Synthesis and structural characterization of an alternating double aquo-bridged and single cyano-bridged polymeric barium–iron complex: {[Ba2(phen)4(H2O)6Fe(CN)6]·Cl·2(phen)·3H2O}n

A new alternating double aquo-bridged and single cyano-bridged polymeric complex {[Ba₂(phen)₄(H₂O)₆Fe(CN)₆]·Cl·2(phen)·3H₂O}_n (1) (phen = 1,10-phenanthroline) has been synthesized and structurally characterized. In the crystal structure the two centrosymmetric [Ba₂(phen)₄(H₂O)₆] units are bridged through two trans CN groups of [Fe(CN)₆]³⁻ ion, which results in the formation of a zig-zag polymeric chain. In each [Ba₂(phen)₄(H₂O)₆] unit, the two Ba centers are joined by double aquo bridges. Both the Ba atoms are 9-coordinated with distorted mono-capped square antiprismatic geometry. An elaborate hydrogen bonding system holds the parallel polymeric chains together.     

Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines

The increasing industrialization and motorization of the world has led to a steep rise for the demand of petroleum-based fuels. Petroleum-based fuels are obtained from limited reserves. These finite reserves are highly concentrated in certain regions of the world. Therefore, those countries not having these resources are facing energy/foreign exchange crisis, mainly due to the import of crude petroleum. Hence, it is necessary to look for alternative fuels which can be produced from resources available locally within the country such as alcohol, biodiesel, vegetable oils etc. This paper reviews the production, characterization and current statuses of vegetable oil and biodiesel as well as the experimental research work carried out in various countries. This paper touches upon well-to-wheel greenhouse gas emissions, well-to-wheel efficiencies, fuel versatility, infrastructure, availability, economics, engine performance and emissions, effect on wear, lubricating oil etc.     

Exploring Pharmacological Functions of Alternatively Spliced Variants of the Mu Opioid Receptor Gene,Oprm1, via Gene-Targeted Animal Models

The mu opioid receptor has a distinct place in the opioid receptor family, since it mediates the actions of most opioids used clinically (e.g., morphine and fentanyl), as well as drugs of abuse (e.g., heroin). The single-copy mu opioid receptor gene, OPRM1, goes through extensive alternative pre-mRNA splicing to generate numerous splice variants that are conserved from rodents to humans. These OPRM1 splice variants can be classified into three structurally distinct types: (1) full-length 7 transmembrane (TM) carboxyl (C)-terminal variants; (2) truncated 6TM variants; and (3) single TM variants. Distinct pharmacological functions of these splice variants have been demonstrated by both in vitro and in vivo studies, particularly by using several unique gene-targeted mouse models. These studies provide new insights into our understanding of the complex actions of mu opioids with regard to OPRM1 alternative splicing. This review provides an overview of the studies that used these gene-targeted mouse models for exploring the functional importance of Oprm1 splice variants.     

Novel Detection Scheme for LSAS Using Power Allocation in Multi User Scenario with LTE-A and MMB Channels

Massive MIMO (also known as the “Large-Scale Antenna System”) enables a significant reduction of latency on the air interface with the use of a large excess of service-antennas over active terminals and time division duplex operation. For large-scale MIMO, several technical issues need to be addressed (e.g., pilot pattern design and low-antenna power transmission design) and theoretically addressed (e.g., channel estimation and power allocation schemes). In this paper, we analyze the ergodic spectral efficiency upper bound of a large-scale MIMO, and the key technologies including channel uplink detection. We also present new approaches for detection and power allocation. Assuming arbitrary antenna correlation and user distributions, we derive approximations of achievable rates with linear detection techniques, namely zero forcing, maximum ratio combining, minimum mean squared error (MMSE) and eigen-value decomposition power allocation (EVD-PA). While the approximations are tight in the large system limit with an infinitely large number of antennas and user terminals, they also match our simulations for realistic system dimensions. We further show that a simple EVD-PA detection scheme can achieve the same performance as MMSE with one order of magnitude fewer antennas in both uncorrelated and correlated fading channels. Our simulation results show that our proposal is a better detection scheme than the conventional scheme for LSAS. Also, we used two channel environment channels for further analysis of our algorithm: the Long Term Evolution Advanced channel and the Millimeter wave Mobile Broadband channel.

     

Initial rapid wetting in metallic systems

The initial rapid wetting of a solid surface by a liquid phase is an important step in many industrial processes. Liquid-phase sintering of powder metallurgical steels is one such industrial process, where metallic powders of micrometer size are used. Investigating the dynamic wetting of a high-temperature metallic drop of micrometer size experimentally is very challenging. Here, a phase-field-based numerical model is first implemented and verified by accurately capturing the initial dynamic wetting of millimeter-sized metal drops and then the model is extended to predict the dynamic wetting of a micrometer-sized metal drop. We found, in accordance with recent observations, that contact line friction is required for accurate simulation of dynamic wetting. Our results predict the wetting time for a micrometer-sized metal drop and also indicate that the dynamic wetting patterns at the micro- and millimeter length scales are qualitatively similar. We also found that the wetting process is much faster for a micrometer-sized metal drop compared to a millimeter-sized metal drop.     

Receive antenna selection for MIMO systems over correlated fading channels

In this letter, we propose a novel receive antenna selection algorithm based on cross entropy optimization to maximize the capacity over spatially correlated channels in multiple-input multiple-output (MIMO) wireless systems. The performance of the proposed algorithm is investigated and compared with the existing schemes. Simulation results show that our low complexity algorithm can achieve near-optimal results that converge to within 99% of the optimal results obtained by exhaustive search. In addition, the proposed algorithm achieves near-optimal results irrespective of the mutual relationship between the number of transmit and receive antennas, the statistical properties of the channel and the operating signal-to-noise ratio.     

Stress Corrosion Cracking and Oil Leakage in a Control Oil Piping System

This article describes the results of an investigation concerning with the failure of a pipe which was carrying oil from the control oil unit to the steam turbine control valves servomotor. The failure was in the form of a crack, propagating horizontally along the pipe. The crack initiated on the outside of the pipe. The cause of the failure was investigated by conducting visual examination, detailed macro and microstructural examinations and determining the composition of material from the failed pipe. The composition of the pipe material was analyzed by atomic absorption spectrometer. The failure of the oil pipe was attributed to stress corrosion cracking. The pipe material is A312 TP 304L. Recommendation to minimize such failures includes coating the pipe to prevent contact with chloride from the surrounding marine environment.     

Fabrication of innovative charkha for pashmina spinning and its impact assessment

Pashmina, a finest natural animal fiber is utilized for preparation of world famous Kashmiri pashmina shawls by traditional practices. Hand spinning is one of the important processing step, wherein fibers are converted into a fine yarn on a traditional spinning wheel (yander). The task is usually carried out by women folk. It is a laborious process resulting in a lot of physical stress affecting the efficiency of artisans. An innovative charkha has been fabricated to reduce the physical stress and its effect on the spinning efficiency and remuneration of artisans over traditional one was evaluated. The study revealed that innovative charkha was efficient in terms of time consumed for spinning by 73.50% over traditional one besides decreasing physical drudgery. In terms of income, there was an increase of 146% over traditional one for same period of time without deteriorating the quality of yarn.     

Consequence-based structural design approach for black swan events

The metaphor of black swan refers to unpredictable events like 9/11, the Indian Ocean tsunami, or the Oklahoma City Federal Building bombing, that cause catastrophic consequences for structural system safety. The likelihood of occurrence for such unforeseen events cannot be estimated from the observed data or prognosticated by experts. The absence of event and likelihood information renders futile the application of usual risk-based methods for design. Therefore, a shift from the probabilistic approach to consequence-based structural design is necessary for coping with the unexpected demands. This is accomplished through the conceptual development of a system capacity oriented design approach, where structural members are designed for variable reliabilities based upon their contribution to causing adverse system consequences. Information about general structural integrity encoded in the stiffness matrix is applied, using member consequence factors ranging from 0 to 1, for determining a member’s contribution towards system response. The structural system is designed using member consequence factors as additional partial factors on the resistance side of the design equations. The consequence-based scheme does not need a triggering hazard event (or its likelihood) and is an apt structural design approach for black swan events.