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排序方式: 共有852条查询结果,搜索用时 930 毫秒
761.
Very shortly following the discovery of single-walled carbon nanotubes laser-based methods emerged as reliable ways to produce moderate quantities with very consistent composition and properties. They have also proven to be good platforms for the systematic investigation of various synthesis parameters in the hope of better understanding the growth process. Several variations exist with differences such as laser wavelength, number of lasers, background temperature, and target composition. A number of common elements have emerged for the production of both high quality and high yields of SWNT, such as the effectiveness of bimetal catalysts like CoNi and NiY, and the need for high process temperatures and controlling the rate of cooling. Combined with the growing amount of in situ diagnostic and computational modelling data we are slowly making progress towards understanding the growth process. This article will present an overview of recent advancements in laser-based synthesis methods and what information can be extracted about the growth process. 相似文献
762.
Wavefront sensors are usually based on measuring the wavefront derivatives. The most commonly used approach to quantitatively reconstruct the wavefront uses discrete Fourier transform, which leads to artifacts when phase objects are located at the image borders. We propose here a simple approach to avoid these artifacts based on the duplication and antisymmetrization of the derivatives data, in the derivative direction, before integration. This approach completely erases the border effects by creating continuity and differentiability at the edge of the image. We finally compare this corrected approach to the literature on model images and quantitative phase images of biological microscopic samples, and discuss the effects of the artifacts on the particular application of dry mass measurements. 相似文献
763.
Vibrations are detrimental to the performance of modern adaptive optics (AO) systems. In this paper, we describe new methods tested to mitigate the vibrations encountered in some of the instruments of the Gemini South telescope. By implementing a spectral analysis of the slope measurements from several wavefront sensors and an imager, we can determine the frequencies and magnitude of these vibrations. We found a persistent vibration at 55 Hz with others occurring occasionally at 14 and 100 Hz. Two types of AO controllers were designed and implemented, Kalman and H∞, in the multiconjugate AO tip-tilt loop. The first results show a similar performance for these advanced controllers and a clear improvement in vibration rejection and overall performance over the classical integrator scheme. It is shown that the reduction in the standard deviation of the residual slopes (as measured by wavefront sensors) is highly dependent on turbulence, wind speed, and vibration conditions, ranging--in terms of slopes RMS value--from an almost negligible reduction for high speed wind to a factor of 5 for a combination of low wind and strong vibrations. 相似文献
764.
A. Monfardini A. Benoit A. Bideaud N. Boudou M. Calvo P. Camus C. Hoffmann F.-X. Désert S. Leclercq M. Roesch K. Schuster P. Ade S. Doyle P. Mauskopf E. Pascale C. Tucker A. Bourrion J. Macias-Perez C. Vescovi A. Barishev J. Baselmans L. Ferrari S. J. C. Yates A. Cruciani P. De Bernardis S. Masi C. Giordano B. Marghesin H. G. Leduc L. Swenson 《Journal of Low Temperature Physics》2012,167(5-6):834-839
We are developing an instrument based on Kinetic Inductance Detectors (KID) known as the Néel IRAM KID Array (NIKA). Leveraging the experience gained from the first generation NIKA in 2009, an improved, dual-band (150?GHz and 240?GHz) instrument has been designed and tested at the Institut of RadioAstronomie Millimetrique (IRAM) 30-meter telescope in October 2010. The performances, in terms of sensitivity on-the-sky at 150?GHz, are already comparable to existing state-of-the-art bolometer-based instruments. NIKA represents thus the first real proof that KID are a viable technology for ground-based Astronomy. We will describe the instrument, the most recent results and the future plans for building a large resident mm-wave camera. 相似文献
765.
Mehmet Dasdemir Benoit Maze Nagendra Anantharamaiah Behnam Pourdeyhimi 《Journal of Materials Science》2012,47(16):5955-5969
In this study, we investigated the effect of polymer type, composition, and interface on the structural and mechanical properties of core–sheath type bicomponent nonwoven fibers. These fibers were produced using poly(ethylene terephthalate)/polyethylene (PET/PE), polyamide 6/polyethylene (PA6/PE), polyamide 6/polypropylene (PA6/PP), polypropylene/polyethylene (PP/PE) polymer configurations at varying compositions. The crystallinity, crystalline structure, and thermal behavior of each component in bicomponent fibers were studied and compared with their homocomponent counterparts. We found that the fiber structure of the core component was enhanced in PET/PE, PA6/PE, and PA6/PP whereas that of the sheath component was degraded in all polymer combinations compared to corresponding single component fibers. The degrees of these changes were also shown to be composition dependent. These results were attributed to the mutual interaction between two components and its effect on the thermal and stress histories experienced by polymers during bicomponent fiber spinning. For the interface study, the polymer–polymer compatibility and the interfacial adhesion for the laminates of corresponding polymeric films were determined. It was shown that PP/PE was the most compatible polymer pairing with the highest interfacial adhesion value. On the other hand, PET/PE was found to be the most incompatible polymer pairings followed by PA6/PP and PA6/PE. Accordingly, the tensile strength values of the bicomponent fibers deviated from the theoretically estimated values depending on core–sheath compatibility. Thus, while PP/PE yielded a higher tensile strength value than estimated, other polymer combinations showed lower values in accordance with their degree of incompatibility and interfacial adhesion. These results unveiled the direct relation between interface and tensile response of the bicomponent fiber. 相似文献
766.
Kathy Van Butsele Sébastien Cajot Sandra Van Vlierberghe Peter Dubruel Catherine Passirani Jean‐Pierre Benoit Robert Jérôme Christine Jérôme 《Advanced functional materials》2009,19(9):1416-1425
In the present work, a method is proposed to assemble pH‐responsive, flower‐like micelles that can expose a targeting unit at their periphery upon a decrease in pH. The micelles are composed of a novel biotinylated triblock copolymer of poly(εε‐caprolactone)‐block‐poly(ethylene oxide)‐block‐poly(2‐vinylpyridine) (PCL‐b‐PEO‐b‐P2VP) and the non‐biotinylated analogue. The block copolymers are synthesized by sequential anionic and ring‐opening polymerization. The pH‐dependent micellization behaviour in aqueous solution of the triblock copolymers developed is studied using dynamic light scattering, zeta potential, transmission electron microscopy (TEM), and fluorimetric measurements. The shielding of the biotin at neutral pH and their availability at the micelle surface upon protonation is established by TEM and surface plasmon resonance with avidin and streptavidin‐coated gold surfaces. The preliminary stealthy behavior of these pH‐responsive micelles is examined using the complement activation (CH50) test. 相似文献
767.
This study quantifies historic and current mercury contamination in New Haven Harbor (New Haven, Connecticut, USA) through the analysis of sediment cores. The mercury concentration measured in surface sediment ranged from 320 to 1640 μg kg− 1 with an average of 530 μg kg− 1. The harbor is relatively small in area (6.6 km2) but displays a large range in concentrations, illustrating the important methodological issue that a large number of samples may be necessary to capture the variability in even a small area. Depth profiles of mercury reflect sedimentation over a range of 20 to 200 years and indicate a complex history of contamination. Mercury depth profiles were compared with lead, copper, cadmium, and silver concentrations and the metals generally covary. This trend indicates that the sources of mercury and heavy metals are linked and that regionally specific sources dominate the historic input of metals rather than large-scale atmospheric deposition patterns. Results also show there are large differences in absolute concentrations of metals among sites in the harbor. Differences in the abundance of Fe-rich, fine-grained sediment likely control the level of metals in various parts of the harbor. Proximity to current sources and the long, diverse industrial history of the harbor also influence the distribution pattern. All of the cores can be modeled as mixing between pre-industrial sediments and either one or two pollution endmembers. This study demonstrates the importance of riverine sources in the mass balance of mercury delivered to coastal areas and of watershed management to preserve coastal ecosystems. 相似文献
768.
Maya Boutros Julien Starck Benoit de Tymowski Jean-Michel Trichard Patrick Da Costa 《Topics in Catalysis》2009,52(13-20):1786-1790
Alumina-supported indium and gallium oxide catalysts were prepared by excess solvent impregnation, characterized and tested for the reduction of NO x by ethanol in Lean Burn Conditions. The promotion of alumina by “poor” metals showed an interesting ability to selectively reduce NO x to N2. 相似文献
769.
Ana M. Díez-Pascual Jingwen Guan Benoit Simard Marián A. Gómez-Fatou 《Composites Part A》2012,43(6):1007-1015
The mechanical properties, electrical and thermal conductivity of single-walled carbon nanotube (SWCNT) buckypaper (BP) embedded in poly(ether ether ketone) (PEEK) or poly(phenylene sulphide) (PPS) matrices were investigated. Dynamic mechanical analysis demonstrated a significant increase in the storage modulus and glass transition temperature of the polymers, indicating strong SWCNT–matrix interfacial adhesion. The composites showed improved stiffness and strength, as revealed by tensile and flexural tests, while their ductility and toughness moderately decreased. Exceptional enhancements in the electrical and thermal conductivity of PPS and PEEK were found. Their Young’s moduli and thermal conductivities were compared with the predictions of theoretical models. This investigation indicates that SWCNT-BPs possess great potential to improve the performance of thermoplastics and satisfy a wide variety of demands in multi-disciplinary technological applications. 相似文献
770.
M McKerral MS Roy J Benoit F Leporé P Lachapelle 《Canadian Metallurgical Quarterly》1997,37(22):3193-3199
With the use of the simple motor reaction time (RT), we examined the contribution of the hemiretinas to the timing of the pattern reversal visual evoked potential (PVEP). RTs were obtained to the reversal of a progressively dimmer check falling either on the central, nasal, temporal, superior or inferior retina. Results were correlated with the peak time of the P1 wave evoked to the reversal of the entire checkerboard stimulus to the same luminance conditions as that used to generate the RT measurements. Our results clearly indicate that the time taken to trigger a manual response depends not only on the luminance of the stimulus, but also on where it falls on the retina. Comparing the above data with the peak time of the PVEP obtained to the reversal of the entire screen indicates that at brighter luminance the peak time of the P1 wave correlates with that measured from the most central retina, while at dimmer intensities it correlates with the mathematical average of all the retinal locations tested. 相似文献