Selective Supramolecular Fullerene-Porphyrin Interactions and Switching in Surface-Confined C(60)-Ce(TPP)(2) Dyads

The control of organic molecules, supramolecular complexes and donor-acceptor systems at interfaces is a key issue in the development of novel hybrid architectures for regulation of charge-carrier transport pathways in nanoelectronics or organic photovoltaics. However, at present little is known regarding the intricate features of stacked molecular nanostructures stabilized by noncovalent interactions. Here we explore at the single molecule level the geometry and electronic properties of model donor-acceptor dyads stabilized by van der Waals interactions on a single crystal Ag(111) support. Our combined scanning tunneling microscopy/spectroscopy (STM/STS) and first-principles computational modeling study reveals site-selective positioning of C(60) molecules on Ce(TPP)(2) porphyrin double-decker arrays with the fullerene centered on the π-system of the top bowl-shaped tetrapyrrole macrocycle. Three specific orientations of the C(60) cage in the van der Waals complex are identified that can be reversibly switched by STM manipulation protocols. Each configuration presents a distinct conductivity, which accounts for a tristable molecular switch and the tunability of the intradyad coupling. In addition, STS data evidence electronic decoupling of the hovering C(60) units from the metal substrate, a prerequisite for photophysical applications.     

Vitamins in brewing: effects of post‐fermentation treatments and exposure and maturation on the thiamine and riboflavin vitamer content of beer

Post‐fermentation processes and maturation are important steps in beer production as they help to shape the organoleptic properties and stabilize the final product. Brewers can use a variety of processing aids (e.g. isinglass, PVPP, etc.) and processes (e.g. pasteurization, bottle conditioning, etc.) to achieve a desired final product with a desirable shelf life; however, these processes can have detrimental effects on the vitamin content of the beer. This research found that heat treatments have a marked influence on the decrease in the thiamine diphosphate vitamer, while PVPP and silica treatments have a greater influence on the decrease in riboflavin vitamers. Refrigeration, filtration or centrifugation have no, or only very limited, influence on thiamine or riboflavin vitamers, while application of isinglass, bentonite, tannic acid and SO₂ causes a decrease in both thiamine and riboflavin vitamers. Storage of beer at refrigerated temperatures appears to provide protection against significant degradation of both thiamine and riboflavin vitamers; however, storage of filtered beer at elevated temperatures shows a decrease in thiamine diphosphate and riboflavin. Storage of bottle‐conditioned beer at elevated temperatures shows a marked decrease in yeast viability, accompanied by a decrease in thiamine diphosphate and free riboflavin, and a marked increase in free thiamine. These findings provide an insight into the reason why there is a significant variation in the vitamer content of beers, even within a single beer style. Copyright © 2016 The Institute of Brewing & Distilling     

Kinoform apodization

Abstract

A new apodization principle is introduced, according to which the amplitude function is realized as a varying diffraction efficiency of the multistep phase diffractive element. A proper modification of the phase-step heights within the apodization region allows one to redirect light from the main diffraction order into its conjugate, simultaneously avoiding the presence of light in the two nearest neighbouring orders. The analysis is confirmed by the simulation results.     

Efficient Recovery of Combustibles From Coking Coal Fines

The processing of three Indian coking coal fines with feed ash values of 25.12% (S1), 22.97% (S2), and 30.38% (S3) was studied. Substantial improvement in the overall recovery of combustible could be obtained by splitting sample S1, exhibiting good washability but poor release behavior, into a coarser and a finer fraction and treating them by gravity and Jameson cell flotation, respectively. Sample S2 had over 70% of the material below 100 µm and had excellent release characteristics. The Jameson cell flotation indeed resulted in very high recovery of combustibles at the desired target ash values and split processing was not required for this sample. The floatability and washability characteristics of sample S3 indicated that gravity-based methods might improve combustible recovery in terms of theoretical yield at the desired product ash values. A combination of spiral concentration of the coarser fraction and froth flotation of the finer fraction using a Jameson cell showed some improvement in the combustible recovery of this sample. It was established in this study that if the floatability is poor or moderate, then split processing improves coal cleaning performance. Flotation alone may be recommended only when samples exhibit excellent floatability.     

Energy absorption and damage propagation in 2D triaxially braided carbon fiber composites: effects of in situ matrix properties

Results from an experimental program to investigate the propagation of damage and energy dissipation in 2D triaxially braided carbon fiber textile composites (2DTBC) under static conditions are reported. A methodology is presented in which classical concepts from fracture mechanics are generalized to address damage growth in an orthotropic and heterogeneous structural material. Along with results from the experimental program, a novel numerical technique that employs ideas from cohesive zone modeling, and implemented through the use of finite-element analysis, is also presented. The inputs that are required for the discrete cohesive zone model (DCZM) are identified. Compact tension specimen fracture tests and double notched tension tests were carried out to measure the fracture energy (G _Ic), and the maximum cohesive strength (σ _c), of the 2DTBC. The DCZM modeling strategy was independently verified by conducting single edge notched three-point bend tests using a modified three-point bend test fixture. The experimental and numerical analyses were carried out for two different types of 2DTBC made from the same textile architecture but infused with two different resin systems to validate the proposed methodology.     

Simplified Large‐Area Manufacturing of Organic Electrochemical Transistors Combining Printing and a Self‐Aligning Laser Ablation Step

A hybrid manufacturing approach for organic electrochemical transistors (OECTs) on flexible substrates is reported. The technology is based on conventional and digital printing (screen and inkjet printing), laser processing, and post‐press technologies. A careful selection of the conductive, dielectric, and semiconductor materials with respect to their optical properties enables a self‐aligning pattern formation which results in a significant reduction of the usual registration problems during manufacturing. For the prototype OECTs, based on this technology, on/off ratios up to 600 and switching times of 100 milliseconds at gate voltages in the range of 1 V were obtained.     

Antioxidant, lipolytic and proteolytic enzyme activities in pork meat from different genotypes

Oxidative processes in meat lead to meat quality deterioration. Meat has endogenous antioxidants and prooxidants, but information on factors influencing the activity of antioxidant enzymes in meat is limited. Lipolytic and proteolytic enzymes are involved in important aspects of meat quality. Our objective was to find differences between five different genotypes on the activity of antioxidant, lipolytic and proteolytic enzymes in meat. Forty Psoas major muscles of females of five different pig genotypes were used, Pietrain, Landrace, Large-White, lberian, and lberian×Duroc. Pre slaughter conditions were similar for all the genotypes. After slaughter, muscles were vacuum packed and frozen at -20?°C until required. Differences between genotypes were found for the activity of catalase and SOD, while GSH-Px showed no differences. The highest differences between breeds were found for the lberian breed where catalase had the highest activity. Catalase activity also showed differences between the white pigs, with large values for LR and lower activities in P. There were no differences in neutral lipase activities between the different genotypes while acid lipase and phospholipase showed significant differences. The activities of cathepsin B and H were significantly lower for Iberian pigs compared with other breeds except LR, while the ratio of cathepsin B+L/cathepsin B was higher in Iberian. The differences between genotypes found in enzyme activities suggest some genetic effects on the antioxidant, lipolytic and proteolitytic activity of pork meat.     

Oxidative DNA damage correlates with carotid artery atherosclerosis in hemodialysis patients

Oxidative stress is accepted as a nonclassical cardiovascular risk factor in chronic renal failure patients. The aim of this study was to evaluate the relation between oxidative DNA damage (8‐hydroxy‐2′‐deoxyguanosine/deoxyguanosine [8‐OHdG/dG] ratio), oxidative stress biomarkers, antioxidant enzymes, and carotid artery intima‐media thickness (CIMT) in hemodialysis (HD) patients. Forty chronic HD patients without known atherosclerotic disease and 48 age‐ and sex‐matched healthy individuals were included in the study. Plasma malondialdehyde (MDA) levels and 8‐OHdG/dG ratio were determined as oxidative stress markers. Superoxide dismutase (SOD) and glutathione peroxidase (GPx) activities were measured as antioxidants. CIMT was assessed by carotid artery ultrasonography. 8‐OHdG/dG ratios and MDA levels were higher; SOD and GPx activities were lower in HD patients compared to controls. HD patients had significantly higher CIMT compared to controls (0.61 ± 0.08 vs. 0.42 ± 0.05, p < 0.001). There was a significant positive correlation between CIMT and 8‐OHdG/dG ratio (r = 0.57, p < 0.01) and MDA levels (r = 0.41, p < 0.01), while there was a significant negative correlation between CIMT and SOD (r = ?0.47, p < 0.01) and GPx levels (r = ?0.62, p < 0.01). It is firstly demonstrated that CIMT is positively correlated with oxidative DNA damage in HD patients without known atherosclerotic disease.     

Effect of selection for growth rate on biochemical, quality and texture characteristics of meat from rabbits

Biochemical characteristics, including myosin heavy chain I (MHC-I) percentage, isocitrate dehydrogenase and aldolase activities, meat quality traits and instrumental texture properties of rabbits selected for different growth rates were studied. The animals of the control (C) group (7th generation; n=60) were raised in parallel with those of selection (S) group (21st generation; n=60). Carcass weights (1230.1 ± 19.8 and 1348.3 ± 20.1 g, for C and S, respectively) and perirenal and scapular fat content differed significantly (P<0.01) between the two groups. Water holding capacity was expressed as the percentage of pressure released water and was significantly different (P<0.05) between groups C and S (33.29% and 35.57%). MHC-I percentage and aldolase activity also differed significantly (P<0.05) between groups, group C showing higher oxidative traits than group S (MHC-I: 12.5% and 9.8%; aldolase: 597.11 and 636.83 UI/g muscle). Texture properties from the Warner-Bratzler test showed higher (P<0.001) shear firmness for loin in the S group (1.69 kg/s cm²) than in the C group (1.34 kg/s cm²). In addition, the texture profile analysis indicated that chewiness, gumminess and hardness were also higher in the S group (P<0.01). In conclusion, the results confirmed a positive effect of the selection on productive traits and a negative effect on instrumental texture properties and on the water holding capacity of the meat.     

Chemical and physical properties of short rotation tree species

The European Union’s growth strategy (Europe 2020) requires reductions in greenhouse gas (GHG) emissions and increases in both renewable energy sources and energy efficiency. Short rotation forestry (SRF) has achieved greater awareness due to these targets. Short rotations (1–12 years), rapid growth and the ability to coppice are typical for SRF. Salix, Populus, Alnus and Betula have smaller GHG emissions of biomass production than annual agricultural plant species, since management and harvesting are not needed every year. Physicochemical properties of these species must be known when their utilisation is planned and optimised. Seven tree species were studied: three willows (Salix myrsinifolia, Salix schwerinii and Klara), one aspen (Populus tremula), one alder (Alnus glutinosa) and two birches (Betula pendula and Betula pubescens). One stem wood (S) sample and one stem wood and bark (SB) sample of each tree were investigated. Furthermore, seven surface soil samples and four incineration ash samples (two S. myrsinifolia and two S. schwerinii) were also studied. Heating values, densities, ash contents as well as carbon, hydrogen and nitrogen contents of all short rotation biomass samples were usually quite typical for the corresponding tree species. Additional observations included the accumulation of cadmium in willow and aspen samples, small chloride content values, and higher ash- and element contents in SB samples than in the corresponding S samples. Nutrient content of ash was usually higher in the S sample, contradictory to biomass samples, and finally the cadmium content of the ash samples was very high.