Characterization of (1'R,4S,4aR,7S,7aR)-dihydronepetalactol as a semiochemical for lacewings,including Chrysopa spp. and Peyerimhoffina gracilis

The enantiomerically pure diastereoisomers (1R,4S,4aR,7S,7aR)- (1) and (1R,4R,4aR,7S,7aR)-dihydronepetalactol (2) were synthesized diastereoselectively from a renewable resource, (4aS,7S,7aR)-nepetalactone (3), isolated as the main constituent of the essential oil of the catmint plant Nepeta cataria. The stereochemistry of the compounds was determined by NMR spectroscopy and X-ray crystallography, and the compounds were identified, respectively, as neomatatabiol and isoneomatatabiol, natural products from Actinidia polygama, for which the lactol stereochemistry was previously incompletely defined. Compound 1 was found to catch significant numbers of three species of lacewing in the field: in Korea, Chrysopa cognata, and in the United Kingdom, Nineta vittata and most notably Peyerimhoffina gracilis. All species caught in significant numbers were found more frequently in traps releasing 1 than 2, while more C. cognata, C. formosa, and C. phyllochroma were found in traps releasing (1R,4aS,7S,7aR)-nepetalactol (4). The catch of P. gracilis with 1 is of particular interest as this lacewing has only recently been recorded in the United Kingdom. Where sexed, the lacewings of all species trapped were found to be male, implying a possible pheromonal role for these or structurally related compounds.     

新电动力转向系统的模型开发和控制方法

本文研究了一个新柱型电动力转向(EPS-TT)系统.这种EPS-TT系统的显著特点是采用光隔离转矩传感器测量转向器转矩,它的辅助转矩控制方法是采用一个单向马达和两个离合器.因而它不需要一个复杂的马达驱动系统,该系统在作反向转动时要耗费大量的电能.为估算EPS-TT开发了一个完整的转向系统模型和一个简化了的模型.一个完整的车辆模型用来研究车辆的响应.为控制EPS-TT系统设计了线圈载体控制法和比例积分微分控制算法.分析了加于系列不同正弦输入和结果性能.结果表明用ESP-TT系统所达到的性能和常规的ESP系统通过的频率范围相似.整个转向系统模型结果和简化了的模型结果相似但车辆的响应稍稍不同.该线圈载体控制提供了好的性能不影响车辆的稳定性和可控性.     

Direct Graphene Transfer and Its Application to Transfer Printing Using Mechanically Controlled,Large Area Graphene/Copper Freestanding Layer

Direct graphene transfer is an attractive candidate to prevent graphene damage, which is a critical problem of the conventional wet transfer method. Direct graphene transfer can fabricate the transferred graphene film with fewer defects by using a polymeric carrier. Here a unique direct transfer method is proposed using a 300 nm thick copper carrier as a suspended film and a transfer printing process by using the polydimethylsiloxane (PDMS) stamp under controlled peeling rate and modulus. Single and multilayer graphene are transferred to flat and curved PDMS target substrate directly. With the transfer printing process, the transfer yield of a trilayer graphene with 1000 µm s^?1 peeling rate is 68.6% of that with 1 µm s^?1 peeling rate. It is revealed that the graphene transfer yield is highly related to the storage modulus of the PDMS stamp: graphene transfer yield decreases when the storage modulus of the PDMS stamp is lower than a specific threshold value. The relationship between the graphene transfer yield and the interfacial shear strain of the PDMS stamp is studied by finite‐element method simulation and digital image correlation.     

High-resolution image reconstruction with multisensors

This article considers the problem of reconstructing a high-resolution image from multiple undersampled, shifted, degraded frames with subpixel displacement errors. This leads to a formulation involving a periodically shift-variant system model. The maximum a posteriori (MAP) estimation scheme is used subject to the assumption that the original high-resolution image is modeled by a stationary Markov-Gaussian random field. The resulting MAP formulation is expressed as a complex linear matrix equation, where the characterizing matrix involves the periodic block Toeplitz with Toeplitz block (BTTB) blur matrix and banded-BTTB inverse covariance matrix associated with the original image. By approximating the periodic-BTTB and the banded-BTTB matrices with, respectively, the periodic block circulant with circulant block (BCCB) and the banded-BCCB matrices, it is shown that the computation-intensive MAP formulation can be decomposed into a set of smaller matrix equations by using the two-dimensional discrete Fourier transform. Exact solutions are also considered through the use of the preconditioned conjugate gradient algorithm. Computer simulations are given to illustrate the procedure. © 1998 John Wiley & Sons, Inc. Int J Imaging Syst Technol, 9, 294–304, 1998     

The effects of annealing temperature on characteristics of UBMS sputtered CNx films for protective coatings

The carbon nitride (CNx) films have been prepared by unbalanced magnetron sputtering (UBMS) at room temperature. The deposited CNx films have been post-annealed at temperatures ranging from 300 °C to 700 °C in increments of 200 °C using rapid thermal annealing (RTA) equipment in vacuum ambient. We investigated the effects of rapid thermal annealing on the structural, surface, and physical properties of CNx films for application of protective coatings. As the result, the increasing annealing temperature led to a decline in physical properties of CNx films such as hardness, elastic modulus, adhesion, frication coefficient, and surface roughness, however it is attributed to the improvement of the residual stress in the film. These results are related to the ordering of sp² bonded clustering and the increase of disordered graphite domain by the desorption of N contents in the films, Specially, high annealing temperature over 700 °C is attributed to the graphitization of film.     

Synthesis of TiO2 thin films using single molecular precursors by MOCVD method for dye-sensitized solar cells application and study on film growth mechanism

For dye-sensitized solar cells application, in this study, we have synthesized TiO₂ thin films at deposition temperature in the range of 300–750 °C by metalorganic chemical vapor deposition (MOCVD) method. Titanium(IV) isopropoxide, {TIP, Ti(OⁱPr)₄} and Bis(dimethylamido)titanium diisopropoxide, {BTDIP, (Me₂N)₂Ti(OⁱPr)₂} were used as single source precursors that contain Ti and O atoms in the same molecule, respectively. Crack-free, highly oriented TiO₂ polycrystalline thin films with anatase phase were deposited on Si(1 0 0) with TIP at temperature as low as 450 °C. XRD and TED data showed that below 500 °C, the TiO₂ thin films were dominantly grown in the [2 1 1] direction on Si(1 0 0), whereas with increasing the deposition temperature to 700 °C, the main film growth direction was changed to [2 0 0]. Above 700 °C, however, rutile phase TiO₂ thin films have only been obtained. In the case of BTDIP, on the other hand, only amorphous film was grown on Si(1 0 0) below 450 °C while a highly oriented anatase TiO₂ film in the [2 0 0] direction was obtained at 500 °C. With further increasing deposition temperatures over 600 °C, the main film growth direction shows a sequential change from rutile [1 0 1] to rutile [4 0 0], indicating a possibility of getting single crystalline TiO₂ film with rutile phase. This means that the precursor together with deposition temperature can be one of important parameters to influence film growth direction, crystallinity as well as crystal structure. To investigate the CVD mechanism of both precursors in detail, temperature dependence of growth rate was also carried out, and we then obtained different activation energy of deposition to be 77.9 and 55.4 kJ/mol for TIP and BTDIP, respectively. Also, we are tested some TiO₂ film synthesized with BTDIP precursor to apply dye-sensitized solar cell.     

Utilizing Advanced Characterization Tools to Prevent Reflective Cracking

To prevent premature failures of rehabilitated concrete pavements, transportation authorities need tools to characterize the prerehab pavement condition of its load carrying capacity, and to determine the resistance of the overlay material to underlying crack/joint movements. Two quantitative methods, the rolling dynamic deflectometer (RDD) and overlay tester (OT), along with field performance data were employed in rehabilitation studies involving reflective cracks. The RDD is able to continuously assess vertical differential movements at joints/cracks that represent the potential for reflective cracks on existing pavements. The OT has the ability to determine the resistance of the overlay material to underlying crack/joint movements. The RDD W1?W3 deflections were used to determine areas that have a high potential for reflective cracking due to poor load transfer across joints and cracks. This paper documents results from the RDD and OT on the following five rehabilitation projects: (1) SH225; (2) US96; (3) SH12; (4) SH342; and (5) IH35W. Based on the available test results from these five projects, it was observed that the W1?W3 threshold values of 5.5 mils (0.140 mm) for exposed concrete pavement and 6.5 mils (0.165 mm) for composite pavement with existing hot mix asphalt overlay and an OT threshold value of 700 cycles correlated well with the field performance. Ignoring either of these critical factors may lead to premature reflective cracking.     

Bypass line assisted start-up of a loop heat pipe with a flat evaporator

Loop heat pipes often experience start-up problems especially under low thermal loads. A bypass line was installed between the evaporator and the liquid reservoir to alleviate the difficulties associated with start-up of a loop heat pipe with flat evaporator. The evaporator and condenser had dimensions of 40 mm (W) by 50 mm (L). The wall and tube materials were stainless steel and the working fluid was methanol. Axial grooves were provided in the flat evaporator to serve as vapor passages. The inner diameters of liquid and vapor transport lines were 2 mm and 4 mm, respectively, and the length of the two lines was 0.5 m each. The thermal load range was up to 130 W for horizontal alignment with the condenser temperature of 10°C. The experimental results showed that the minimum thermal load for start-up was lowered by 37% when the bypass line was employed. This paper was recommended for publication in revised form by Associate Editor Dae Hee Lee Joon Hong Boo received his B.S. degree in Mechanical Engineering from Seoul National University in 1978. He then received his M.S.M.E. and Ph.D. degrees from Georgia Institute of Technology in 1984 and 1989, respectively. Dr. Boo is currently a Professor in the School of Aerospace and Mechanical Engineering at Korea Aerospace University, where he joined in 1989. His research interests include heat transfer, heat pipes, and energy systems. He conducted joint research with Texas A&M University and Waseda University in 1994 and 2008, respectively, as Visiting Professor. Dr. Boo is an active member of the International Heat Pipe Conference Committee. Eui Guk Jung received his B.S. and M.S. degrees in Aerospace and Mechanical Engineering from Korea Aerospace University, in 2002 and 2004, respectively. He is currently a Ph.D. candidate in the Graduate School at Korea Aerospace University. His research interests include applications of heat pipes and loop heat pipes.     

Characterization on polymerized thin films for low-k insulator using PECVD

Plasma polymerized cyclohexane and TEOS hybrid thin films have been deposited on silicon substrates at room temperature with varying RF power by plasma-enhanced chemical vapor deposition (PECVD) method. As-grown thin films were annealed in vacuum. Cyclohexane monomer was utilized as organic precursor and TEOS monomer as inorganic precursor. Hydrogen and argon were used as bubbler and carrier gases, respectively. The as-grown plasma polymerized hybrid thin films were analyzed by FT-IR spectroscopy, hardness and modulus measurements, and electrical properties. Annealed hybrid thin films were also analyzed. The dielectric constant of thin films increases with increasing plasma power.     

Completed double layer boundary element method for periodic fibre suspension in viscoelastic fluid

A numerical method to simulate the periodic fibre suspension in viscoelastic fluid is developed with the completed double layer boundary element method (CDLBEM). The periodic summations that arise in the formulation were well handled by Ewald summation technique to speed up the convergence rate in the computation. The formulation for velocity field in periodic fibre suspension in viscoelastic fluid is derived and is used to simulate multiple fibres suspended in a viscoelastic shear flow. Simulations are carried out for various fibre aspect ratios and volume fractions ranging from dilute to concentrated regimes. Numerical results of macroscopic rheological properties of the system are compared to available experiments on viscoelastic fibre suspensions, and are found to agree reasonably well with the experimental data.