Simulation de l'action solaire

Summary Resinous binders and plastic materials are generally sensitive to the action of solar rays. The solar radiation acts together on aspect (colour alteration) and on mechanical properties. The first chapter is devoted to the study of the actual solar radiation, an attempt is made to identify the reasons why this radiation can be aggressive for resinous binders. Chapter 2 gives as examples some deterioration mechanisms of plastic materials under the action of light combined to that of the oxygen of atmosphere. The 3rd chapter covers the simulation of radiation; the different models of lamps used for the study of simulated or artificial ageing are described with their advantages and drawbacks, and practical advice is given concerning the utilization of these lamps.      

Electrochemical Studies on the passive behaviour of tin in different buffer solutions

The effect of pH on the passivity of Sn has been investigated in buffered (phthalate-borate, and citrate phosphate buffer series), and in unbuffered phosphate solutions, using the cyclic voltammetric technique. Two anodic peaks; the first being more pronounced than the second, and on cathodic peak have been observed in the two buffer series at different scan rates and pH values. The anodic and cathodic peak current densities (I_p) and potentials (E_p) are functions of the scan rate (v) and the pH value. Plots of I_p against v^1/2 yield straight lines at each pH value. The effect of pH on I_p for the first anodic peak shows a shallow minimum in the near neutral and slightly alkaline range at all scan rates. Straight lines are also observed between E_p and v^1/2, the extrapolation of which to v = 0 gives the spontaneous (no polarization) oxidation or reduction potentials (E′ and E″). The absence of polarization effects in E′ and E″ make them the most suitable values for comparison with thermodynamic data. Therefore, the two straight lines obtained between E′ and E″ on one hand and the pH on the other hand to give an estimate of (i) the slope (dE°/dpH), and (ii) the value of E° at pH - 0 (from intercept). Comparison of the two experimental values with all available thermodynamic data for Sn(II) and Sn(IV) oxides and hydroxides shows that: (i) the first anodic peak represents the formation of Sn(OH)₂ from Sn and OH^?, (ii) the second anodic peak represents the formation of Sn(OH)₄ directly from Sn and OH^?, and (iii) the cathodic reduction peak correponds to the reduction of Sn(IV) oxidized species to Sn. The results in citratephosphate buffer have been treated in the same manner. However, the result of (dE°/dpH) and E° at pH = 0 deviate from thermodynamic data, because of the possible participation of other anodic reactions such as the formation of soluble Sn compounds, Sn complexes, and incorporation of anions in the anodic film.     

Temperature dependence of the anodic oxidation of titanium below the oxygen evolution potential

The growth of thin anodic oxide films on Ti in the temperature range between 20 and 70° C can be expressed in purely coulometric terms. In diluted and aerated borate solutions the potential increases linearly with time; the slope of the curves increases with increasing current intensity; after 10 to 20 min all the curves show a transition to a flattened shape. Temperature changes have but an insignificant influence on the general character of the curves; the transition to the flatter portion occurs after about 20 min, too, but potentials are the lower, the higher the temperature. The values of the activation energy calculated from the results show, that the layer formation is not only controlled by the bound are face reactions, but also by certain factors coming from the bulk of the solution.     

Dynamic Host-Group/Multi-Destination Routing for Multicast Sessions

Multicast routing research efforts have mostly focused on supporting the host-group model in which multicast packets are addressed to a host (or multicast) group. Another multicast routing approach uses multi-destination addressing, where a multicast packet carries a list of the unique (unicast) addresses of all the group members. This form of routing can be accomplished using limited or no additional state beyond the existing unicast routing tables. It, therefore, scales well with the number of multicast sessions but does not scale well with the size of the multicast group and, in fact, requires the size of the multicast group to be below a certain threshold. In this paper, we envision a future scenario in which both host-group and multi-destination addressing routing approaches coexist within the Internet. We develop a dynamic routing context for this future scenario wherein a multicast session can adapt among different routing configurations depending on the number of multicast group members and how this number changes over time. We consider three routing options: (1) A single multi-destination addressed flow – suitable for small-group sessions, (2) multiple multi-destination addressed flows – suitable for medium-group sessions and (3) a single host-group addressed flow – suitable for large-group sessions. For multicast sessions that vary in group membership over time, different routing protocols may be best at different points in time. Our work is concerned with the development and evaluation of protocols that allow a multicast session to dynamically switch among these three routing options as the size of the session changes.     

Cavity growth in neutron-irradiated magnesium oxide

The growth of cuboidal cavities in neutron-irradiated magnesium oxide after annealing in the temperature range 1475 to 1775° C has been followed using the techniques of transmission electron microscopy and electron spin resonance. Microscopic examination has shown that, while cavities are nucleated on annealing at about 1500° C, most of their growth does not occur until a temperature approaching 1625° C is exceeded. Electron spin resonance spectra from the same samples annealed in the temperature range 1475 to 1575° C indicate that some of the vacancies, which are released to the lattice when cavities are nucleated, are used in the formation, from iron present at impurity level in the crystals, of Fe³⁺ in octahedral symmetry at magnesium sites. This corresponds to the region of negligible cavity growth. For annealing treatments at and above 1625° C however, the fractional volume of crystal occupied by cavities increases by a factor of ten and simultaneously the octahedral symmetry Fe³⁺ transitions disappear. The role of iron in controlling vacancy movement and cavity growth is discussed.     

Anodic polarization of tungsten in neutral and alkaline solutions under conditions of anode film growth

Anodic polarization of W has been studied in neutral (Na₂SO₄, NaCl) and alkaline solutions (ammonium borate, Na₂CO₃, Na₃PO₄, and NaOH) by the galvanostatic method under conditions which lead to anode film growth. The rate of oxide growth has been calculated as a function of current density, nature and concentration of electrolyte. Film growth to potentials above 100 V is achieved in alkaline solutions, provided the solution is dilute and the current density is high. The applicability of the high field ionic conduction has been verified from the dependence of both reciprocal capacity and potential on the logarithm of current density. Data are recorded for the coulometric increase of oxide thickness. The constants of the exponential law, and the electric field.     

The structural properties of Ge<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript> Sb<Subscript>40−<Emphasis Type="Italic">x</Emphasis></Subscript> Se<Subscript>60</Subscript> system

High purity glasses with an average coordination number N_c in the Ge_xSb_40–xSe₆₀ ternary system between 2.4 and 2.7, were prepared under vacuum with x = 0, 10, 20 and 30. X-ray diffraction (XRD) as, well as the Differential Scanning Calorimetry (DSC) studies were carried out to identify the amorphous and polycrystalline structure for the Ge-Sb-Se system. The dependence of properties such as the mean atomic volume V_a, the glass transition temperature T_g and the number of topological constraints N_con were studied as a function of N_c, in the light of recent model proposed for covalent random network. The occurrence of this dependence in addition to those due to topological effects leads to the conclusion that the effects of chemical ordering and the effect, which have topological origin, coexist in this system. To understand the effect of N_c on the glass-forming capability, the number of lone-pair electrons, (N_cs–N_c)/2, and the efficiency of the structural modification were calculated and discussed in relation to topological consideration. This then renders support to Phillipstheoretical model.     

Galvanostatic formation of barrier-type Anodic oxides

Experimental Factors Affecting Oxide Growth Results of galvanostatic anodization of various metals with varying valve-metal behaviour including Nb, Ta, Zr, Ti, Al, W, Te, Sb, and Bi are compiled and compared with respect to the effect of various experimental factors such as surface pretreatment, stirring, solution composition, temperature of the bath, on the efficiency of oxide growth relative to that for other anodic processes. It is concluded that all of the above factors play an important role in the anodization of the non-typical valve metals, particularly Sb, Bi and W. Typical anodic charging curves associated with the process of oxide growth are given for several valve metals. Experimental data relevant to the phenomena of oxide breakdown are recorded and compared. The results indicate that the mechanism of breakdown varies for the same metal with variations in the experimental conditions.     

A Scalable Framework For Segmenting Magnetic Resonance Images

A fast, accurate and fully automatic method of segmenting magnetic resonance images of the human brain is introduced. The approach scales well allowing fast segmentations of fine resolution images. The approach is based on modifications of the soft clustering algorithm, fuzzy c-means, that enable it to scale to large data sets. Two types of modifications to create incremental versions of fuzzy c-means are discussed. They are much faster when compared to fuzzy c-means for medium to extremely large data sets because they work on successive subsets of the data. They are comparable in quality to application of fuzzy c-means to all of the data. The clustering algorithms coupled with inhomogeneity correction and smoothing are used to create a framework for automatically segmenting magnetic resonance images of the human brain. The framework is applied to a set of normal human brain volumes acquired from different magnetic resonance scanners using different head coils, acquisition parameters and field strengths. Results are compared to those from two widely used magnetic resonance image segmentation programs, Statistical Parametric Mapping and the FMRIB Software Library (FSL). The results are comparable to FSL while providing significant speed-up and better scalability to larger volumes of data.