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61.
Xiaojing Zhang Yuquan Cai Xianwei Zhang Tariq Aziz Hong Fan Carla Bittencourt 《应用聚合物科学杂志》2021,138(22):50515
A eugenol-based silicone-containing monomer 4,4′-(1,1,3,3-tetramethyldisiloxane-1,3-dipropyl)bis-2-methoxyphenol(EUSi) was synthesized from eugenol and 1,1,3,3-tetramethyldisiloxane via the hydrosilylation reaction. And waterborne polyurethane (WPU) with excellent properties was obtained by using EUSi as a type of diol chain extender. The unique combination of rigidity and flexibility in the chemical structure of EUSi greatly facilitated the mechanical properties, thermal properties, and water resistance of WPU. With only a 3% dosage of EUSi, the maximum tensile strength was increased from 6.2 to 22.4 MPa, while the water absorption was decreased from 31.3% to a surprisingly 7.6%. Our work provides a new convenient strategy for the preparation of organosilicon-modified WPU with improved performance. 相似文献
62.
Nawal Makhloufi Nadia Chougui Farouk Rezgui Elias Benramdane Carmen S. R. Freire Carla Vilela Armando J. D. Silvestre 《应用聚合物科学杂志》2021,138(20):50450
The present study investigated the fabrication and characterization of bio-based sustainable films composed of a terrestrial plant raw material, namely Opuntia ficus-indica (OFI) cladodes powder (CP) and a marine seaweed derivative, namely agar (A). The effect of glycerol concentration on the properties of the casted films was evaluated at four different contents, namely 30, 40, 50 and 60 wt%. The films present UV-blocking properties, as well as moderate mechanical performance, thermal stability, and water vapor transmission rate (WVTR). The results point to an increase in thickness, elongation at break, moisture content, water solubility, and WVTR with increasing glycerol content. On the contrary, Young's modulus, tensile strength, and water contact angle decreased as glycerol concentration increased. The best combination is obtained for the film with 30% glycerol, based on an intermediate compromise between physical, mechanical, thermal, and barrier properties. All these outcomes express the potentiality of the powder obtained from grinding the OFI cladodes as raw material to produce low-cost films for the development of sustainable packaging materials. 相似文献
63.
Carla G. Luciano Larissa Tessaro Rodrigo V. Lourenço Ana Mônica Q. B. Bittante Andrezza M. Fernandes Paulo J. A. Sobral 《应用聚合物科学杂志》2021,138(42):51246
Research on biopolymers-based active films produced with natural antioxidants and/or antimicrobials has gained attention over the last few years; however, anti-mold activity has been less studied than those of anti-bacteria. The aim of this work was the development and characterization of bi-layer films based on gelatin with natamycin and/or “Pitanga” leaf hydroethanolic extract in the second thin layer in order to determine the effects of these bioactive compounds on bi-layered film properties. The films were characterized regarding their moisture content and solubility in water, optical properties, microstructure, mechanical and thermal properties, water contact angle, water vapor permeability, UV/visible light transmission, X-ray diffraction, Fourier transform infrared (FTIR) spectroscopy, and antioxidant and anti-mold activities. Active films presented activity against Penicillium spp and Aspergillus niger and demonstrated antioxidant activity, as measured by ABTS •+ and DPPH • methods. Neither additive used in the films' second layer significantly affected the films' moisture content, thermal properties or the molecular interactions of the polymer matrix, assessed by FTIR, although some mechanical properties were affected, and the water contact angle. In conclusion, bi-layer films have reduced the quantity of additives required to maintain the antioxidant and anti-mold activities, as compared to similar monolayer films of the same thickness. 相似文献
64.
G. J. Feng J. D. Rossi M. T. Gerusky 《Journal of Materials Engineering and Performance》1994,3(1):105-109
An attempt has been made to apply the linear elastic fracture mechanics concept to Beta-C titanium alloy pressure vessels
that exhibited brittle fractures during hydrotesting. Based on the results of stress analysis on the real structures and fracture
surface examinations, a stress-intensity factor,K
IC, was estimated. TheK
IC value of the material in the cracking direction was measured by a surface semi-elliptical crack method. It was found that
theK
IC value of the material is very close to the estimated stress-intensity factorK
I during failure, which places the pressure vessels in a critical condition in that a small variation in flaw size may cause
a catastrophic failure. A compromise must be made betweenK
IC and the required yield strength. In this restricted case, the yield strength of the material should be controlled in the
range of 1150 to 1200 MPa to avoid brittle fracture and the possible occurrence of yield during hydrotesting. Control of microstructure
and other mechanical properties is also discussed in this investigation. 相似文献
65.
Andre Suslik Spritzer Jeremy Boy Pierre Dragicevic Jean‐Daniel Fekete Carla Maria Dal Sasso Freitas 《Computer Graphics Forum》2015,34(3):461-470
Node‐link infographics are visually very rich and can communicate messages effectively, but can be very difficult to create, often involving a painstaking and artisanal process. In this paper we present an investigation of node‐link visualizations for communication and how to better support their creation. We begin by breaking down these images into their basic elements and analyzing how they are created. We then present a set of techniques aimed at improving the creation workflow by bringing more flexibility and power to users, letting them manipulate all aspects of a node‐link diagram (layout, visual attributes, etc.) while taking into account the context in which it will appear. These techniques were implemented in a proof‐of‐concept prototype called GraphCoiffure, which was designed as an intermediary step between graph drawing/editing software and image authoring applications. We describe how GraphCoiffure improves the workflow and illustrate its benefits through practical examples. 相似文献
66.
We present the first step of a research aimed at automating a driven interactive 3D modeling of an existing architectural object. The method is based on oriented multi-image spherical panoramas produced by stitching techniques. The photogrammetric process has two steps: the creation of a semi-automatic process to find homolog points in two panoramas; the creation of parametric definitions for an interactive modeling creating points, segments, and surfaces based on the plotted points in the first step. By connecting these two steps, the creation of the model will be automatic, as we indicate the necessary points in just one panoramic photo. The principals of multi-view geometry and epipolar geometry were applied to simplify the calculation in the first step in order to create an automatic identification of the correspondent points in the other panorama. The epipolar geometry is described by both analytical and graphical programming, implementing in the first case a C++ application and in the second case a Rhinoceros and Grasshopper application. A case study of the Ponte Rotto in Rome (Italy) is presented. 相似文献
67.
68.
Felisari L Grillo V Jabeen F Rubini S Menozzi C Rossi F Martelli F 《Ultramicroscopy》2011,111(8):1018-1028
A dedicated specimen holder has been designed to perform low-voltage scanning transmission electron microscopy in dark field mode. Different test samples, namely InGaAs/GaAs quantum wells, InGaAs nanowires and thick InGaAs layers, have been analysed to test the reliability of the model based on the proportionality to the specimen mass-thickness, generally used for image intensity interpretation of scattering contrast processes. We found that size of the probe, absorption and channelling must be taken into account to give a quantitative interpretation of image intensity. We develop a simple procedure to evaluate the probe-size effect and to obtain a quantitative indication of the absorption coefficient. Possible artefacts induced by channelling are pointed out. With the developed procedure, the low voltage approach can be successfully applied for quantitative compositional analysis. The method is then applied to the estimation of the In content in the core of InGaAs/GaAs core-shell nanowires. 相似文献
69.
Nicholas Mattei Maria Silvia Pini Francesca Rossi K. Brent Venable 《Annals of Mathematics and Artificial Intelligence》2013,68(1-3):135-160
We investigate the computational complexity of finding optimal bribery schemes in voting domains where the candidate set is the Cartesian product of a set of variables and voters use CP-nets, an expressive and compact way to represent preferences. To do this, we generalize the traditional bribery problem to take into account several issues over which agents vote, and their inter-dependencies. We consider five voting rules, three kinds of bribery actions, and five cost schemes. For most of the combinations of these parameters, we find that bribery in this setting is computationally easy. 相似文献
70.
Jeanbourquin D Sage D Nguyen L Schaeli B Kayal S Barry DA Rossi L 《Water science and technology》2011,64(5):1108-1114
Discharges of combined sewer overflows (CSOs) and stormwater are recognized as an important source of environmental contamination. However, the harsh sewer environment and particular hydraulic conditions during rain events reduce the reliability of traditional flow measurement probes. An in situ system for sewer water flow monitoring based on video images was evaluated. Algorithms to determine water velocities were developed based on image-processing techniques. The image-based water velocity algorithm identifies surface features and measures their positions with respect to real world coordinates. A web-based user interface and a three-tier system architecture enable remote configuration of the cameras and the image-processing algorithms in order to calculate automatically flow velocity on-line. Results of investigations conducted in a CSO are presented. The system was found to measure reliably water velocities, thereby providing the means to understand particular hydraulic behaviors. 相似文献