Nitridation Kinetics of Silicon Monocrystal and Morphology of Nitride Film

Basing on TGA (thermal gravimetric analysis) of thermal nitridation at l200, l250, l300℃, respectively,analysis of high temperature kinetics for nitridation of silicon monocrystal has been carried out. According tothe theory for kinetics of reaction of vapour with solid phase a nitridation kinetic model, from which it can beshown thal the rate of nitridation reaction of silicon crystal should be controlled by three stage limiting factors,was proposed. These limiting factors are chemical reaction, chemical reaction mixed with diffusion and diffu-sion. Using this model to treat our experimental data, satisfactory correlation coefficient and apparentactivation energy of nitridation of p-type (lll) silicon crystal have been obtained. The nitride film was identi'fied to be a-Si_3N_4 (Hexagonal, a=0.7758nm,c_o=0.5623nm) by X-ray diffraction analysis. Morphology ofthe nitride films formed in different nitridation duration was observed in both planar andcross-sectional viewsby SEM (scanning electron microscope).     

产品质量管理方法研究述评

对国内外在实施产品质量管理中的质量评价、质量控制、质量保证和质量改进等活动研究的现状进行了系统、全面的概述和深入的分析，并提出了亟待研究与解决的课题。     

赤泥粉煤灰免烧砖工艺配方研究

利用铝厂赤泥、自备电厂粉煤灰为主要原料研制了免烧砖。自然养护的赤泥免烧砖28d达到了非烧结鲁通粘土砖标准JC／T 422—1991（1996）中15级要求。实验结果表明，各原料的最佳配比总结为：赤泥，25％～40％；粉煤灰，18％～28％；骨料，30％～35％；石灰，8％～10％；石膏，2％～3％；水泥，1％。赤泥粉煤灰免烧砖有望成为粘土烧结砖的替代产品。     

Ti衬底层对FePt颗粒膜的微结构和磁特性的影响

在室温下,应用对靶直流磁控溅射设备在普通玻璃基片上制备了FePt(30nm)/Ti(tnm)颗粒膜样品,随后,在真空中进行了原位退火.详细研究了Ti衬底层对FePt颗粒膜的微结构和磁特性的影响.X射线衍射图谱表明样品形成了较有序的L10织构,Ti和FePt形成了三元FePtTi合金.当Ti层厚度t=5 nm、退火温度Ta=500℃时,样品具有高度有序的L10织构、小的颗粒尺寸和优异的磁特性.矫顽力超过了6.7 kOe,饱和磁化强度为620emu/cc.并且具有较小的开关场分布.结果表明FePt/Ti颗粒膜系统可作为超高密度磁记录介质的候选者.     

Effect of cooling rate on the microstructure of electron beam welded joints of two-phase TiAl-based alloy

The analysis of the microstructural characterization and phase composition of electron beam welded joint zones of Ti- 43Al-9V-O. 3Y alloy has been done in this study. The welded seam is mainly composed of B2 phase, the partial γ ＋ α2 twophase lamellar structure and granular γm phase. And the lanthanon Y existed as YAl2 phase and served as grain refined. The impact of different cooling rates on joint microstructure, fracture characteristic and tensile strength were investigated. The high cooling rate restrained the structural transformation and resulted in the ordering structure. The fracture of the joint was brittle cleavage fracture because the ordering structure went against restraining the crack propagation. With the decrease of cooling rate, the transformation amounts of lamellar structure increased, and the fracture presented the layered and crosslayered characteristic.     

Preparation and characterization of TiO2 photoelectrode codoped with aluminum and boron and its application in dye-sensitized solar cell

Nanocrystalline titania films codoped with aluminum and boron were prepared by cathodic vacuum arc deposition. In the process, titanium alloy target was used under an O2/Ar atmosphere, and sensitization of films were carried out by natural dye-sensitized complex in anhydrous ethanol. The structure, surface morphology and UV-vis spectra of titania films codoped were measured by X-ray diffraction analysis, scanning electron microscopy and ultraviolet-visible spectrometer. Theas-deposited films are found to be amorphous. The films annealed were examinedto be of anatase structure with orientation along the (101) planes, the averagecrystal size is in the range between 41 and 45 nm. SEM results show that thereare some pores in the codoped titania films, the optical properties of the dye-sensitized films were also measured which reveals that the spectral responses of films shift to the visible region. Under simulated sunlight illumination, the overall energy conversion efficiency of dye-sensitized nanocrystalline solar cell is 0.9%.     

金属凝固微观组织形成的数值模拟

依据金属凝固的基本理论,在Oldfield的连续形核和晶粒长大模型基础上,引入了时间因子,运用随机方法,建立了连续冷却条件下形核和生长的随机模型,使形核和生长模型函数与时间直接相关,反映了连续冷却条件下的金属凝固微观组织的演化过程。基于上述模型,编制了计算模拟程序,模拟了Zn-5Al共晶合金微观组织的凝固过程,并用试验结果对模拟结果进行了验证对比,模拟结果与试验结果基本相符。     

155kA预焙槽多组阳极脱落的原因及对策

通过对155kA预焙槽造成多组阳极脱落的原因分析和采取对策的总结，可作为其它容量预焙槽处理类似事故的借鉴，起到预防和杜绝此类事故发生的积极作用。     

Simplified and efficient calibration of a mechanistic cutting force model for ball-end milling

Accurate evaluation of the empirical coefficients of a mechanistic cutting force model is critical to the reliability of the predicted cutting forces. This paper presents a simplified and efficient method to determine the cutting force coefficients of a ball-end milling model. The unique feature of this new method is that only a single half-slot cut is to be performed to calibrate the empirical force coefficients that are valid over a wide range of cutting conditions. The instantaneous cutting forces are used with the established helical cutting edge profile on the ball-end mill. The half-slot calibration cut enables successive determination of the lumped discrete values of the varying cutting mechanics parameters along the cutter axis whereas the size effect parameters are determined from the known variation of undeformed chip thickness with cutter rotation. The effectiveness of the present method in determining the cutting force coefficients has been demonstrated experimentally with a series of verification test cuts.     

离子镀TiN膜层的抗蚀性研究

本文对比研究了45钢和ICr18NigTi钢两种不同基体材料镀TiN膜与未镀TiN膜试样的抗盐水腐蚀性能。结果表明，在基材上沉积致密的TiN膜层能十分有效地提高抗腐蚀性，并指出在膜层存在针孔时，将使抗腐蚀性降低，而且这种影响与基材有关。