Tuning the gas separation performance of fluorinated and sulfonated PEEK membranes by incorporation of zeolite 4A

Mixed matrix membranes (MMMs) containing fluorinated‐sulfonated poly(ether ether ketone) (F‐SPEEK) and zeolite 4A filler, were prepared by solution casting. F‐SPEEK with a fixed degree of sulfonation (40%) was used for membrane synthesis. The SEM pictures showed good interfacial adhesion between filler particles and polymer, which was also confirmed by the increase in glass transition temperature of MMMs with increase in filler particles. Pure and mixed gas permeation experiments were carried out to investigate the potential of this membrane material. The results revealed that addition of zeolite 4A fillers enhanced both permeability and selectivity owing to the intrinsic nature of polymer and modified membrane morphology due to filler. The highest permeability obtained for CO₂ at 30% filler loading was 49.2 Barrer, while highest selectivities obtained for CO₂/CH₄ and CO₂/N₂ were 55 and 58 compared to 47 and 51 for the unfilled polymer, respectively. Intrinsic CO₂ solubility of F‐SPEEK was observed to be decreased from 10.7 to 1.9 (10^?2) cm³ (STP)/cm³ cmHg with the addition of Zeolite 4A. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45952.     

New control allocation algorithms in fixed point framework for overactuated systems with actuator saturation

In this paper, two control allocation algorithms have been proposed for overactuated systems. The algorithms are developed by formulating constrained control allocation problem into an equivalent fixed point framework. The first algorithm follows sequential solving method while the other one involves a zero finding technique by the Newton method. In order to consider limiting constraints, the saturation function has been taken into account that leads to a nonsmooth zero finding problem and the proposed method guarantees superlinear convergence. The second algorithm is easy to implement and faster than the algorithm developed based on the sequential solving technique. To demonstrate the effectiveness of the proposed algorithms, a detail simulation study has been carried out, in which one example considers both the actuator rate and amplitude constraints.     

Satellite-sensed tropospheric NO2 patterns and anomalies over Indus,Ganges, Brahmaputra,and Meghna river basins

This study presents trends, seasonality, hot spots, and anomalies of tropospheric NO₂ pollution over four basins of Indus, Ganges, Brahmaputra, and Meghna rivers in South Asia using observations from Ozone Monitoring Instrument (OMI) on-board Aura satellite during 2004–2015. For the first time this area, a highly populated and industrialized region with significant emissions of air pollutants, has been discussed collectively. OMI data reveal significantly elevated NO₂ column over the region averaged at (1.9 ± 0.1) × 10¹⁵ molecules cm^–2 (average ± standard deviation of observations) with an increase of 21.12% (slope (0.036 ± 0.004) × 10¹⁵ molecules cm^–2, y-intercept (1.705 ± 0.024) × 10¹⁵ molecules cm^–2, R² = 0.92) during the study period. According to MACCity anthropogenic emissions inventory transportation, energy, residential, and industrial sectors are the major contributors of high NO_x emissions. NO₂ pollution hot spots are identified and their tendencies have been discussed. The hot spots of megacities Lahore (Pakistan) and Dhaka (Bangladesh) are found to be strengthening and expanding over the time. Eastern Ganges Basin shows the highest NO₂ concentration at (2.63 ± 0.22) × 10¹⁵ molecules cm^–2 and growth rate of 3.22% per year mainly linked to power generation, fossil fuel extraction, mining activities, and biomass burning. NO₂ over Indus–Ganges–Brahmaputra–Meghna Basin exhibits seasonal maximum in winter and minimum in monsoon. The highest seasonality is found over Meghna Basin due to large variations in meteorological conditions and large-scale crop-residue burning. Some anomalies in NO₂ levels have been detected linked to intense crop-residue burning events. During these anomalies, exceptionally high levels of daily NO₂ reaching up to 76.23 × 10¹⁵ molecules cm^–2 have been observed over some places in Indus and Meghna Basins.     

Information hiding in edges: A high capacity information hiding technique using hybrid edge detection

The multimedia security is becoming more and more important as the data being exchanged on the Internet is increasing exponentially. Though cryptography is one of the methods which is used to secure the data during transit, but the camouflaged appearance of the scrambled data alerts the adversary about some critical information being shared. In such a scenario, steganography has been used as an alternate solution to secure the secret information. In this paper a color image steganographic algorithm based on hybrid edge detection is proposed. The color image is partitioned into constituent Red (R), Green (G) and Blue (B) planes. Hybrid edge detection is used for finding the edge and non-edge pixels of Green and Blue planes of cover image. The Green and Blue planes are used for hiding the data while Red plane holds the pixel status (whether edge or non-edge) of these planes. The RC4 encryption algorithm is used to encrypt secret message before embedding it in the cover image to enhance security of the secret data. A fragile watermark/logo (whose size is less than 1% of total secret data) has been embedded, besides secret data in the cover image, to facilitate content authentication and early tamper detection. At the receiver, firstly logo is extracted. If it is same as one embedded at transmitter, indicating that secret data has not been altered during transit, secret data is extracted. Otherwise (if extracted logo is not same as used at input) the receiver does not waste critical time to extract compromised data but sends an automatic retransmission request. Experimental investigations reveal that the proposed scheme is capable of providing high quality of stego-images for a fairly high pay load. A comparison of the proposed technique with some state of art schemes substantiates the above arguments.     

Structural,optical, and photocatalytic investigation of nickel oxide@graphene oxide nanocomposite thin films by RF magnetron sputtering

Despite the recent advancement in graphene oxide (GO) as a host material in energy and environmental sectors, its composite thin films with metal oxides such as nickel oxide (NiO) and its optical, structural, chemical state, and photocatalytic activities have been poorly explored. Herein, we have reported the GO/NiO thin films preparation by a combination of chemical and physical deposition techniques (i.e. spin coating followed by DC/RF sputtering). The as-prepared composites thin films were characterised using Raman spectroscopy, X-ray diffraction/photoelectron spectroscopy scanning electron microscopy, and atomic force microscopy. The surface topography confirmed the uniform deposition of NiO over thin films of GO. The XPS results showed the formation of NiC along with the partial reduction in GO into graphene with their existing four constituents, i.e. NiO, NiC, GO, in the thin film composites. The classical plasmon, Wemple and Didomenico model, was first time applied for GO/NiO to compute energy loss functions, and dispersion energy parameters. The theoretical calculated values for the deposited GO/NiO thin films were found to be in very close agreement to the standard classical plasmon values. The change in spin orbital movement of Ni is considered due to the interaction between its nanoparticles and basal planes of GO. Thin films applied for the photodegradation of recalcitrant organic pollutant 2-chlorophenol (2-CP) revealed the dependence of photocatalytic efficiency on particle size and also on the interaction of GO with NiO rather than the ratio of NiO and GO in the films.     

Healable Transparent Electronic Devices

With the advent of the digital era, healable electronic devices are being developed to alleviate the propagation of breakdown in electronics due to the mechanical damage caused by bending, accidental cutting or scratching. Meanwhile, flexible transparent electronics, exhibiting high transmittance and robust flexibility, are drawing enormous research efforts due to their potential applications in various integrated wearable electronics. However, the breakdown of flexible transparent electronics seriously limits their reliability and lifetime. Therefore, transparent healable electronics are desired to tackle these problems, yet most of the healable electronics are not transparent nowadays. The combination of high performance, healability, and transparency into electronics is often mutually exclusive. Herein, after a brief introduction of self‐healing materials, healable electronics, and flexible transparent electronics, the recent progress in the healable electronic devices without transparency is reviewed in detail. Then, healable transparent electronic devices with high transparency, robust portability, and reliable flexibility are summarized. They are drawing great attention owing to their potential application in optical devices as well as smart wearable and integrated optoelectronic devices. Following that, the critical challenges and prospects are highlighted for the development of healable transparent electronic devices.     

Ambipolar leakage suppression in electron–hole bilayer TFET: investigation and analysis

In this paper, we propose and simulate two new structures of electron–hole bilayer tunnel field-effect transistors (EHBTFET). The proposed devices are n-heterogate with \(\hbox {M}_{1}\) as overlap gate, \(\hbox {M}_{2}\) as underlap gate and employs a high-k dielectric pocket in the drain underlap. Proposed structure 1 employs symmetric underlaps (Lgs = Lgd = Lu). The leakage analysis of this structure shows that the lateral ambipolar leakage between channel and drain is reduced by approximately three orders, the OFF-state leakage is reduced by one order, and the \(I_{\mathrm{ON}}/I_{\mathrm{OFF}}\) ratio is increased by more than one order at \(V_\mathrm{{GS}}=V_{\mathrm{DS}} =1.0\) V as compared to the conventional Si EHBTFET. The performance is improved further by employing asymmetric underlaps (\(\hbox {Lgs}\ne \hbox {Lgd}\)) with double dielectric pockets at source and drain, called as proposed structure 2. The pocket dimensions have been optimized, and an average subthreshold swing of 17.7 mV/dec (25.5% improved) over five decades of current is achieved with an ON current of \(0.23~\upmu \hbox {A}/\upmu \hbox {m}\) (11% improved) in proposed structure 2 in comparison with the conventional EHBTFET. Further, the parasitic leakage paths between overlap/underlap interfaces are blocked and the OFF-state leakage is reduced by more than two orders. A high \(I_{\mathrm{ON}}/I_{\mathrm{OFF}}\,\hbox {ratio}~>10^{9}\) (two orders higher) is achieved at \(V_{\mathrm{DS}} =V_{\mathrm{GS}} =1.0~\hbox {V}\) in the proposed structure 2 in comparison with the conventional one.     

Participatory design in interactive media design education for the solution of unfamiliar design problems: a case study on a disabling environment and an emerging technology

This paper investigates the effectiveness of participatory design study in rendering the students' capability of producing innovative design solutions to problems with uncertainties with which the students have no prior experience. At the project, the students were given a case to work on augmented reality technology with which they had no previous experience and design a tactical interface for sailing boats, a field they had no competence in. While the students were asked to develop proposals for this design problem with which they were inexperienced, a two-stage study was conducted to enable them to produce ideas on the topic. This paper discusses the impacts of such a participatory method in terms of design education. At the end of our study, it was observed that the students were positively influenced by the process in which they worked collaboratively with an expert user group.     

Nanocomposites of transition metals tungstate for potential applications in magnetic and microwave devices

Ni_2-xCo_x(WO₄)₂ and Ni_2-xMn_x(WO₄)₂ (x?=?0.0, 0.50, 1.0, 1.50 and 2.0) nanocomposites have been synthesized by facile hydrothermal method. The synthesized samples have been characterized by powder XRD and Scanning Electron Microscopy to analyze the structure and morphology. Structural analysis has revealed the single phase formation with wolframite monoclinic system for NiWO₄ samples. The calculated crystallite size ranges from 6 to 40 nm for the nanocomposites. Magnetic and dielectric parameters have also been studied. Magnetic susceptibility measurements of each sample have been carried out at room temperature (312 K) by using Sherwood magnetometer. A decrease in susceptibility values has been observed by increase in the concentration of manganese or cobalt in nickel tungstate leading to antiferromagnetic behavior. Dielectric measurements in the frequency range of 6 kHz to 1 MHz have been calculated. The analysis showed that dielectric parameters decrease with increase in frequency.     

Method for Restoring Consistency in Probabilistic Knowledge Bases

ABSTRACT

Ensuring consistency of knowledge systems is always one of the essential requirements because, without it, most of these systems become useless. Because of the importance, many studies have involved the restoration of consistency in knowledge systems. However, these approaches are only implemented on knowledge systems that are represented by logic or probabilistic logic, thus when we apply them to probabilistic knowledge systems, there are many inadequacies. To overcome these drawbacks, in this paper, we put forward a new model for restoring the consistency of a probabilistic knowledge base by focusing on changing the probabilities in this knowledge base via several inconsistency measures. To this end, a set of inconsistency measures is presented and a family of consistency restoring operators for probabilistic knowledge bases is introduced. Next, an axiomatic model consists of a set of axioms is built to characterize the desirable properties of the consistency restoring operators. Finally, the properties of each consistency restoring operator in the introduced family are investigated and discussed.