, we
describe a class of natural numbers for which the conjecture is true.
Received 28 April 1997 / 10 June 1997 相似文献
36.
This paper presents a comparison of methods for industrial on-line sensor calibration monitoring for redundant sensors. Principal component analysis (PCA) and independent component analysis (ICA) techniques are developed and compared using both simulated data and data sets from an operating nuclear power plant. The performance is dependent on the types of noise sources; however, under most conditions ICA outperforms PCA, based on the bias and variance of their respective parameter estimates. A case study is included to demonstrate the usefulness of both techniques for the early detection of sensor drift. 相似文献
37.
Efficient Total Chemical Synthesis of 13C=18O Isotopomers of Human Insulin for Isotope‐Edited FTIR
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Dr. Balamurugan Dhayalan Dr. Ann Fitzpatrick Dr. Kalyaneswar Mandal Dr. Jonathan Whittaker Prof. Dr. Michael A. Weiss Prof. Dr. Andrei Tokmakoff Prof. Dr. Stephen B. H. Kent 《Chembiochem : a European journal of chemical biology》2016,17(5):415-420
Isotope‐edited two‐dimensional Fourier transform infrared spectroscopy (2 D FTIR) can potentially provide a unique probe of protein structure and dynamics. However, general methods for the site‐specific incorporation of stable 13C=18O labels into the polypeptide backbone of the protein molecule have not yet been established. Here we describe, as a prototype for the incorporation of specific arrays of isotope labels, the total chemical synthesis—via a key ester insulin intermediate—of 97 % enriched [(1‐13C=18O)PheB24] human insulin: stable‐isotope labeled at a single backbone amide carbonyl. The amino acid sequence as well as the positions of the disulfide bonds and the correctly folded structure were unambiguously confirmed by the X‐ray crystal structure of the synthetic protein molecule. In vitro assays of the isotope labeled [(1‐13C=18O)PheB24] human insulin showed that it had full insulin receptor binding activity. Linear and 2 D IR spectra revealed a distinct red‐shifted amide I carbonyl band peak at 1595 cm?1 resulting from the (1‐13C=18O)PheB24 backbone label. This work illustrates the utility of chemical synthesis to enable the application of advanced physical methods for the elucidation of the molecular basis of protein function. 相似文献
38.
We study local structure of time-optimal controls and trajectories for a 3D control-affine system with a 2D control parameter with values in the disk. In particular, we give sufficient conditions, in terms of Lie bracket relations, for optimal controls to be smooth or to have only isolated jump discontinuities. 相似文献
39.
Kate Ryan Sabine M. Neumayer Harsha Vardhan R. Maraka Nicolae-Viorel Buchete Andrei L. Kholkin James H. Rice 《Science and Technology of Advanced Materials》2013,14(1):172-179
AbstractNanocomposites of diphenylalanine (FF) and carbon based materials provide an opportunity to overcome drawbacks associated with using FF micro- and nanostructures in nanobiotechnology applications, in particular their poor structural stability in liquid solutions. In this study, FF/graphene oxide (GO) composites were found to self-assemble into layered micro- and nanostructures, which exhibited improved thermal and aqueous stability. Dependent on the FF/GO ratio, the solubility of these structures was reduced to 35.65% after 30 min as compared to 92.4% for pure FF samples. Such functional nanocomposites may extend the use of FF structures to e.g. biosensing, electrochemical, electromechanical or electronic applications. 相似文献
40.
Andrei Victor Sandu Alexandra Ciomaga Gheorghe Nemtoi Costica Bejinariu Ion Sandu 《Microscopy research and technique》2012,75(12):1711-1716
This article presents the SEM‐EDX and microFTIR study and the corrosion behavior of new five types of phosphated coatings obtained by coprecipitation in acid aqueous medium of some metal cations, pursuing the influence of the addition of other cations and a moderator of precipitation, on the uniformity and compactness of the layers and on the morphology of dendritic structure of Zn(II) and Fe(II) phosphates. Microsc. Res. Tech. 2012. © 2012 Wiley Periodicals, Inc. 相似文献