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排序方式: 共有2508条查询结果,搜索用时 31 毫秒
41.
Gabino A. Carriedo Francisco J. García Alonso Alejandro Presa Soto 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(2):399-406
The chiral phosphazene copolymers {[NP(O2C12H8)]0.9[NP(O2C20H12)]0.1} (1) and {[NP(O2C12H8)]0.9[NP(O2C20H10Br2)]0.1}
n
(2) [(O2C12H8) = 2,2′-dioxy-1,1′-biphenyl; (O2C20H12) = R-2,2′-dioxy-1,1′-binaphthyl and (O2C20H10Br2) = R-6,6′-dibromo-2,2′-dioxy-1,1′-binaphthyl] were prepared by sequential substitution from [NPCl2]
n
and the corresponding dihydroxy-biphenyl or binaphthyl reagents in the presence of Cs2CO3 and K2CO3. The reaction of (2) with tBuLi in THF, followed by addition of PPh2Cl and a treatment with SiHCl3/PPh3 to eliminate any oxidized OC6H4P(O)Ph2 groups, gave the phosphine containing copolymer {[NP(O2C12H8)]0.9[NP(O2C20H10[PPh2]2)]0.1}
n
(3), that was used as a chiral ligand to support [Ru(p-cymene)Cl] complexes. The resulting catalyst was active for hydrogen
transfer from isopropyl alcohol to acetophenone but the placement of the Ru centers in the 6,6′-positions of the binaphthoxyphosphazene
units induced no enantioselectivity.
Dedicated to Professor Christopher Allen. 相似文献
42.
43.
In this study, we explored a new ion exchange material synthesized by radical polymerization of styrene and 2‐acrylamido‐2‐methyl‐1‐propane sulfonic acid by using 2,2′‐azo‐isobutyronitrile (1 mol %) and divinylbenzene (0.5 mol %) as initiator and crosslinking reagents, respectively. The resin was obtained from a large excess (90%) of styrene in the feed. The yield was 72.3%. The resin was completely insoluble in water and characterized by elemental analysis, FTIR spectroscopy, scanning electron microscopy, and thermal analysis. The metal ion retention capability was investigated for Ag(I), Hg(II), Cd(II), Zn(II), Pb(II), and Cr(III). The effect of pH, time, and resin/metal ion mol ratio on the metal ion retention was studied. Selectivity of the resins from a mixture of metal ions and the maximum retention capacity at optimum pH were also determined. The recovery of the resin by using 1 and 4 M HClO4 and HNO3 demonstrated that it is possible to recover the resin above 80%. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1230–1235, 2003 相似文献
44.
Beatriz Miranda Eva Díaz Salvador Ordez Fernando V. Díez 《Catalysis communications》2006,7(12):945-949
The performance of 0.5% Ru/Al2O3 for the deep oxidation of trichloroethene (1000–2500 ppmV, WHSV = 55 h−1) in air was studied in this work. Experiments were carried out both at dry and wet (20,000 ppmV of H2O) conditions. Catalytic performance was studied in terms of activity and selectivity for the different reaction products (CO2, HCl, Cl2, C2Cl4, CCl4 and CHCl3). Both the activity and the selectivity for total combustion are higher than other catalysts suggested in the literature for this process (especially Pd and Pt).The main organic by-products are CCl4 and CHCl3, whereas in all the other catalysts tested in the literature, tetrachloroethene is the main organic by-product. This fact suggests that the mechanism of the combustion reaction, involving a double-bond scission, is essentially specific for this catalyst.Kinetic data was fit to a pseudo-first order kinetic expression, providing fairly good fit. 相似文献
45.
L.?Alonso M.?J.?Fraga M.?JuárezEmail author P.?Carmona 《Journal of the American Oil Chemists' Society》2002,79(1):1-6
A Fourier transform infrared spectroscopic procedure was used to analyze 34 edible fats (22 shortenings and 12 vegetable margarines)
as neat fats (IRNF) to determine their total trans fatty acid (TFA) content. The sloping baseline was corrected with a reference spectrum based on a nonprocessed olive oil.
The calibration was done using seven partially hydrogenated fats with an individual TFA content previously determined by the
combination of gas chromatography (GC) with argentation thin-layer chromatography. Taking into account the different absorptivities
of various trans isomers, different correction factors were calculated using the calibration standards (0.83 and 1.71 for single trans bonds in both diethylene and triethylene and for trans, trans-diethylene fatty acids, respectively) and applied to calculate the total TFA of samples. Moreover, the samples were converted
to their methyl esters and reanalyzed following the same procedure (IRFAME). Differences in TFA content of fats were not found when a t-test was used to compare the results obtained by IRNF vs. either IRFAME or GC, suggesting that IR of neat fats could be used, thus avoiding the need to prepare sample solutions in organic solvents
and to prepare fatty acid methyl esters. The mean TFA content (determined by IRNF) of a representative group of Spanish shortenings (22 samples) that varied widely in terms of fat sources, processes, and
purposes (bakery, sandwiches, ice cream, coatings, chocolate coverings) was 6.55±11.40%, although more than 54% contained
<3% of TFA. Fatty acid composition of shortenings by direct GC using a 100-m polar cyanopolysiloxane capillary column indicated
that the mean trans-18∶2 isomer content was 0.58%, ranging from 0.9 to 3.4%. Small amounts of trans-18∶3 isomers (<0.3%) were observed in 18 of the 22 shortenings studied; the maximal value was <2%. The mean value of the
fraction saturated+TFA of shortenings was high (59.95±12.73%), including two values higher than 83%. 相似文献
46.
H. Nava C. Ornelas A. Aguilar G. Berhault S. Fuentes G. Alonso 《Catalysis Letters》2003,86(4):257-265
Unsupported cobalt-molybdenum sulfide catalysts were prepared from bimetallic CoMo alkyl precursors by in situ activation during the hydrodesulfurization (HDS) of dibenzothiophene (DBT). The bimetallic CoMo precursors were prepared by reaction of tetraalkylammonium thiomolybdate salts, (R4N)2MoS4 (where R = H, methyl, butyl, pentyl or hexyl), with CoCl2 in water at a Co/Mo molar ratio of 0.3. These catalysts exhibit a Swiss-cheese-like morphology, high surface areas (from 52 up to 320 m2/g), high content of carbon (C/Mo = 2.2-3.3) and type IV adsorption-desorption isotherms of nitrogen. The in situ activation of these tetraalkylammonium thiobimetalate precursors leads to a mesoporous structure with pore size ranging from 2 to 4.5 nm. X-ray diffraction showed that the structure of unsupported cobalt-molybdenum sulfide catalysts corresponds to a poorly crystalline structure characteristic of 2H-MoS2 with low-stacked layers. The nature of the alkyl group strongly affects both the surface area and the HDS activity. The catalytic activity is strongly enhanced when using carbon-containing precursors; the CoMo catalysts prepared by in situ activation of Co/[N(C4H9)4]2MoS4 presents the highest HDS activity. The highest surface area of the catalysts was observed for the CoMo catalyst formed from Co/[N(C6H13)4N]2MoS4. 相似文献
47.
Đurović Gordana Van Neerbos Francine A. C. Bossaert Sofie Herrera-Malaver Beatriz Steensels Jan Arnó Judit Wäckers Felix Sobhy Islam S. Verstrepen Kevin J. Jacquemyn Hans Lievens Bart 《Journal of chemical ecology》2021,47(8-9):788-798
Journal of Chemical Ecology - There is increasing evidence that microorganisms, particularly fungi and bacteria, emit volatile compounds that mediate the foraging behaviour of insects and therefore... 相似文献
48.
D.R. Salgado F.J. Alonso 《International Journal of Machine Tools and Manufacture》2007,47(14):2140-2152
This paper presents a tool condition monitoring system (TCMS) for on-line tool wear monitoring in turning. The proposed TCMS was developed taking into account the necessary trade-off between cost and performance to be applicable in practice, in addition to a high success rate. The monitoring signals were the feed motor current and the sound signal. The former was used to estimate the feed cutting force using the least squares version of support vector machines (LS-SVM). Singular spectrum analysis (SSA) was used to extract information correlated with tool wear from the sound signal. The estimated feed cutting force and the SSA decomposition of the sound signal alone with the cutting conditions constitute the input data to the TCMS. Again LS-SVM was used to estimate tool condition and its reliability for on-line implementation was validated by experiments using AISI 1040 steel. The results showed that the proposed TCMS is fast and reliable for tool condition monitoring. 相似文献
49.
Warm deep drawing of wrought magnesium alloy sheets produced by semi-solid roll strip-casting process 总被引:1,自引:0,他引:1
H. Watari N. Koga K. Davey T. Haga M.T. Alonso Ragado 《International Journal of Machine Tools and Manufacture》2006,46(11):1233-1237
This paper is concerned with the development of a continuous strip-casting technology to facilitate the manufacture of magnesium sheet alloys economically whilst maintaining high quality. Established in the paper is warm formability of cast magnesium alloy sheets after being hot rolled by semi-solid roll strip-casting process. It has been found that magnesium sheet with 2.0–4.0 mm thickness could be produced at a speed of 25 m/min. Hot rolling and annealing temperatures during hot rolling were also changed to examine which condition would be appropriate for producing wrought magnesium alloys with good formability. Microstructures of the crystals of the manufactured wrought magnesium alloys were observed. It has been found that a limiting drawing ratio of 2.7 was possible in a warm deep-drawing test of the cast magnesium alloy sheets after being hot rolled. 相似文献
50.