Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder.     

CHARAC TERIZATION OF TiAl POWDER PRODUCED BY MECHANICAL ALLOYING

The microstructure,alloying reaction and sintering behavior of the powder produced by Mechanical Al-loying(MA)for 8 h from 64 wt.-% Ti powder and 36 wt.-% Al powder were studied by scanning electronmicroscopy,optical microscopy,X-ray diffractometry,differential scanning calorimetry(DSC)and dilatometry.The mechanically alloyed powder partictes are Ti-Al composite particles.Thus,titanium aluminides can formeasily in the powder through diffusion during heat treatment.It is shown that the sintering behavior of this pow-der,different from the behaviors of TiAl alloy powder and mixed powder of 64 wt.-% Ti powder and 36 wt.-%Al powder,changes from expansion at temperatures below 1000℃ to shrinkage at temperatures above 1000℃.Homogeneously alloyed TiAl material with a density over 96% of the theoretical density can be produced fromthe mechanically alloyed powder by compaction-sintering.     

冬季CO2水玻璃砂促硬防蠕变技术

介绍了使用一种专用改性荆加入普通水玻璃中，使CO2水玻璃砂在低温环境下也能速硬，可防止铸型（芯）蠕变的技术。     

变电站典型光通信模式研究

目前,通信条件已发生了革命性的变化,由早期的载波、微波和电缆等通信介质发展成为以光缆为主的通信网络.电力系统以OPGW光缆、ADSS光缆为主,已覆盖了几乎所有的输变电场所.因此,应建立与之适应的通信模式.通过研究现代通信条件、变电站通信的需求,提出了统一化的、简单的变电站通信模式.     

单周控制光伏并网系统的最大功率控制研究

单周控制的单级全桥光伏并网系统具有容量大、效率高、成本低等优点.但现有基于单周控制的光伏电池最大功率跟踪存在着难以搜索最大功率点、难以稳定工作在最大功率点以及搜索精度差等缺点.针对以上不足,提出了基于增量电导的光伏电池最大功率跟踪算法,该算法将光伏电池输出功率引入到单周控制的输入量中,同时优化了光伏电池输出电压的给定量.该算法在硬件上实现简单,仿真和实验结果表明该算法能够准确跟踪光伏电池最大功率点,并具有较高的精度和稳定性.     

Evaluation research on applicability of rapid iodide migration test

The applicability of the rapid iodide migration test was systematically studied. Comparative experimental tests of different test conditions, including several external voltages, test durations, concrete ages and mixing proportions, were carried out to make clear the transport behaviors of iodide under parallel electric fields. Numerical simulations were also done using the finite element method to found the correlation between chloride and iodide transport behaviors. The test and numerical results show that the chloride transport behaviors of RIM and RCM tests have a good correlation under the several conditions used in the present paper. Moreover, the influence of external conditions （external voltages, test durations） on the test results is small. Thus, it can be concluded that the RIM method is available to determine the chloride penetration resistance of the chloride-eroded structural concrete.     

车用空调器压缩机前端板铸件壳型铸造工艺实践

对前端板铸件壳型铸造中存在的铸造缺陷,采用优化浇注系统,对铁水进行二次孕育处理,调整碳当量控制在3.90%~4.15%,硅含量降低0.15%~0.20%,使产品抗拉强度≥270MPa,硬度(HB)为187~241,满足用户要求。     

圆锥裁剪BLOB的视频目标检测方法

真实场景的视频目标检测需要消除阴影、反射和鬼影等噪声的影响,以检测出运动目标和静止目标.为了实现系统性的视频目标检测,提出一种自适应圆锥裁剪联通块(TC-BLOB)榆测方法.基于BLOB知识,将3D颜色空间变换为"夹角-模差"2D空间后,定义一套圆锥裁剪规则划分出阴影BLOB和反射BLOB;再以一种持久化记忆PM方法判别出鬼影BLOB;最后改进双背景模型检测出静止目标和运动目标.采用不同环境视频进行实验的结果表明,文中方法足有效的,并有独立于后续跟踪的优点.