双机共用尾水调压室阻力系数试验研究

主要对水流在流入和流出调压室时,其流量比、阻抗孔面积和运行机组数目的变化对调压室阻力系数的影响开展了研究,并对双机共用尾水调压室的物理模型进行了水工试验。试验结果表明,调压室的阻力系数会随着流量比的增大和阻抗孔面积的减小而增大。其中,在分流工况时,双机运行的调压室阻力系数比单机运行的调压室阻力系数要大;在合流工况时,单机运行的调压室阻力系数与双机运行时的相差无几。试验结果可为类似型式的尾水调压室的设计与研究提供借鉴及参考。     

超微粒子的合成及其应用

本文综述了超微粒子的合成方法和应用。着重叙述了超微粒子在催化、生物、医学、记录材料、传感材料等方面的应用。     

利用蓄电池废硫酸和硼泥制备高品质氢氧化镁

利用废铅酸蓄电池中的废硫酸作为浸取剂,对硼泥中的镁进行回收并制备出高品质的氢氧化镁产品。实验得出了酸浸硼泥的最佳工艺条件：酸浸温度为80℃;酸浸时间为30 min;酸用量为硫酸与硼泥质量比为1.2∶1。利用不同金属水解pH的不同,将酸浸过程中从硼泥和废硫酸中引入的杂质依次去除,得到精制硫酸镁溶液。由精制硫酸镁制取氢氧化镁的工艺条件为：常温下,沉淀剂为氨水,反应终点pH为11,反应时间为2 h,反应物在50℃下陈化12 h,过滤、洗涤后105℃烘干。实验考察了不同沉淀剂对氢氧化镁形貌的影响。所得氢氧化镁纯度在97%以上,粒径在0.1～1μm之间,各项指标均优于中国化工行业标准。     

Synthesis and properties of soluble polypyrrole doped with dodecylbenzenesulfonate and combined with polymeric additive poly(ethylene glycol)

Soluble polypyrrole (PPy) samples advanced in electrical conductivity σ were chemically synthesized with dodecylbenzenesulfonate (DBS) sodium salt as a dopant, with poly(ethylene glycol) (PEG) as an additive, and with ammonium persulfate as an oxidant. The PPy–DBS–PEG samples were soluble in organic solvents (N‐methylpyrrolinone and m‐cresol). The greater the molar percentage ratio was of DBS, the greater the solubility was of synthesized PPy composites (PPy–DBS–PEG). The maximum electrical conductivity at room temperature for PPy–DBS–PEG was 1.02 S/cm, which was in fact the true conductivity of 100/10 (mol %) PPy/DBS. The chemical composition and doping level of PPy–DBS–PEG were determined by elemental analysis. The results of Fourier transform infrared spectroscopy were used for the structural characterization of PPy–DBS–PEG. The scanning electron microscopy results showed that the electrical conductivity was related to the morphology of PPy–DBS–PEG. According to thermogravimetric analysis, PPy–DBS–PEG was more thermostable than PPy–DBS. Electron spin resonance measurements showed that the polaron and bipolaron acted as charge carriers of PPy–DBS–PEG. According to the temperature dependence of the electrical conductivity, PPy–DBS–PEG was a semiconductor and followed the three‐dimensional variable‐range hopping model. The improved electrical conductivity apparently resulted from the reduction of the crosslinking and structural defects of the PPy chains. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 1170–1175, 2005     

石英砂的塑性机理研究

研究了石英砂的塑性并对其进行改善,得出石英砂颗粒大小、砖坯含水率、砖坯p H值和增塑剂含量对砖坯塑性的影响规律及机理,并且为利用石英砂而采用可塑成型去制备高性能的烧结砖探索出了合适的成型工艺条件:球磨时间24h、含水率为29%、坯料p H=9和增塑剂含量为5%。     

Thermal stability of composite phase change material microcapsules incorporated with silver nano-particles

This paper reports a study on the thermal stability of phase change material microcapsules that are incorporated with silver nano-particles (Ag-NPs). The novel microcapsules were fabricated by the technique of in situ polymerization, with aminoplast as the wall and phase change material bromo-hexadecane (PCM BrC16) as the core. Thermal gravimetry (TG) analysis was applied to measure the thermal stability of these microcapsules and surface morphology of the microcapsules was observed by means of scanning electron microscopy (SEM) after an application of curing treatment at 130 °C. Comparing with conventional phase change material microcapsules (PCMMs), nano-composite phase change material microcapsules (NCPCMMs) have higher thermal stability. This can be attributed to nano-composite structure of the microcapsules, in which metal Ag-NPs distributed on the surface to increase wall toughness and strength. The possible reinforcement mechanisms of the nano-composite structure are explored.     

New fatty acid derivatives from <Emphasis Type="Italic">Homaxinella</Emphasis> sp., a marine sponge

Fractionation of the MeOH extract of Homaxinella sp., a marine sponge, led to the isolation of a sodium salt of a new brominated FA (1), two new MG (2 and 4), and a new lysoPC (6). The geometry of the double bonds in 1 and 2 was defined by comparison of the NMR chemical shifts of the allylic carbons, nuclear Overhauser effect spectroscopy correlations of the allylic protons, and coupling constants of the vinylic protons with those reported. Evidence mainly from NMR and MS analyses established the planar structures of the compounds. Compounds 1, 2, 4, and 6 were evaluated for cytotoxicity against a panel of five human solid tumor cell lines. Only compound 1 showed moderate activity.     

木塑复合材料制品一步法挤出成型技术的研究

介绍了木塑复合材料制品一步法挤出成型中常见的5种挤出设备,提出了选择这些设备时需要考虑的一些因素,分析了木塑复合制品挤出成型技术中温度、压力、喂料和排气等问题产生的原因。并结合实验和理论,从螺杆、机筒、机头设计和加料器选择等方面提出了解决这些问题的措施。     

Optimal entropy-constrained non-uniform scalar quantizer design for low bit-rate pixel domain DVC

In this paper, an optimal entropy-constrained non-uniform scalar quantizer is proposed for the pixel domain DVC. The uniform quantizer is efficient for the hybrid video coding since the residual signals conforming to a single-variance Laplacian distribution. However, the uniform quantizer is not optimal for pixel domain distributed video coding (DVC). This is because the uniform quantizer is not adaptive to the joint distribution of the source and the SI, especially for low level quantization. The signal distribution of pixel domain DVC conforms to the mixture model with multi-variance. The optimal non-uniform quantizer is designed according to the joint distribution, the error between the source and the SI can be decreased. As a result, the bit rate can be saved and the video quality won’t sacrifice too much. Accordingly, a better R-D trade-off can be achieved. First, the quantization level is fixed and the optimal RD trade-off is achieved by using a Lagrangian function J(Q). The rate and distortion components is designed based on P(Y|Q). The conditional probability density function of SI Y depend on quantization partitions Q, P(Y|Q), is approximated by a Guassian mixture model at encocder. Since the SI can not be accessed at encoder, an estimation of P(Y|Q) based on the distribution of the source is proposed. Next, J(Q) is optimized by an iterative Lloyd-Max algorithm with a novel quantization partition updating algorithm. To guarantee the convergence of J(Q), the monotonicity of the interval in which the endpoints of the quantizer lie must be satisfied. Then, a quantizer partition updating algorithm which considers the extreme points of the histogram of the source is proposed. Consequently, the entropy-constrained optimal non-uniform quantization partitions are derived and a better RD trade-off is achieved by applying them. Experiment results show that the proposed scheme can improve the performance by 0.5 dB averagely compared to the uniform scalar quantization.     

Prediction-based realistic 3D model compression

The benefit of using the geometry image to represent an arbitrary 3D mesh is that the 3D mesh can be re-sampled as a completely regular structure and coded efficiently by common image compression methods. For geometry image-based 3D mesh compression, we need to code the normal-map images while coding geometry images to improve the subjective quality and realistic effects of the reconstructed model. In traditional methods, a geometry image and a normal-map image are coded independently. However a strong correlation exists between these two kinds of images, because both of them are generated from the same 3D mesh and share the same parameterization. In this paper we propose a predictive coding framework, in which the normal-map image is predicted based on the geometric correlation between them. Additionally we utilize the strong geometric correlation among three components of normal-map image to improve the predicting accuracy. The experimental results show the proposed coding framework improves the coding efficiency of normal-map image, meanwhile the realistic effect of a 3D mesh is significantly enhanced.