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排序方式: 共有952条查询结果,搜索用时 15 毫秒
11.
Rajib Bandyopadhyay Mahuya Bandyopadhyay Yoshihiro Kubota Yoshihiro Sugi 《Journal of Porous Materials》2002,9(2):83-95
AlPO4-5 and AlPO4-11 were synthesized by dry-gel conversion (DGC) method. Steam-assisted conversion (SAC) and vapor-phase transport (VPT) techniques were applied for this purpose. The synthesis was successful in presence of a certain minimum amount of external bulk water, without which the crystallization failed. Crystallization by VPT method was slower than corresponding SAC and HTS method. SAPO analogs of the samples, SAPO-5 and SAPO-11 were also synthesized by DGC method. Samples made by DGC methods had higher yield than the conventional hydrothermal synthesis (HTS); otherwise the samples showed similar characteristics as that made by HTS. XRD, SEM and N2-adsorption results showed high crystallinity and purity of the samples made by DGC, and 27Al MAS NMR spectra indicated the tetrahedral framework nature of Al. SAPO-5 and SAPO-11 were tested for their catalytic activity in isopropylation of biphenyl, and in terms of conversion and selectivity, SAPO-5 was found to be suitable for this application. 相似文献
12.
Bandyopadhyay Soma Thakur S. S. Mandal J. K. 《Innovations in Systems and Software Engineering》2021,17(1):45-52
Innovations in Systems and Software Engineering - Recommender system is a computer-based intelligent technique which facilitates the customers to fulfill their purchase requirements. In addition to... 相似文献
13.
Jayita Bandyopadhyay Caroline Mekoa Dimakatso Makwakwa Sifiso Skosana Suprakas Sinha Ray 《Polymer Engineering and Science》2021,61(4):1195-1208
The development of a reactively processed polypropylene nanocomposite (PPNC) with consequential improvements in the heat deflection temperature (HDT), Vicat softening temperature (VST), and crystallization peak temperature (Tc) is reported herein. Neat PP without nanoclay was also reactively processed to elucidate the effects of fillers on the improvement in physical properties. The results show a considerable improvement in the HDT of PPNC (77.9 °C) compared to those of neat PP (62.6 °C) and reactively processed branched PP (BPP; 69.2 °C). Moreover, the Tc of PP in PPNC improved by ~14% compared to that of neat PP. Various models of nonisothermal crystallization kinetics were employed to elucidate the nucleation and crystal growth mechanisms, and to correlate them with the observed HDT improvement in PPNC. Thermal transitions investigated by modulated differential scanning calorimetry explained the changes observed in the VSTs of all the samples. To the best of our knowledge, this is the first report on a significant improvement in HDT along with a marked increase in Tc. Such simultaneous improvements in HDT, VST, and Tc are highly desirable for applications involving the use of PP-based materials in rigid packaging. 相似文献
14.
Weichang Xue Amit Bandyopadhyay Susmita Bose Chuanxian Ding K.M.C. Cheung 《Surface & coatings technology》2007,201(8):4685-4693
The use of strontium-containing hydroxyapatite (Sr-HA) as a biomaterial has been reported recently. In vitro and in vivo studies have shown that Sr-HA promotes osteoblast response and stimulates new bone formation. In order to extend its usage to major load-bearing applications, such as artificial hip replacement, it has been proposed that the material could be used in the form of a coating on implant surfaces. This paper reports a preliminary study of biocompatibility of plasma sprayed Sr-HA coatings on a metallic substrate. Coatings of Sr-HA containing 10 mol% Sr2+ was produced on titanium alloy substrates. The coating exhibited good bonding with the substrate. The bioactivity of Sr-HA coating was evaluated in vitro by immersion in simulated body fluid (SBF). After immersion in SBF, Sr-HA coating exhibited great ability to induce apatite precipitation on its surface. The possible effects of cell-materials interactions of Sr-HA coating were examined by culturing osteoprecursor cells (OPC1) on coating surfaces. The effect of Sr-HA was also compared to a hydroxyapatite (HA) coating, which is widely used in orthopedics and dentistry. The results indicated that Sr-HA coating had good biocompatibility with human osteoblasts. OPC1 cells survived and proliferated well on the surface of coating. Sr-HA coating promoted OPC1 cells attachment, and more local contacts were produced on the surface. The presence of Sr stimulated OPC1 cell differentiation and ALP expression. No deleterious effect on ECM formation and mineralization was found with Sr-HA coating. The results indicated that Sr-HA coating had good mechanical properties and bioactivity in vitro. 相似文献
15.
The flame spraying process, which is a common industrial thermal spraying application, has been analyzed by means of three-dimensional
computational fluid dynamics (CFD) simulations. The process used at the Volvo Aero Corporation for the coating of fan and
compressor housings has been modeled. The process uses the Metco 6P torch (Metco, Westbury, NY), which ejects a mixture of
acetylene and oxygen at high speed through a ring of 16 orifices to form the flame. A stream of argon gas flowing through
an orifice in the center of the ring carries a powder of nickel-covered bentonite through the flame to the spray substrate.
The torch is cooled by a flow of air through an outer ring of 9 orifices. The simulation emulated reality closely by including
the individual inlets for fuel, cooling air, and injected particles. The gas combustion was simulated as a turbulent, multicomponent
chemically reacting flow. The standard, two-equation k-ε turbulence model was used. The chemical reaction rates appeared as
source terms in the species transport equations. They were computed from the contributions of the Arrhenius rate expressions
and the Magnussen and Hjertager eddy dissipation model. The first simulations included several intermediate chemical substances
whose predicted concentration agreed favorably with measurements. Later, more simplified simulations incorporated only the
global chemical reaction involving the initial and the final products, with corrections to the thermal properties being made
to account for the missing intermediaries. The gas velocity and temperature fields predicted by the later simulations compared
satisfactorily to those predicted by the earlier, more elaborate, ones. Therefore, the final simulations, which incorporated
injected particles, were conducted employing the simplified model with only the global reaction. An in-house finite difference
code was developed to calculate particle properties. Allowance was made for elliptical shapes, phase changes, and internal
heat transfer with regard to the composite material. The particle velocities and temperatures predicted by the final simulations
compared fairly well with experimental results obtained with the optical DPV2000 system. 相似文献
16.
Bahni Ray Dipankar Bandyopadhyay Ashutosh Sharma Sang Woo Joo Shizhi Qian Gautam Biswas 《Microfluidics and nanofluidics》2013,15(1):19-33
Spatiotemporal deformations of the free charged surface of a thin electrolyte film undergoing a coupled electrokinetic flow composed of an electroosmotic flow (EOF) on a charged solid substrate and an electrophoretic flow (EPF) at its free surface are explored through linear stability analysis and the long-wave nonlinear simulations. The nonlinear evolution equation for the deforming surface is derived by considering both the Maxwell’s stresses and the hydrodynamic stresses. The electric potential across the film is obtained from the Poisson–Boltzmann equation under the Debye–Hückel approximation. The simulations show that at the charged electrolyte–air interface, the applied electric field generates an EPF similar to that of a large charged particle. The EOF near the solid–electrolyte interface and the EPF at the electrolyte–air interface are in the same (or opposite) directions when the zeta potentials at the two interfaces are of the opposite (or same) signs. The linear and nonlinear analyses of the evolution equation predict the presence of travelling waves, which is strongly modulated by the applied electric field and the magnitude/sign of the interface zeta potentials. The time and length scales of the unstable modes reduce as the sign of zeta potential at the two interfaces is varied from being opposite to same and also with the increasing applied electric field. The increased destabilization is caused by a reverse EPF near the free surface when the interfaces bear the same sign of zeta potentials. Flow reversal by EPF at the free surface occurs at smaller zeta potential of the free surface when the film is thicker because of less influence of the EOF arising at the solid–electrolyte boundary. The amplitude of the surface waves is found to be smaller when the unstable waves travel at a faster speed. The films can undergo pseudo-dewetting when the free surface is almost stationary under the combined influences of EPF and EOF. The free surface instability of the coupled EOF and EPF has some interesting implications in the development of micro/nano fluidic devices involving a free surface. 相似文献
17.
Choudhury Alokeparna Samanta Sourav Pratihar Sanjoy Bandyopadhyay Oishila 《Applied Intelligence》2022,52(7):7339-7372
Applied Intelligence - Microscopic Image segmentation has a crucial role in detecting and diagnosing numerous critical diseases like Alzheimer’s disease, Kidney disease, Cancer, many... 相似文献
18.
Mayuresh Patole Santanu Bandyopadhyay Dominic C. Y. Foo Raymond R. Tan 《Clean Technologies and Environmental Policy》2017,19(7):1967-1975
Pinch analysis was initially developed as a methodology for optimizing energy efficiency in process plants. Applications of pinch analysis applications are based on common principles of using stream quantity and quality to determine optimal system targets. This initial targeting step identifies the pinch point, which then allows complex problems to be decomposed for the subsequent design of an optimal network using insights drawn from the targeting stage. One important class of pinch analysis problems is energy planning with footprint constraints, which began with the development of carbon emissions pinch analysis; in such problems, energy sources and demands are characterized by carbon footprint as the quality index. This methodology has been extended by using alternative quality indexes that measure different sustainability dimensions, such as water footprint, land footprint, emergy transformity, inoperability risk, energy return on investment and human fatalities. Pinch analysis variants still have the limitation of being able to use one quality index at a time, while previous attempts to develop pinch analysis methods using multiple indices have only been partially successful for special cases. In this work, a multiple-index pinch analysis method is developed by using an aggregate quality index, based on a weighted linear function of different quality indexes normally used in energy planning. The weights used to compute the aggregate index are determined via the analytic hierarchy process. A case study for Indian power sector is solved to illustrate how this approach allows multiple sustainability dimensions to be accounted for in energy planning. 相似文献
19.
Single‐Molecule Magnets: Giant Hysteresis of Single‐Molecule Magnets Adsorbed on a Nonmagnetic Insulator (Adv. Mater. 26/2016)
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20.
J. B. Mandal B. Bandyopadhyay B. Ghosh H. Rajagopal A. Sequeira J. V. Yakhmi 《Journal of Superconductivity》1996,9(2):253-257
Rietveld analysis of powder neutron diffraction pattern recorded on Sr-based 1201-phase superconductor (T
c
=53 K), (Hg0.7Cr0.3)Sr2CuO4+ shows that the oxygen atoms at O(3) site are disordered atx=y=0.3712. This fourfold split site has a total combined occupancy of 80% and is the only occupied site in the (Hg, Cr)O plane. 相似文献