Comparing the corrosivity of acidic species in petroleum fractions by raman spectroscopy,energy-dispersive spectrum and scanning electron microscopy

The main object of this work was to compare the corrosion powers of acidic species: naphthenic acid, fatty acid and aromatic acid which were found in petroleum fraction. They were blended into base oils to formulate three simulate oils (E, F and G) with the same TAN values of 2.3 mg KOH/g. AISI 316 steel surfaces immersed in oils were measured by Raman spectroscopy, energydispersive spectrum and scanning electron microscopy after 24, 48, 72 h to evaluate their corrosion. From the Raman images, the corrosion products were confirmed. Besides goethite (α-Fe(OOH)) in corrosion product E at 48 hours; magnetite (Fe₃O₄) in F at 24 hours; and hematite (α-Fe₂O₃ and α-Fe₂O₃) in G at 72hours, there were disordered carbons on steel E and ferric benzoate film on steel G. The contents of elements from EDS have markedly different characteristics, indicating that dominant corrosion products on steel samples resulted from three acidic species are different. The morphology in SEM also corroborated above data that corrosion products have difference. Combining the data of three measurements, the rank of corrosion power based on the formations of ferric oxides was determined: fatty acid > naphthenic acid > aromatic acid.     

Enantioselective Construction of Cyclic Enaminone‐Based 3‐Substituted 3‐Amino‐2‐oxindole Scaffolds via Catalytic Asymmetric Additions of Isatin‐Derived Imines

The first catalytic asymmetric construction of the cyclic enaminone‐based 3‐substituted 3‐amino‐2‐oxindole scaffold with potential bioactivity has been developed via chiral phosphoric acid‐catalyzed enantioselective addition reactions of cyclic enaminones to isatin‐derived imines, which afforded a series of cyclic enaminone‐based 3‐substituted 3‐amino‐2‐oxindoles in high yields and excellent enantioselectivities (up to 99% yield, 97% ee). The investigation of the reaction mechanism suggested that it was facilitated by a dual hydrogen‐bonding activation mode between the two substrates and the chiral phosphoric acid. Besides, this method could be utilized for a large‐scale synthesis with maintained enantioselectivity. This approach will not only offer a useful method for enantioselective construction of the cyclic enaminone‐based 3‐substituted 3‐amino‐2‐oxindole scaffold, but also enrich the research on catalytic asymmetric addition reactions of isatin‐derived imines by using electron‐rich olefins as nucleophiles. More importantly, a preliminary evaluation on the cytotoxicity of some selected products revealed that two of the enantio‐pure compounds exhibited moderate to strong cytotoxicity to A549, 786‐0, ECA109 and BT474 cancer cell lines.

     

Preparation of antimicrobial activated carbon fiber for adsorption

Journal of Porous Materials - Activated carbon fiber (ACF) is often used as efficient adsorption material for removal of contaminants from water. However, the propagation of microorganism on ACF...     

Synthesis of Polymer Nanospheres Conjugated Ce (IV) Complexes for Constructing Double Antibacterial Centers

Journal of Inorganic and Organometallic Polymers and Materials - The antimicrobial materials are rapidly emerging as a primary component in mitigation of bacterial pathogens, and functional...     

Analysis of stress evolution characteristics during TBM excavation in deep buried tunnels

Bulletin of Engineering Geology and the Environment - Full-face tunnel boring machines (TBMs) are widely used in tunnel engineering projects as an efficient, safe and economical tunneling method....     

Chemical synthesis of SmCo_5/Co magnetic nanocomposites

A three-step chemical synthesis of SmCo_5/Co nanocomposites was developed. Firstly, the Co-Sm(OH)_3-Ca(OH)_2 precursors were prepared by co-precipitation.Secondly, SmCo_5 particles were obtained by reductive annealing of the precursors. At last, the SmCo_5/Co nanocomposites were achieved by chemical deposition based on SmCo_5 particles. The SmCo_5/Co nanocomposites contain hard magnetic phase of SmCo_5 with about 100 nm in size and soft magnetic phase of Co with about 8 nm in size,exhibiting independent two-phase structure without alloying. Compared to that of single-phase SmCo_5 particles, the saturation magnetization of SmCo_5/Co nanocomposites is increased by 27.5%. The synthesis provides a new route to fabricate SmCo-based nanocomposites.     

基于巯基嘧啶类衍生物构筑配合物的研究进展

主要就巯基嘧啶及其衍生物类配体的种类,配位方式进行了综述,指出巯基嘧啶及其衍生物类配体在化学和医学上得到了科学家的普遍关注;列举了这类配体构筑配合物的应用,并对其发展前景作了展望。     

Powder Size Influence on Tensile Properties and Porosity for PM Ti_2AlNb Alloy Prepared by Hot Isostatic Pressing

Pre-alloyed powder of Ti_2AlNb alloy was prepared by electrode induction gas atomization method, and the powder was screened into fi ve kinds of powder size distribution. Fully dense Ti_2AlNb alloy was prepared by powder metallurgy(PM) using hot isostatic pressing. The properties of pre-alloyed powder and PM Ti_2AlNb alloy were tested. Results show that mean grain size of PM Ti_2AlNb alloy is infl uenced by powder particle size, but particle size has no signifi cant infl uence on tensile properties. Finer Ti_2AlNb powder has low Argon gas bubble ratio and high oxygen content, and poor fl owability of fi ner powder increases the degree of diffculty during degassing. As a result, big pores( 50 μm) are observed in PM Ti_2AlNb alloy prepared by fi ner powder and cause plasticity loss of tensile properties. In order to get a better comprehensive properties of PM Ti_2AlNb alloy, powder with an average size(～ 100 μm) is suggested.     

试论空气自动监测系统的社会化运营监管

本文针对我国现有的空气质量自动监测系统的运行,结合我国空气质量现状,具有针对性的整理出了关于空气自动监测系统能够保质保量完成的先进经验。本文系统的解释了空气自动监测系统,也希望能够借此来推动空气自动监测系统的进一步发展。     

分析南京沙洲停保场改建工程设计变更的监理

为了满足市民公交出行的需求,南京市不断加强扩大城市停车场地的改建。本文主要分析了南京沙洲停保场在改建过程中,如何加强设计变更的监理控制方法及提高设计变更监理效率,以促进南京公交场站改建工程的发展。