Synthesis,characterization, and redox and electrochromic behaviors of poly(3-n-octyloxythiophene)

Poly(3-n-octyloxythiophene), a conjugated polymer, which possessed solubility in common organic solvents, was synthesized by electrochemical polymerization in the presence of lithium perchlorate as the supporting electrolyte and sodium dodecyl sulfate as the surfactant in an aqueous medium. Characterizations of the intermediate, monomer, and polymer were performed by NMR spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, and gel permeation chromatography. The process of electrochemical polymerization and the electrochemical redox behaviors were investigated by cyclic voltammetry and the potentiostatic method. A poly(3-n-octyloxythiophene) film that was deposited on a platinum electrode was found to exhibit electrochromic behaviors, and it switched electrochemically between blue–green oxidized and dark red reduced states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

自适应相干噪声衰减技术

去除噪声是必需的地震数据处理过程。由于地表条件和地震波激发、传播以及接收条件等诸多方面的原因，时常引起地震记录上出现各种相干干扰波。本文主要针对地震数据处理中地震剖面上存在的各种相干噪声，提出了时问一空间域自适应相干噪声衰减技术，以进行信噪分离。这种方法把噪声在整个处理平面上的视速度近似看作常量(正值或负值)，可以有效地消除地震剖面上的线性噪声、面波以及多次波等，并且对信号的保真度高。本文方法是复杂地区低信噪比地震数据处理的一种理想的噪声去除方法，具有运算速度快、压制噪声效果好等优点。     

Isobaric vapor–liquid equilibria for mixtures of tetrahydrofuran, 2-propanol, and 2,2,4-trimethylpentane at 101.3 kPa

Vapor–liquid equilibrium (VLE) at 101.3 kPa have been determined for a ternary system (tetrahydofuran + 2-propanol + 2,2,4-trimethylpentane) and its constituent binary systems (tetrahydrofuran + 2-propanol, tetrahydrofuran + 2,2,4-trimethylpentane, and 2-propanol + 2,2,4-trimethylpentane). The activity coefficients of liquid mixtures were calculated from the modified Raoult's law. Thermodynamic consistency tests were performed for all VLE data. The VLE data of the binary mixtures and ternary mixtures were correlated using the Margules, Wilson, NRTL, and UNIQUAC activity-coefficient models. The models with their best-fitted interaction parameters of the binary systems were used to predict the ternary vapor–liquid equilibrium. All VLE data are also used to calculate the reduced excess molar Gibbs free energy g^E/RT and the deviations in the boiling point ΔT. The calculated quantities of g^E/RT and ΔT were fitted to variable-degree polynomials in terms of liquid composition.     

数字分量电视图像的光纤传输实验

介绍了光纤传输数字电视的意义，电视信号分量数字化的标准和优点。利用自行研制的２７０Ｍｂ／ｓ光发射机和光接收机，建立了分量数字电视信号的光纤传输系统，直接传输了１００ｋｍ光纤，系统传输无误码，传输后图像质量不变。光接收机灵敏度达－２９．２４ｄＢｍ，动态范围为１３．５ｄＢ。无压缩电视图像的传输对于远程医疗和演播室间转输节目等有非常实际的意义。     

玻璃与金属封接用杜美丝

利用ＡＥＳ、ＷＤＳ和ｘ－射线衍射等方法，研究了杜美丝表面层、铁镍芯与覆铜层界面的微观结构与特性。结果表明：良好的表面层应由Ｃｕ２Ｏ和非晶态的硼砂构成；玻璃与杜美丝的润湿性决定于表面层的净化程度和构成及加热条件。     

Stability of Mixtoxantrone Hydrochloride in Solution

A stability-indicating reversed-phase high performance liquid chromatographic method was developed for the detection of mitoxantrone HC1 and its degradation products under accelerated degradation conditions. The degradation kinetics of mitoxantrone HC1 in aqueous solution over a pH range of 1.18 to 7.20 and its stability in propylene glycol-or polyethylene glycol 400-based solutions were investigated. The observed rate constants were shown to follow apparent first-order kinetics in all cases. The pH-rate profile shows that maximum stability of mitoxantrone HC1 was obtained at pH 4.01. No general acid or base catalysis from acetate or phosphate buffer species was observed. The catalysis rate constants on the protonated mitoxantrone imposed by hydrogen ion water and hydroxy ion were determined to be 3.72 × 10 min^-1 5.64 × 10-min^-1 and 1.108 × 10^-2min^-1, respectively. The degradation rate constants of mitoxantrone affected by different ionic strength systems. Irradiation with 254 nm UV light at 25±0.5°C was found when canpared with the light-protected controls. Incorporation of nonaqueous propylene glycol or polyethylene glycol in the pH 4.01 mitoxantrone solution shows an increase in its stability at 502±0.5°C.     

用于疏通油水井的脉冲放电技术

评价了各种不同的解堵技术，指出冲击波解堵是一种很有发展前途的技术。介绍了液中脉冲放电产生冲击波的基本原理，并由此研制出了一套井下脉冲放电油水井处理设备样机。通过现场试验，表明用冲击波疏通油井能较好地解除油井污染，提高采收率。