Self‐Assembled Graphene–Enzyme Hierarchical Nanostructures for Electrochemical Biosensing

The self‐assembly of sodium dodecyl benzene sulphonate (SDBS) functionalized graphene sheets (GSs) and horseradish peroxidase (HRP) by electrostatic attraction into novel hierarchical nanostructures in aqueous solution is reported. Data from scanning electron microscopy, high‐resolution transmission electron microscopy, and X‐ray diffraction demonstrate that the HRP–GSs bionanocomposites feature ordered hierarchical nanostructures with well‐dispersed HRP intercalated between the GSs. UV‐vis and infrared spectra indicate the native structure of HRP is maintained after the assembly, implying good biocompatibility of SDBS‐functionalized GSs. Furthermore, the HRP–GSs composites are utilized for the fabrication of enzyme electrodes (HRP–GSs electrodes). Electrochemical measurements reveal that the resulting HRP–GSs electrodes display high electrocatalytic activity to H₂O₂ with high sensitivity, wide linear range, low detection limit, and fast amperometric response. These desirable electrochemical performances are attributed to excellent biocompatibility and superb electron transport efficiency of GSs as well as high HRP loading and synergistic catalytic effect of the HRP–GSs bionanocomposites toward H₂O₂. As graphene can be readily non‐covalently functionalized by “designer” aromatic molecules with different electrostatic properties, the proposed self‐assembly strategy affords a facile and effective platform for the assembly of various biomolecules into hierarchically ordered bionanocomposites in biosensing and biocatalytic applications.     

Synthesis,Morphology, and Properties of Poly(3‐hexylthiophene)‐block‐Poly(vinylphenyl oxadiazole) Donor–Acceptor Rod–Coil Block Copolymers and Their Memory Device Applications

Novel donor–acceptor rod–coil diblock copolymers of regioregular poly(3‐hexylthiophene) ( P3HT )‐block‐poly(2‐phenyl‐5‐(4‐vinylphenyl)‐1,3,4‐oxadiaz‐ole) ( POXD ) are successfully synthesized by the combination of a modified Grignard metathesis reaction ( GRIM ) and atom transfer radical polymerization ( ATRP ). The effects of the block ratios of the P3HT donor and POXD pendant acceptor blocks on the morphology, field effect transistor mobility, and memory device characteristics are explored. The TEM, SAXS, WAXS, and AFM results suggest that the coil block fraction significantly affects the chain packing of the P3HT block and depresses its crystallinity. The optical absorption spectra indicate that the intramolecular charge transfer between the main chain P3HT donor and the side chain POXD acceptor is relatively weak and the level of order of P3HT chains is reduced by the incorporation of the POXD acceptor. The field effect transistor (FET) hole mobility of the system exhibits a similar trend on the optical properties, which are also decreased with the reduced ordered P3HT crystallinity. The low‐lying highest occupied molecular orbital (HOMO) energy level (–6.08 eV) of POXD is employed as charge trap for the electrical switching memory devices. P3HT‐ b ‐POXD exhibits a non‐volatile bistable memory or insulator behavior depending on the P3HT / POXD block ratio and the resulting morphology. The ITO/ P3HT₄₄ ‐b‐ POXD₁₈ /Al memory device shows a non‐volatile switching characteristic with negative differential resistance (NDR) effect due to the charge trapped POXD block. These experimental results provide the new strategies for the design of donor‐acceptor rod‐coil block copolymers for controlling morphology and physical properties as well as advanced memory device applications.     

Multicast capacity and delay trade‐offs in ad hoc networks with random iid mobility model

In this paper, multicast capacity and delay trade‐offs of mobile ad hoc networks are considered under random independently and identically distributed (iid) mobility model. Compared with unicast, multicast can reduce the overall network load by a factor with high probability (whp) in static random ad hoc networks, where k is the number of destination nodes in a multicast session. So we firstly discuss whether the law still holds in mobile random ad hoc networks, and in this case what delay should be tolerated. Through the relation between average retransmissions and multicast capacity, we prove that order of multicast capacity is not achievable whp, and delay for multicast capacity is , where is the number of ad hoc nodes in the whole networks, and and c is a positive constant. Then achievable throughput whp is considered. The nearest neighbor transmission strategy is introduced by Grossglauser and Tse to achieve throughput which is so far the highest achievable unicast capacity. So the multicast capacity of mobile ad hoc networks under this strategy is studied. The analysis shows that under any multicast routing scheme based on the nearest neighbor transmission strategy, the upper bound on multicast capacity is whp. Then we propose a multicast routing and scheduling scheme by which mobile ad hoc networks can achieve throughput whp, and must tolerate total network delay. Copyright © 2009 John Wiley & Sons, Ltd.     

扫描隧道显微镜钨针尖的制备与表征

采用直流电化学刻蚀方法制备扫描隧道显微镜钨针尖,研究了电化学刻蚀过程中NaOH溶液浓度、钨丝浸入长度和刻蚀电压对针尖形貌的影响。通过扫描电子显微镜(SEM)测量针尖曲率半径和针尖纵横比值,以表征针尖的尺寸和形状;通过能谱仪(EDS)分析针尖表面成分,以表征表面清洁度;通过场发射显微镜(FEM)得到Fowler-Nordheim (F-N)曲线来检测针尖发射性能。实验结果表明,当溶液浓度为2 mol/L、钨丝浸入长度为4 mm、刻蚀电压为3 V时,可以得到曲率半径约为100 nm、纵横比值为13的针尖,且表面无钨的氧化层。FEM结果显示当对针尖施加500 V的负偏压时,针尖可以稳定发射50 nA量级的电流,且针尖性能具有良好的一致性。     

高清视频通信云服务若干关键技术研究

相对于普通清晰度的视频通话,高清视频通信在用户体验上有巨大的飞跃,随之带来的是巨大的带宽需求和终端强大的计算能力的要求.目前有许多的厂家都能提供高清视频通信业务,但是在回声处理、自动增益、多方视频会议等关键技术方面,还有很多需要改进和优化的空间.本文将结合应用实践介绍一些针对高清视频通信云服务中的关键技术所进行的优化工作.     

A 220 GHz dynamic frequency divider in 0.5 μm InP DHBT technology

A high performance 3 inch 0.5 μ m InP DHBT technology with three interconnecting layers has been developed. The epitaxial layer structure and geometry parameters of the device were carefully studied to get the required performances. The 0.5×5 μm² InP DHBTs demonstrated f_t=350 GHz, f_max=532 GHz and BV_CEO=4.8 V, which were modeled using Agilent-HBT large signal model. As a benchmark circuit, a dynamic frequency divider operating from 110 to 220 GHz has been designed, fabricated and measured with this technology. The ultra-high-speed 0.5 μm InP DHBT technology offers a combination of ultra-high-speed and high breakdown voltage, which makes it an ideal candidate for next generation 100 GHz+mixed signal integrated circuits.     

基于ANSYS的CPU散热器不同角度鳍片散热分析

由于计算机的体积不断缩小,CPU散热器的散热效果对CPU工作性能的影响越加明显,在智能计算机的有限空间散热问题值得深入讨论和研究.本文利用ANSYS软件建立了CPU散热器的三维有限元模型,对其进行热学性能分析.通过改变散热器鳍片角度得到了散热器的温度分布云图和热梯度分布云图,然后对离散数据进行线性拟合,分析了不同角度的散热器鳍片分别与最大温降、热流量、最大长度值之间的函数关系.研究表明,不同角度的鳍片对散热器的散热效果产生一定的影响,为散热器的优化设计提供了重要依据.     

水电站综合自动化系统抗电磁干扰的措施

水电站综合综合自动化系统是随着科技的日新月异而迅速发展起来的,它以电子信息技术和自动化技术为基础,处于电磁环境下的该系统因灵敏度较高、功能多样、结构复杂等特点易受电磁干扰,因而无法正常运行与工作.因此采取有效措施阻止电磁对水电站综合自动化系统的干扰迫在眉睫.     

叠层片式ZnO压敏电阻器研究进展

叠层片式ZnO压敏电阻器(MLCV)具有体积小、通流容量大、响应速度快、表面安装性好和易实现低压化等优点,其广泛应用于电子和电力系统中。介绍了叠层片式ZnO压敏电阻器的生片材料和内电极材料的研究现状,分析了当前工艺中存在的电极扩散问题,并提出了其解决的办法,同时指出了叠层片式ZnO压敏电阻器向低压化、小型化、集成化及低成本化方向发展的趋势。     

基于CDP1854的智能数据适配器设计与使用

异步接收/同步发送数据适配器是PC机与受控终端之间实现信息交换的接口电路。为了实现信息传送,需要将从PC机串口发送来的串行异步信息转换为同步信息发送出去,该适配器可实现异步接收/串行发送,达到PC机控制受控终端的目的。