Effect of nanopore geometry on ion current rectification

We present the results of systematic studies of ion current rectification performed on artificial asymmetric nanopores with different geometries and dimensions. The nanopores are fabricated by the ion track etching method using surfactant-doped alkaline solutions. By varying the alkali concentration in the etchant and the etching time, control over the pore profile and dimensions is achieved. The pore geometry is characterized in detail using field-emission scanning electron microscopy. The dependence of the ion current rectification ratio on the pore length, tip diameter, and the degree of pore taper is analysed. The experimental data are compared to the calculations based on the Poisson-Nernst-Planck equations. A strong effect of the tip geometry on the diode-like behaviour is confirmed.     

Towards integrative computational materials engineering of steel components

This article outlines on-going activities at the RWTH Aachen University aiming at a standardized, modular, extendable and open simulation platform for materials processing. This platform on the one hand facilitates the information exchange between different simulation tools and thus strongly reduces the effort to design/re-design production processes. On the other hand, tracking of simulation results along the entire production chain provides new insights into mechanisms, which cannot be explained on the basis of individual simulations. Respective simulation chains provide e.g. the basis for the determination of materials and component properties, like e.g. distortions, for an improved product quality, for more efficient and more reliable production processes and many further aspects. After a short introduction to the platform concept, actual examples for different test case scenarios will be presented and discussed.     

Uranium exerts acute toxicity by binding to pyrroloquinoline quinone cofactor

Uranium as an environmental contaminant has been shown to be toxic to eukaryotes and prokaryotes; however, no specific mechanisms of uranium toxicity have been proposed so far. Here a combination of in vivo, in vitro, and in silico studies are presented describing direct inhibition of pyrroloquinoline quinone (PQQ)-dependent growth and metabolism by uranyl cations. Electrospray-ionization mass spectroscopy, UV-vis optical spectroscopy, competitive Ca(2+)/uranyl binding studies, relevant crystal structures, and molecular modeling unequivocally indicate the preferred binding of uranyl simultaneously to the carboxyl oxygen, pyridine nitrogen, and quinone oxygen of the PQQ molecule. The observed toxicity patterns are consistent with the biotic ligand model of acute metal toxicity. In addition to the environmental implications, this work represents the first proposed molecular mechanism of uranium toxicity in bacteria, and has relevance for uranium toxicity in many living systems.     

Asymmetric track membranes: Relationship between nanopore geometry and ionic conductivity

The revealing of the “diodelike” properties of electrolyte-filled asymmetric nanopores in track membranes has given significant impetus to a detailed study of the properties of “track” nanocapillaries. Studying the behavior of electrolyte solutions in nanovolumes of a given geometry is very important for many applications, such as nanofluid technology, the resistive pulse method for detecting colloidal particles and molecules, modeling of biological membranes, etc. An attempt to find a quantitative relationship between the geometric shape of asymmetric nanopores and asymmetry in electrical conductivity has been made in this paper. The method of chemical etching in the presence of a surfactant was used for the formation of nanopores with different profiles. The pore structure was studied by electron microscopy. It has been found that the rectification ratio increases with the membrane thickness and depends strongly on the curvature of the pore profile in the selective layer. The maximum of the rectification has been observed in a 0.05–0.1M KCl. Simulation of the ionic conductivity of asymmetric nanopores by the Poisson-Nernst-Planck equation qualitatively explains the observed behavior. The effect of the asymmetry of electrical conductivity is well expressed even in cases when the pore radius in the selective layer is substantially greater than the Debye length. The modification of the pore surface by grafting of aminopropyltriethoxysilane results in the sign inversion of electric charge and a sharp change in the current-voltage characteristics of the membranes.     

Purities prediction in a manufacturing froth flotation plant: the deep learning techniques

Neural Computing and Applications - Accurate and timely investigation to concentrate grade and recovery is a premise of realizing automation control in a froth flotation process. This study seeks...     

Pointcuts, advice, refinements, and collaborations: similarities, differences, and synergies

Aspect-oriented programming (AOP) is a novel programming paradigm that aims at modularizing complex software. It embraces several mechanisms including (1) pointcuts and advice as well as (2) refinements and collaborations. Though all these mechanisms deal with crosscutting concerns, i.e., a special class of design and implementation problems that challenge traditional programming paradigms, they do so in different ways. In this article we explore their relationship and their impact on modularity, which is an important prerequisite for reliable and maintainable software. Our exploration helps researchers and practitioners to understand their differences and exposes which mechanism is best used for which problem.     

Nonlinear absorption of thin Al2O3 films at 193 nm

Absorption of thin Al(2)O(3) films was measured at 193 nm with an ArF-laser calorimeter. In addition to the expected high linear absorption coefficient, we found, for the first time to our knowledge, that two-photon absorption and transient color-center formation are nonnegligible loss channels in thin films at 193 nm. The nonlinear absorption coefficient is of the order of several times 10(-4) cm/W.     

Nonlinear Decentralized Feedback Linearizing Controller Design for Islanded DC Microgrids

This paper aims to design decentralized controllers for different components in islanded DC microgrids. The major components in the DC microgrid as considered in this paper include a fuel cell, solar photovoltaic (PV) unit, and battery energy storage system (BESS) along with critical and non-critical loads. The main control objective is to maintain the power balance within the DC microgrid through the regulation of the common DC-bus voltage. The controllers are designed based on the dynamical models of the fuel cell, solar PV unit, and BESS. The feedback linearization technique is employed to obtain the control laws, which simplifies the original dynamical models and decouples different components in the form of several subsystems. In this way, the feedback linearization technique allows different components in DC microgrids to achieve the desired control objectives by using only the local information (i.e., in a decentralized manner). The performance of the proposed decentralized controllers for different components is evaluated on a test DC microgrid under different operating conditions. Simulation results demonstrate that the proposed control scheme performs in a much better way as compared to an existing proportional integral controller.