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41.
42.
The effect of crude oil n-paraffin molecular weight distribution on wax crystallization risk was studied. Sixteen highly paraffinic crude oils from Eastern Venezuela were characterized, in terms of hydrocarbon family distribution, by High Temperature Simulate Distillation (HTSD), Gel Permeation Chromatography (GPC), and wax content. n-Paraffin chain length was correlated with crude oil cloud point and pour point. It was demonstrated that high molecular weight linear paraffins are responsible for crude oil wax precipitation. A quantitative correlation between molecular weight distribution and crude oil flowing properties was also obtained. It was found that the wider the molecular weight distribution, the lower is the wax crystallization risk. Blends of different paraffinic crude oils were prepared and their flowing properties were evaluated in comparison with the original crudes. Cloud points below the mean value were obtained. In some cases, a synergistic effect was observed (cloud points below the minimum of the two crude oils). Blends of some of these crudes with condensates afforded improvements on crude oil flow and a reduction of wax crystallization tendency (cloud point). This phenomenon can be attributed to a combination of two factors: I. increases in C24-n-paraffins, and II. a wider molecular weight distribution. 相似文献
43.
Francisco J. Collado Eduardo Sevilla Carlos Valcárcel 《American Institute of Chemical Engineers》2002,48(5):1100-1108
New thermodynamic fundamentals for vertical pneumatic conueying are proposed with derivation based strictly on mass conservation and continuum concept. For a 1-D, vertical, steady gas-solid flow, these new mass and energy balances allowed the derivation of a new nondimensional energy factor containing the pressure drop. This energy factor correlated quite well with the difference between the inlet gas velocity and solids terminal velocity, when tested against high-pressure, 15-m-high, vertical pneumatic transport data from Institute of Gas Technology. The energy factor was also checked against atmospheric-pressure data of the 5-m lift line of the Pennsylvania State Uniuersity. The new energy factor covers quite well both the atmospheric- and high-pressure sets of data (923 tests) including two heights, lean- and dense-phase transports, several pipe diameters, broad and narrow particle-size distributions, and different materials. The dissipation terms in gas-solid flow were also clearly identified. 相似文献
44.
45.
In this work, we present a novel process to produce plasticized PVC articles. Plasticized PVC dispersion resin (dry blend) was extruded and poured into a hot mold. The mold was transferred to a rotomolding machine, where the final geometry was obtained. Formulations using commercial PVC suspension resin and three different types of plasticizers were prepared under different processing conditions. The physical appearance of the articles and the tensile properties of the materials were evaluated. 相似文献
46.
Dipl.-Phys. Andreas Neuber M. Sc. Guenther Carlos Krieger Dipl.-Ing. Markus Tacke Prof. Dr.-Ing Johannes Janicka 《Forschung im Ingenieurwesen》1996,62(7-8):188-194
Zusammenfassung Die laserspektroskopischen Me?methoden laserinduzierte Fluoreszenz und spontane Ramanspektroskopie werden eingesetzt zur Messung
der Konzentrationen von Stickoxid, Hydroxyl sowie der chemischen Hauptkomponenten und der Temperatur. Betrachtet wird die
thermische Umsetzung von Wasserstoff mit Luftsauerstoff. Es wird die experimentelle Vorgehensweise und Problematik dargestellt.
Ebenso wird der Weg der Modellierung und Berechnung turbulenter Verbrennungsvorg?nge am konkreten Beispiel skizziert. Die
Annahme chemischen Gleichgewichts stellt sich als ungenügend in der Berechnung der Stickoxid- und Hydroxylkonzentrationen
heraus. Eine deutlich bessere Vorhersage wird durch Einführen einer Reaktionsfortschrittsvariablen für das chemische Modell
erreicht. 相似文献
47.
R Legouis M Cohen-Salmon I del Castillo J Levilliers L Capy JP Mornow C Petit 《Canadian Metallurgical Quarterly》1993,17(2):516-518
The human KAL gene, responsible for the X-linked Kallmann syndrome, was isolated previously. Southern blot analysis using human cDNA probes detected cross-hybridization with DNA from several organisms, including chicken and quail. The entire coding sequences of chicken and quail KAL cDNAs were determined. A comparison of these cDNAs with the human KAL cDNA reveals an overall identity of 73 and 72%, respectively. This results in 76 and 75% identity at the protein level. The highest conservation was found in the WAP four-disulfide core motif and in two of the four fibronectin type III repeats reported in the human protein. These results further support the hypothesis that the KAL protein is an extracellular matrix component with anti-protease and adhesion functions. 相似文献
48.
Susana Criado Norman A. García Maria I. Gutirrez Vicente Avila Sonia G. Bertolotti Rio Cuarto 《European Journal of Lipid Science and Technology》1996,98(5):172-175
The ability of mono-, di-, tri-and tetra-hydroxyflavones (7-and 3-hy-droxyflavones, 7, 8-dihydroxyflavone, baicalein and fisetin) to act as photoprotectors against singlet molecular oxygen [O2(Δg)]-initiated photooxidation of fats has been established by a kinetic study. The overall quenching rate constants for a series of five hydroxyflavones perfectly parallel their respective behaviour as inhibitors of the sensitized photooxidation of linoleic acid. The best antioxidative effect was exerted by 7-hydroxyflavone which does not chemically react with O2(1Δg). Nevertheless for the remaining flavonoids of the series, the physical deactivation of O2(1Δg) largely prevails over the chemical process. As for the cases of phenols and related hydroxy-aromatic derivatives, the ionization of the -OH group in the flavones, dramatically accelerates the rate of photooxidation. Under these conditions, the 7-hydroxyflavone also reacts effectively with O2(1Δg). Given that flavonoids are natural oil components, this medium effect should be taken into account during the oil-refining process, in order to avoid the flavonoid photodestruction. 相似文献
49.
Summary The separation of various metal ions by the water-soluble N-maleyl glycine polymer in conjunction with membrane filtration was investigated. The method is based on the retention of inorganic ions by this polymer in a membrane filtration cell and subsequent separation of low-molecular-weight species from the polymer complex formed. It is shown that poly(N-maleyl glycine) can bind several metal ions in aqueous solution at pH 3. At higher pH, the water-soluble polymer can be applied to the separation and preconcentration of many metal ions. In addition, the maximum capacity values of the homopolymer for copper(II) were investigated and compared in the presence of various metal ions at different pHs. 相似文献
50.
R Gutiérrez del Pozo MJ Ricart Brulles MC Bacque L Fernández-Cruz R Talbot-Wright P Carretero González 《Canadian Metallurgical Quarterly》1997,21(10):950-955
OBJECTIVE: Retrospective study of urological complications in our series of reno-pancreatic transplants. MATERIAL AND METHODS: Between February 1983 and May 1994 our group has conducted 93 RPT, 80 of which, mean age 36 +/- 6 years (24-54 years), are studied in this paper: 57 male and 23 female with an average time in dialysis of 20 +/- 15 months (0-84 months) and diabetes evolution of 21 +/- 5 years (11-37 years). RESULTS: Actuarial annual survival of patient, renal graft and pancreatic graft has been 85%, 79% and 74% respectively. Haematuria: 25% incidence, with graft pancreatitis etiology in 16 cases, rejection in 8 and urinary fistula in 6. Urinary infection: 85% incidence, symptomatic in 23 patients (29%) and asymptomatic in the remaining cases. Dysuria, urethritis and urethral stenosis: 14 patients, all male, most with both conditions associated. Reconversion of pancreatic exocrine secretion by intestinal route was performed in 7 patients. Urinary fistula: secondary to surgery in 9 cases and rejection in 4. Etiology of one case remained unknown. In 4 cases it was resolved with conservative treatment, and with surgical correction in 8. One patient required pancreatic transplantectomy and one patient died of AMI. CONCLUSIONS: Urological complication in RPT account for a significant morbidity, urinary fistula being the one with greater repercussion on the patient and pancreatic graft survival. 相似文献